Electrophilic Substitution at a Saturated Carbon Atom

Teil 5

Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.

In this edition, the subject matter of this well-known book has been reorganized with integration of the study of aliphatic and aromatic compounds on the basis of functional groups, laying emphasis on the mechanistic aspects. Special emphasis has been laid on the mechanism and electronic interpretation of the reactions of different classes of compounds, bringing out the salient points of difference in the properties of aliphatic and aromatic compounds. With its very comprehensive coverage, the book will not only be useful to the UG and PG students of chemistry but also IIT/NEET aspirants.

Selected Works in Organic Chemistry focuses on the processes, methodologies, reactions, and approaches involved in organic chemistry, including analysis of diazo compounds and infrared absorption spectra. The publication first offers information on the method of synthesis of aromatic organomercury salts; method of synthesis of symmetrical aromatic organomercury compounds; and diazo method of synthesis of aromatic organomercury compounds with negative substituent in nucleus. The reaction of aliphatic diazo compounds with mercury salts and synthesis of organotin compounds through diazo compounds are also discussed. The manuscript takes a look at the synthesis of aromatic organometal compounds of bismuth through diazo compounds; synthesis of aromatic germanium compounds through aryldiazonium tetrafluoroborate; and reduction of organomercury compounds by bivalent tin salts as a method of synthesis. The text also examines the activation energy of the disaggregation process of associated alkoxy titanium derivatives and determination of positions of substituents in ferrocene compounds by means of infrared absorption spectra. The publication is a valuable reference for readers interested in organic chemistry.