What happens to a chemical once it enters the natural environment?How do its physical and chemical properties influence itstransport, persistence, and partitioning in the biosphere? How donatural forces influence its distribution? How are the answers tothese questions useful in making toxicological and epidemiologicalforecasts? Environmental Chemodynamics, Second Edition introduces readers tothe concepts, tools, and techniques currently used to answer theseand other critical questions about the fate and transport ofchemicals in the natural environment. Like its critically acclaimedpredecessor, its main focus is on the mechanisms and rates ofmovement of chemicals across the air/soil, soil/water, andwater/air interfaces, and on how natural processes work to mobilizechemicals near and across interfaces--information vital toperforming human and ecological risk assessments. Also consistent with the first edition, EnvironmentalChemodynamics, Second Edition is organized to accommodate readersof every level of experience. The first section is devoted totheoretical underpinnings and includes discussions of mass balance,thermodynamics, transport science concepts, and more. The secondsection concentrates on practical aspects, including the movementbetween bed-sediment and water, movement between soil and air, andintraphase chemical behavior. This revised and updated edition of Louis J. Thibodeaux's 1979classic features new or expanded coverage of: * Equilibrium models for environmental compartments * Dry deposition of particles and vapors onto water and soilsurfaces * Chemical profiles in rivers and estuaries, particles and porousmedia * Fate and transport in the atmospheric boundary layer and withinsubterranean media * Chemical exchange between water column and bed-sediment * Intraphase chemical transport and fate This Second Edition of Environmental Chemodynamics also includestwice as many references and 50% more exercises and practiceproblems.

Partitioning of chemicals in the environment and its modeling is becoming an important field in environmental science and engineering. This book enables students, researchers, and interested laymen to enter the field of environmental modeling in a fast and effective way. The book contains modeling software (CemoS V 1.10), data sets and the CemoS handbook. Each chapter contains examples and exercises.

Reviews existing knowledge in the natural and engineering sciences to determine the rates, lifetimes, routes, and reservoirs of chemicals moving through the environment and to estimate the level of exposure to susceptible living and nonliving targets. Uses simple models and ideas as guides in constructing integrated environmental and ecosystem models for simulating chemical movement and fate. Coverage includes phase equilibrium and transport processes; the interphase and intraphase transport process; movement of inorganic and organic chemicals across the air-water interface; desorption of chemicals from the mud-water interface; volatilization of pesticides from air-soil surfaces; and vertical distribution of dissolved, reactive chemicals in stratified waterbodies. Includes numerous problems from current literature and appendices with chemical, physical, transport, and environmental data.

Given the presence of a wide variety of contaminants in the environment, it is important to understand what drives a contaminant from one medium to another, as well as the manner and extent to which a contaminant associates with the different media or phases within a local environmental system. Partition and Adsorption of Organic Contaminants in Environmental Systems forms a comprehensive resource on the behavioral characteristics of contaminants so that appropriate strategies can be adopted to either prevent or minimize their adverse impacts on human welfare and natural resources. Cary Chiou’s far-reaching text depicts the processes by which nonionic organic contaminants are sorbed to natural biotic and abiotic substances. This book focuses on physical principles and system parameters that affect the contaminant uptake by soil from water, air, and other media; by fish from water; and by plants from soil and water. As contaminant uptake by natural organic substances is often predominantly a partition interaction, the partition characteristics in several solvent-water model mixtures are treated in detail to elucidate the relevant physicochemical parameters. The account of contaminant sorption to soils, fish, and plants is strengthened by companion chapters on: Fundamentals of solution theory Interphase partition equations Fundamentals of adsorption theory Vapor adsorption on mineral and carbonaceous solids No other single source in the field delivers as compelling a combination of background understanding and "state-of-the-science" comprehension of current issues. Ideally suited for a graduate-level environmental course, Partition and Adsorption of Organic Contaminants in Environmental Systems also serves as a technical guide to current and future research in the field.

Based on discussions at the 2007 SETAC Europe PERAS Workshop in Coimbra, Semi-Field Methods for the Environmental Risk Assessment of Pesticides in Soil presents a timely summary of state-of-the-art higher-tier terrestrial risk assessment of plant protection products (PPPs). Influential regulators, academics, and industry scientists provide a compre

Pollution and its control are now one of the most serious problems in environmental management, affecting localized areas, regions, and, increasingly, the entire ecosphere. Chemistry and Ecotoxicology of Pollution provides a basic understanding of the chemical, toxicological, and ecological factors involved when major classes of pollutants act on natural systems. The nature and effects of these pollutants are examined from the primary level of their sources and chemical properties, through their interactions in the environment, to their ultimate ecological effects on organisms and ecosystems. Pollutants are divided into groups, with similar properties, and then the chemistry and ecotoxicology of each group is defined. More importantly, in collating and evaluating available information on pollution processes, the book develops unifying theories on the fundamental chemical and ecological nature of pollution processes. The book uses a conceptual framework to evaluate the impact of pollutants on the components and functions of natural ecosystems. It is based on the chemical and physical properties of a pollutant, its environmental behavior and fate, exposure to and toxic effects on organisms, their populations, communities, and responses of affected ecosystems. This sequence can be applied to known, potential, and emerging pollutants of concern. As government initiatives for the control of chemicals take greater effects, pollution research, particularly in ecotoxicology, will be further developed. Chemistry and Ecotoxicology of Pollution helps play an important role in determining the future direction of research activities in environmental management and pollution control on a worldwide scale. It is a basic resource for students (e.g. environmental chemistry, ecology, land and water management, environmental or public health, environmental engineering, and sustainability science), scientists, researchers, policy makers, and professionals in need of a clear understanding of the nature and effects of environmental pollution from an ecological perspective.

A comprehensive account of the state of the science of environmental mass transport Edited by Louis J. Thibodeaux and Donald Mackay, renowned experts in this field, the Handbook of Chemical Mass Transport in the Environment covers those processes which are critically important for assessing chemical fate, exposure, and risk. In a comprehensive and authoritative format, this unique handbook provides environmental chemists, geoscientists, engineers, and modelers with the essential capabilities to understand and quantify transport. In addition, it offers a one-stop resource on environmental mass transfer and mass transport coefficient estimation methods for all genres. The book begins by discussing mass transport fundamentals from an environmental perspective. It introduces the concept of mobility — key to environmental fate, since transport must occur prior to any reaction or partitioning within the natural multimedia compartments. The fugacity approach to environmental mass transfer and the conventional approach are examined. This is followed by a description of the individual mass transport processes and the appropriate flux equations required for a quantitative expression. The editors have identified 41 individual processes believed to be the most environmentally significant, which form the basis for the remainder of the book Using a consistent format for easy reference, each chapter: Introduces the specific processes Provides a detailed qualitative description Presents key theoretical mathematical formulations Describes field or laboratory measurements of transport parameters Gives data tables and algorithms for numerical estimates Offers a guide for users familiar with the process who are seeking a direct pathway to obtain the numerical coefficients Presents computed example problems, case studies and/or exercises with worked-through solutions and answers The final chapter presents the editors’ insight into future needs and emerging priorities. Accessible and relevant to a broad range of science and engineering users, this volume captures the state of the transport science and practice in this critical area.