The field of membrane separation technology is presently in a state of rapid growth and innovation. Many different membrane separation processes have been developed during the past half century and new processes are constantly emerging from academic, industrial, and governmental laboratories. While new membrane separation processes are being conceived with remarkable frequency, existing processes are also being constantly improved in order to enhance their economic competitiveness. Significant improvements are currently being made in many aspects of membrane separation technology: in the development of new membrane materials with higher selectivity and/or permeability, in the fabrication methods for high-flux asymmetric or composite membranes, in membrane module construction and in process design. Membrane separation technology is presently being used in an impressive variety of applications and has generated businesses totalling over one billion U.S. dollars annually.The main objective of this book is to present the principles and applications of a variety of membrane separation processes from the unique perspectives of investigators who have made important contributions to their fields. Another objective is to provide the reader with an authoritative resource on various aspects of this rapidly growing technology. The text can be used by someone who wishes to learn about a general area of application as well as by the knowledgeable person seeking more detailed information.

III . 2 Preparation of synthetic membranes 72 III . 3 Phase inversion membranes 75 III. 3. 1 Preparation by evaporation 76 III . 3. 2 Precipitation. from the vapour phase 76 III . 3. 3 Precipitation by controlled evaporation 76 Thermal precipitation 76 III . 3. 4 III . 3. 5 Immersion precipitation 77 Preparation techniques for immersion precipitation 77 III . 4 Flat membranes 77 III . 4. 1 78 III . 4. 2 Tubular membranes 81 III . 5 Preparation techniques for composite membranes 82 III. 5. 1 Interfacial polymerisation Dip-coating 83 III . 5. 2 III . 5. 3 Plasma polymerisation 86 III . 5. 4 Modification of homogeneous dense membranes 87 III . 6 Phase separation in polymer systems 89 III . 6. 1 Introduction 89 III . 6. 1. 1 Thermodynamics 89 III . 6. 2 Demixing processes 99 III . 6. 2. 1 Binary mixtures 99 III . 6. 2. 2 Ternary systems 102 III . 6. 3 Crystallisation 104 III . 6. 4 Gelation 106 III . 6. 5 Vitrification 108 III . 6. 6 Thermal precipitation 109 III . 6. 7 Immersion precipitation 110 III . 6. 8 Diffusional aspects 114 III . 6. 9 Mechanism of membrane formation 117 III. 7 Influence of various parameters on membrane morphology 123 III. 7. 1 Choice of solvent-nonsolvent system 123 III . 7. 2 Choice of the polymer 129 III . 7. 3 Polymer concentration 130 III . 7. 4 Composition of the coagulation bath 132 III . 7. 5 Composition of the casting solution 133 III . 7.

Membrane technology is a rapidly developing area, with key growth accross the process sector, including biotech separation and biomedical applications (e.g. haemodialysis, artificial lungs), through to large scale industrial applications in the water and waste-water processing and the food and drink industries. As processes mature, and the cost of membranes continues to dramatically reduce, so their applications and use are set to expand. Process engineers need access to the latest information in this area to assist with their daily work and to help to develop and apply new and ever more efficient liquid processing solutions. This book covers the latest technologies and applications, with contributions from leading figures in the field. Throughout, the emphasis is on delivering solutions to practitioners. Real world case studies and data from leading organizations -- including Cargill, Lilly, Microbach, ITT -- mean this book delivers the latest solutions as well as a critical working reference to filtration and separation professionals. - Covers the latest technologies and applications in this fast moving bioprocessing sector - Presents a wide range of case studies that ensure readers benefit from the hard-won experience of others, saving time, money and effort - World class author team headed up by the Chair of Chemical Engineering at Oxford University, UK and the VP of Plant Operations and Process Technology at Cargill Corp, the food services company and largest privately owned company in the US

Inorganic membrane science and technology is a new field of membrane separation technology which until recently was dominated by the earlier field of polymer membranes. Currently the subject is undergoing rapid development and innovation.The present book describes the fundamental principles of both synthesis of inorganic membranes and membrane supports and also the associated phenomena of transport and separation in a semi-quantitative form.Features of this book:- Examples are given which illustrate the state-of-the-art in the synthesis of membranes with controlled properties- Future possibilities and limitations are discussed- The reader is provided with references to more extended treatments in the literature- Potential areas for future innovation are indicated.By combining aspects of both the science and technology of inorganic membranes this book serves as a useful source of information for scientists and engineers working in this field. It also provides some observations of important investigators who have contributed to the development of this subject.

Today, membranes and membrane processes are used as efficient tools for the separation of liquid mixtures or gases in the chemical and biomedical industry, in water desalination and wastewater purification. Despite the fact that various membrane processes, like reverse osmosis, are described in great detail in a number of books, processes involving ion-exchange membranes are only described in a fragmented way in scientific journals and patents; even though large industrial applications, like electrodialysis, have been around for over half a century. Therefore, this book is emphasizing on the most relevant aspects of ion-exchange membranes. This book provides a comprehensive overview of ion-exchange membrane separation processes covering the fundamentals as well as recent developments of the different products and processes and their applications. The audience for this book is heterogeneous, as it includes plant managers and process engineers as well as research scientists and graduate students. The separate chapters are based on different topics. The first chapter describes the relevant Electromembrane processes in a general overview. The second chapter explains thermodynamic and physicochemical fundamentals. The third chapter gives information about ion-exchange membrane preparation techniques, while the fourth and fifth chapter discusses the processes as unit operations giving examples for the design of specific plants. - First work on the principles and applications of electrodialysis and related separation processes - Presently no other comprehensive work that can serve as both reference work and text book is available - Book is suited for teaching students and as source for detailed information

Membrane Separation Processes: Theories, Problems, and Solutions provides graduate and senior undergraduate students and membrane researchers in academia and industry with the fundamental knowledge on the topic by explaining the underlying theory that is indispensable for solving problems that occur in membrane separation processes. All major membrane processes are discussed, and an economic analysis is provided. Separation processes such as RO, UF, MF, RO, PRO and MD are thoroughly discussed. During the last two decades, the scope of the R&D of membrane separation processes has been significantly broadened. Other sections in the book cover membrane contactor and membrane adsorption. In addition, hybrid systems in which two or more membrane systems are combined are now being investigated for large-scale applications. Written by renowned experts with extensive experience with industry, education and R&D who have complementary expertise In-depth coverage of the most important conventional and emerging membrane processes Provides fundamental membrane theories for solving problems in separation processes without using complicated software

This concise and systematically organized text, now in its second edition, gives a clear insight into various membrane separation processes. It covers the fundamentals as well as the recent developments of different processes along with their industrial applications and the products. It includes the basic principles, operating parameters, membrane hardware, flux equation, transport mechanism, and applications of membrane-based technologies. Membrane separation processes are largely rate-controlled separations which require rate analysis for complete understanding. Moreover, a higher level of mathematical analysis, along with the understanding of mass transfer, is also required. These are amply treated in different chapters of the book to make the students comprehend the membrane separation principles with ease. This textbook is primarily designed for undergraduate students of chemical engineering, biochemical engineering and biotechnology for the course in membrane separation processes. Besides, the book will also be useful to process engineers and researchers. KEY FEATURES • Provides sufficient number of examples of industrial applications related to chemical, metallurgical, biochemical and food processing industries. • Focuses on important biomedical applications of membrane-based technologies such as blood oxygenator, controlled drug delivery, plasmapheresis, and bioartificial organs. • Includes chapter-end short questions and problems to test students’ comprehension of the subject. NEW TO THIS EDITION • A new section on membrane cleaning is included. Membrane fabrication methods are supplemented with additional information (Chapter 2). • Additional information on silt density index, forward osmosis and sea water desalination (Chapter 3). • Physicochemical parameters affecting nanofiltration, determination of various resistances using resistance in series model and few more industrial applications with additional short questions (Chapter 4). • Membrane cross-linking methods used in pervaporation, factors affecting pervaporation and few more applications (Chapter 9). • Membrane distillation, membrane reactor with different modules, types of membranes and reactions for membrane reactor (Chapter 13).