From a review of the first edition: "This book [...] covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics. [...] It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert." (F. Papangelou

"This book is much more than an introduction to the subject of its title. It covers in depth a broad range of topics in the mathematical theory of phase transition in statistical mechanics and as an up to date reference in its chosen topics it is a work of outstanding scholarship. It is in fact one of the author's stated aims that this comprehensive monograph should serve both as an introductory text and as a reference for the expert. In its latter function it informs the reader about the state of the art in several directions. It is introductory in the sense that it does not assume any prior knowledge of statistical mechanics and is accessible to a general readership of mathematicians with a basic knowledge of measure theory and probability. As such it should contribute considerably to the further growth of the already lively interest in statistical mechanics on the part of probabilists and other mathematicians." Fredos Papangelou, Zentralblatt MATH The second edition has been extended by a new section on large deviations and some comments on the more recent developments in the area.

A self-contained, mathematical introduction to the driving ideas in equilibrium statistical mechanics, studying important models in detail.

The field of phase transitions and critical phenomena continues to be active in research, producing a steady stream of interesting and fruitful results. No longer an area of specialist interest, it has acquired a central focus in condensed matter studies. The major aim of this serial is to provide review articles that can serve as standard references for research workers in the field, and for graduate students and others wishing to obtain reliable information on important recent developments.The two review articles in this volume complement each other in a remarkable way. Both deal with what might be called the modern geometricapproach to the properties of macroscopic systems. The first article by Georgii (et al.) describes how recent advances in the application ofgeometric ideas leads to a better understanding of pure phases and phase transitions in equilibrium systems. The second article by Alava (et al.)deals with geometrical aspects of multi-body systems in a hands-on way, going beyond abstract theory to obtain practical answers. Thecombination of computers and geometrical ideas described in this volume will doubtless play a major role in the development of statisticalmechanics in the twenty-first century.

In this thesis we consider Gibbs measures defined on sparse, locally tree-like graphs. We investigate the asymptotic behavior of these measures in the limit of graph size tending to infinity. In the first part we study replica symmetric heuristics for the asymptotic free energy density. We develop an interpolation scheme for proving replica symmetric bounds, and apply it to establish new results on the free energy of some classical models of statistical physics, including the Ising, Potts, and hard-core models. In particular, for d even we explicitly determine the asymptotic free energy density of ferromagnetic Potts models on graphs converging locally to the d-regular tree. This result covers, for example, any sequence of d-regular graphs with diverging girth. In the second part of this thesis we study random constraint satisfaction problems in which replica symmetric heuristics are expected to fail. For a large class of these problems, the one-step replica symmetry breaking cavity heuristic yields exact predictions of the satisfiability transition. We give the first rigorous confirmations of this prediction for two problems in this class, not-all-equal-SAT and maximum independent set, both in the setting of random regular graphs. In the second problem we furthermore establish tight concentration of the maximum independent set size.

This is an introductory course on the methods of computing asymptotics of probabilities of rare events: the theory of large deviations. The book combines large deviation theory with basic statistical mechanics, namely Gibbs measures with their variational characterization and the phase transition of the Ising model, in a text intended for a one semester or quarter course. The book begins with a straightforward approach to the key ideas and results of large deviation theory in the context of independent identically distributed random variables. This includes Cramér's theorem, relative entropy, Sanov's theorem, process level large deviations, convex duality, and change of measure arguments. Dependence is introduced through the interactions potentials of equilibrium statistical mechanics. The phase transition of the Ising model is proved in two different ways: first in the classical way with the Peierls argument, Dobrushin's uniqueness condition, and correlation inequalities and then a second time through the percolation approach. Beyond the large deviations of independent variables and Gibbs measures, later parts of the book treat large deviations of Markov chains, the Gärtner-Ellis theorem, and a large deviation theorem of Baxter and Jain that is then applied to a nonstationary process and a random walk in a dynamical random environment. The book has been used with students from mathematics, statistics, engineering, and the sciences and has been written for a broad audience with advanced technical training. Appendixes review basic material from analysis and probability theory and also prove some of the technical results used in the text.