From a review of the first edition: "This book [...] covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics. [...] It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert." (F. Papangelou

The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. No longer an area of specialist interest, it has acquired a central focus in condensed matter studies. The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable information on important recent developments.The two review articles in this volume complement each other in a remarkable way. Both deal with what might be called the modern geometricapproach to the properties of macroscopic systems. The first article by Georgii (et al.) describes how recent advances in the application ofgeometric ideas leads to a better understanding of pure phases and phase transitions in equilibrium systems. The second article by Alava (et al.)deals with geometrical aspects of multi-body systems in a hands-on way, going beyond abstract theory to obtain practical answers. Thecombination of computers and geometrical ideas described in this volume will doubtless play a major role in the development of statisticalmechanics in the twenty-first century.

... "What do you call work?" "Why ain't that work?" Tom resumed his whitewashing, and answered carelessly: "Well. lI1a), he it is, and maybe it aill't. All I know, is, it suits Tom Sawvc/:" "Oil CO/lll!, IIOW, Will do not mean to let 011 that you like it?" The brush continued to move. "Likc it? Well, I do not see wlzy I oughtn't to like it. Does a hoy get a chance to whitewash a fence every day?" That put the thing ill a Ilew light. Ben stopped nibhling the apple ... (From Mark Twain's Adventures of Tom Sawyer, Chapter II.) Mathematics can put quantitative phenomena in a new light; in turn applications may provide a vivid support for mathematical concepts. This volume illustrates some aspects of the mathematical treatment of phase transitions, namely, the classical Stefan problem and its generalizations. The in tended reader is a researcher in application-oriented mathematics. An effort has been made to make a part of the book accessible to beginners, as well as physicists and engineers with a mathematical background. Some room has also been devoted to illustrate analytical tools. This volume deals with research I initiated when I was affiliated with the Istituto di Analisi Numerica del C.N.R. in Pavia, and then continued at the Dipartimento di Matematica dell'Universita di Trento. It was typeset by the author in plain TEX

In this thesis we consider Gibbs measures defined on sparse, locally tree-like graphs. We investigate the asymptotic behavior of these measures in the limit of graph size tending to infinity. In the first part we study replica symmetric heuristics for the asymptotic free energy density. We develop an interpolation scheme for proving replica symmetric bounds, and apply it to establish new results on the free energy of some classical models of statistical physics, including the Ising, Potts, and hard-core models. In particular, for d even we explicitly determine the asymptotic free energy density of ferromagnetic Potts models on graphs converging locally to the d-regular tree. This result covers, for example, any sequence of d-regular graphs with diverging girth. In the second part of this thesis we study random constraint satisfaction problems in which replica symmetric heuristics are expected to fail. For a large class of these problems, the one-step replica symmetry breaking cavity heuristic yields exact predictions of the satisfiability transition. We give the first rigorous confirmations of this prediction for two problems in this class, not-all-equal-SAT and maximum independent set, both in the setting of random regular graphs. In the second problem we furthermore establish tight concentration of the maximum independent set size.

The purpose of this book is to present systematically all known mathematical results on Gibbs measures on Cayley trees (Bethe lattices).The Gibbs measure is a probability measure, which has been an important object in many problems of probability theory and statistical mechanics. It is the measure associated with the Hamiltonian of a physical system (a model) and generalizes the notion of a canonical ensemble. More importantly, when the Hamiltonian can be written as a sum of parts, the Gibbs measure has the Markov property (a certain kind of statistical independence), thus leading to its widespread appearance in many problems outside of physics such as biology, Hopfield networks, Markov networks, and Markov logic networks. Moreover, the Gibbs measure is the unique measure that maximizes the entropy for a given expected energy.The method used for the description of Gibbs measures on Cayley trees is the method of Markov random field theory and recurrent equations of this theory, but the modern theory of Gibbs measures on trees uses new tools such as group theory, information flows on trees, node-weighted random walks, contour methods on trees, and nonlinear analysis. This book discusses all the mentioned methods, which were developed recently.

The book provides an introduction to the physics which underlies phase transitions and to the theoretical techniques currently at our disposal for understanding them. It will be useful for advanced undergraduates, for post-graduate students undertaking research in related fields, and for established researchers in experimental physics, chemistry, and metallurgy as an exposition of current theoretical understanding. - ;Recent developments have led to a good understanding of universality; why phase transitions in systems as diverse as magnets, fluids, liquid crystals, and superconductors can be brought under the same theoretical umbrella and well described by simple models. This book describes the physics underlying universality and then lays out the theoretical approaches now available for studying phase transitions. Traditional techniques, mean-field theory, series expansions, and the transfer matrix, are described; the Monte Carlo method is covered, and two chapters are devoted to the renormalization group, which led to a break-through in the field. The book will be useful as a textbook for a course in `Phase Transitions', as an introduction for graduate students undertaking research in related fields, and as an overview for scientists in other disciplines who work with phase transitions but who are not aware of the current tools in the armoury of the theoretical physicist. - ;Introduction; Statistical mechanics and thermodynamics; Models; Mean-field theories; The transfer matrix; Series expansions; Monte Carlo simulations; The renormalization group; Implementations of the renormalization group. -