This book describes the emergent endohedral metallofullerene, lithium-containing fullerene Li@C60, with an overview from its history to recent application research. The book covers synthesis, preparation, purification, structure, physical and chemical properties, derivatization, computational theoretical studies, and device application of Li@C60. Readers can learn cutting-edge nanotechnology of this exotic nanocarbon material, which is expected to deliver future solutions in clean energy and bio devices. This work is by a researcher who has long experience in carbon nanomaterials—more than 15 years with his contributing coworkers. The level of the book is appropriate for graduate students, post-docs researchers, and young faculty members who are interested in nanomaterials from the point of view of chemistry and physics.

To the eyes of a chemist, carbon is certainly one of the most fascinating elements of the periodic table. Basically, the electronic structure and atomic size of carbon enables this element to form a variety of bonds with other elements and, most importantly, with other carbon atoms as weIl. These unique features lead to the amazingly complicated molecular structures we encounter e. g. in life sciences and organic chemistry. Of course, the technical importance of carbon is enormou- but I don't want to carry too many coals to Newcastle. Prom the viewpoint of an astrophysicist or chemist, the significance of carbon lies in the fact that it is the most abundant condensable element in space. Born in the interior of stars, and from there expelled into the interstellar medium, it initiates the formation of simple and complex molecules and of nanoscopic grains. These in turn form huge clouds in space - the birthplace of new stars and planetary systems. The decisive role of carbon in interstellar chemistry is widely accepted and the search for more and more families of interstellar carbon-bearing molecules is a topic of ongoing research. The interdisciplinary aspect of carbon also concerns its various solid forms, in which C and the other closed-cage fullerenes are certainly some of the most popular 60 newcomers.

Fullerene, molekulare "Fu?balle" aus 60 oder mehr Kohlenstoffatomen, sind eine Substanzklasse mit vielversprechenden Zukunftsaussichten, beispielsweise als Halbleiter, als Basis pharmazeutischer Wirkstoffe oder Polymerwerkstoffe. Dieses Buch bietet Ihnen einen aktuellen Uberblick uber das dynamische Forschungsgebiet. Zur Sprache kommen modernste Themen wie Metallofullerene, Nanorohren und organisch funktionalisierte Fullerenverbindungen. (06/00)

To the eyes of a chemist, carbon is certainly one of the most fascinating elements of the periodic table. Basically, the electronic structure and atomic size of carbon enables this element to form a variety of bonds with other elements and, most importantly, with other carbon atoms as weIl. These unique features lead to the amazingly complicated molecular structures we encounter e. g. in life sciences and organic chemistry. Of course, the technical importance of carbon is enormou- but I don't want to carry too many coals to Newcastle. Prom the viewpoint of an astrophysicist or chemist, the significance of carbon lies in the fact that it is the most abundant condensable element in space. Born in the interior of stars, and from there expelled into the interstellar medium, it initiates the formation of simple and complex molecules and of nanoscopic grains. These in turn form huge clouds in space - the birthplace of new stars and planetary systems. The decisive role of carbon in interstellar chemistry is widely accepted and the search for more and more families of interstellar carbon-bearing molecules is a topic of ongoing research. The interdisciplinary aspect of carbon also concerns its various solid forms, in which C and the other closed-cage fullerenes are certainly some of the most popular 60 newcomers.

A crucial overview of the cutting-edge in nanocarbon research and applications In Synthesis and Applications of Nanocarbons, the distinguished authors have set out to discuss fundamental topics, synthetic approaches, materials challenges, and various applications of this rapidly developing technology. Nanocarbons have recently emerged as a promising material for chemical, energy, environmental, and medical applications because of their unique chemical properties and their rich surface chemistries. This book is the latest entry in the Wiley book series Nanocarbon Chemistry and Interfaces and seeks to comprehensively address many of the newly surfacing areas of controversy and development in the field. This book introduces foundational concepts in nanocarbon technology, hybrids, and applications, while also covering the most recent and cutting-edge developments in this area of study. Synthesis and Applications of Nanocarbons addresses new discoveries in the field, including: · Nanodiamonds · Onion-like carbons · Carbon nanotubes · Fullerenes · Carbon dots · Carbon fibers · Graphene · Aerographite This book provides a transversal view of the various nanocarbon materials and hybrids and helps to share knowledge between the communities of each material and hybrid type.

The discovery of caged carbon structures, in 1985, established a whole new field of carbon chemistry. Unlike graphite and diamond, these structures known as fullerenes are finite in structure and are relevant to a wide variety of fields including supramolecular assemblies, nanostructures, optoelectronic devices and a whole range of biological activities. Fullerenes: Principles and Applications discusses all aspects of this exciting field. Sections include: the basic principles for the chemical reactivity of fullerenes, electrochemistry, light induced processes, fullerenes for material sciences, fullerenes and solar cells, biological applications and multifunctional carbon nanotube materials. Written by leading experts in the field the book summarises the basic principles of fullerene chemistry but also highlights some of the most remarkable advances that have occurred in recent years. Fullerenes: Principles and Applications will appeal to researchers in both academia and industry.

with contributions by numerous experts