The fluorine atom, by virtue of its electronegativity, size, and bond strength with carbon, can be used to create compounds with remarkable properties. Small molecules containing fluorine have many positive impacts on everyday life of which blood substitutes, pharmaceuticals, and surface modifiers are only a few examples. Fluoropolymers, too, while traditionally associated with extreme high performance applications have found their way into our homes, our clothing, and even our language. A recent American president was often likened to the tribology of PTFE. Since the serendipitous discovery of Teflon at the DuPont Jackson Laboratory in 1938, fluoropolymers have grown steadily in technological and marketplace importance. New synthetic fluorine chemistry, new processes, and new apprecia tion of the mechanisms by which fluorine imparts exceptional properties all contribute to accelerating growth in fluoropolymers. There are many stories of harrowing close calls in the fluorine chemistry lab, especially from the early years, and synthetic challenges at times remain daunting. But, fortunately, modem techniques and facilities have enabled significant strides toward taming both the hazards and synthetic uncertainties, In contrast to past environmental problems associated with fluorocarbon refrigerants, the exceptional properties of fluorine in polymers have great environmental value. Some fluoropolymers are enabling green technologies such as hydrogen fuel cells for automobiles and oxygen selective membranes for cleaner diesel combustion.

Introduction to Fluoropolymers demystifies fluoropolymers for a wide audience of designers, engineers, sales staff and managers. This important group of high-performance polymers has applications across a wide range of market sectors, including automotive, aerospace, medical devices, high performance apparel, oil & gas, renewable energy / solar photovoltaics, electronics / semiconductor, pharmaceuticals, and chemical processing. Dr. Ebnesajjad covers the history and applications of a wide variety of materials, including expanded polytetrafluoroethylene, polyvinyl fluoride, vinylidene fluoride polymers and fluoroelastomers, just to name a few. Properties and applications are illustrated by real-world examples as diverse as waterproof clothing, vascular grafts and coatings for aircraft interiors. The different applications of fluoropolymers show the benefits of a group of materials that are highly water-repellant and flame-retardant, with unrivalled lubrication properties and a high level of biocompatibility. Health and safety and environmental aspects are also covered throughout the book. - Demystifies fluoropolymers for a broad audience of engineers in areas such as product design and manufacturing, as well as for non-engineers such as technical sales and management professionals - Explains the potential of fluoropolymers for a wide range of applications across sectors such as aerospace, energy and medical devices - Ideal for both recently qualified engineers and engineers with limited experience of fluoropolymers

Fluoroplastics, Volume 2: Melt Processible Fluoropolymers - The Definitive User's Guide and Data Book compiles the working knowledge of the polymer chemistry and physics of melt processible fluoropolymers with detailed descriptions of commercial processing methods, material properties, fabrication and handling information, technologies, and applications, also including history, market statistics, and safety and recycling aspects. Both volumes of Fluoroplastics contain a large amount of specific property data useful for users to readily compare different materials and align material structure with end use applications. Volume Two concentrates on melt-processible fluoropolymers used across a broad range of industries, including automotive, aerospace, electronic, food, beverage, oil/gas, and medical devices. This new edition is a thoroughly updated and significantly expanded revision covering new technologies and applications, and addressing the changes that have taken place in the fluoropolymer markets. - Exceptionally broad and comprehensive coverage of melt processible fluoropolymers processing and applications - Provides a practical approach, written by long-standing authorities in the fluoropolymers industry - Thoroughly updated and significantly expanded revision covering new technologies and applications, and addressing the changes that have taken place in the fluoropolymer markets

Because of the increasing need for ever better performing materials endowed with specific properties, macromolecular engineering has become a useful tool for designing well-architectured polymers (telomers, telechelics, stars, dendrimers, alternating, block- and graftcopolymers). These polymers are nowadays seeing an enormous growth. Among them, fluoropolymers are seen as high value added materials in many applications ranging from surfactants, optical fibers, biomaterials, coatings, to membranes for fuel cells. Indeed, the relationship between structure of the monomer to the properties of the polymers is of increasing interest so that these properties are tuned for the most appropriate applications. As most fluoropolymers are prepared from radical synthesis, this book devotes various parts on the use of the controlled radical (or pseudo-living) polymerisation of fluoromonomers leading to discoveries of thermoplastic elastomers or original surfactants for polymerisation in supercritical CO2. Well-Architectured Fluoropolymers: Synthesis, Properties and Applications is composed of five chapters starting with a general introduction outlining basic concepts. Emphasis is placed on recent developments, and each chapter describes comprehensive techniques of synthesis of well-defined fluorotelomers or polymers, their properties, characterisations, and their applications, for immediate use by today's engineers, industrial and academic scientists, and researchers. The book has been arranged to enable self-managed reading and learning. It is both a source of data and a reference. - On the synthesis, properties and applications of fluoropolymers: remarkable, high value added materials applied in surfactants, optical fibres, biomaterials, coatings and membranes for fuel cells - For immediate use by today's engineers, industrial and academic scientists, and researchers - Written to enable self-managed reading and learning, being both a source of data and a reference

Handbook of Fluoropolymer Science and Technology A comprehensive handbook on fluoropolymer synthesis, characterization, and processing Fluoropolymers, one of the more durable classes of polymer materials, are known to enable novel technologies as a result of their remarkable properties. As key components in industry applications, fluoropolymers have established commercial interest and scientists have discovered more efficient approaches of handling them. This book reviews up-to-date fluoropolymer platforms as well as recently discovered methods for the preparation of fluorinated materials. It focuses on synthesis, characterization, and processing aspects, providing guidelines for practicing scientists and engineers. In addition, the book covers: Concepts and studies from leading international laboratories, including academia, government, and industrial institutions Emerging technologies and applications in energy, optics, space exploration, fuel cells, microelectronics, gas separation membranes, biomedical instrumentation, and more Current environmental concerns associated with fluoropolymers, relevant regulations, and growth opportunities Overall, the chapters provide coverage of chemical methods and help the reader further understand how fluoropolymer research provides solutions for material challenges. The concepts in this book also inspire professionals to identify new markets and funding sources for fluoropolymer research and development.

Fluoropolymer Applications in Chemical Processing Industries: The Definitive User's Guide and Handbook, Second Edition, contains the most extensive collection of data and information on fluoropolymer applications in chemical processing industries. Because of their superior properties, fluoropolymers have been rapidly replacing metal alloys for corrosion inhibition in chemical processing equipment. This book is a complete compendium of information about fluoropolymer lining materials and structural piping and tubing. Fluoropolymer surfaces preserve purity of processing streams in the chemical processing, plastics, food, pharmaceutical, semiconductor, and pulp and paper industries. Updated to reflect major changes since 2004, this book contains practical, problem-solving tools for professionals in those industries. Equipment manufacturers, plant operators, and product design and manufacturing engineers all will benefit from the in-depth knowledge provided. This new edition includes new fluoropolymer grades and new examples of the fluoropolymer role in preventing corrosion. New fabrication techniques have been added, and additional emphasis has been placed on adhesion and welding techniques. New sections have been added on inspection of new linings, and in-service inspection – including inspection frequency, acceptance criteria, fitness for service evaluation, and reparability. - Includes extensive guidelines for the selection of fluoropolymers for corrosion control - Features a detailed 'how-to' on processes that convert fluoropolymers into shapes and parts - Discusses fabrication techniques to finish the fluoropolymer components before exposure to harsh chemical environments - Includes laboratory techniques to determine the cause of part failure, and a modeling methodology to predict and analyze failure of fluoropolymer parts

Fluoroplastics, Volume 1, compiles in one place a working knowledge of the polymer chemistry and physics of non-melt processible fluoropolymers with detailed descriptions of commercial processing methods, material properties, fabrication and handling information, technologies, and applications. Also, history, market statistics, and safety and recycling aspects are covered. Both volumes contain a large amount of specific property data which is useful for users to readily compare different materials and align material structure with end use applications.Volume 1 concentrates mostly on polytetrafluoroethylene and polychlorotrifluoroethylene and their processing techniques – which are essentially non-melt-processes – used across a broad range of industries including automotive, aerospace, electronic, food, beverage, oil/gas, and medical devices.Since the first edition was published many new technical developments and market changes have taken place and new grades of materials have entered the market. This new edition is a thoroughly updated and significantly expanded revision covering new technologies and applications, and addressing the changes that have taken place in the fluoropolymer markets.Fluoroplastics, Volume 1 is an all-encompassing handbook for non-melt processible fluoropolymers – a unique and invaluable reference for professionals in the fluoropolymer industry and fluoropolymer application industries. - Exceptionally broad and comprehensive coverage of non-melt processible fluoropolymers processing and applications. - Practical approach, written by long-standing authority in the fluoropolymers industry. - New technologies, materials and applications are included in the new edition.