The results obtained from kinetic studies on reactions in solids often depend on numerous factors. Therefore, it is important for researchers to understand how both chemical factors related to composition and procedural choices may influence outcomes. Dynamic Processes in Solids provides an authoritative overview of reactions in solids and helps readers interpret the results obtained from kinetic studies. In chapters written by active researchers, the reader will learn about choosing appropriate experimental techniques and their limitations for studying various types of reactions. Beginning with an introduction to numerous aspects of rate processes in solids and experimental techniques, information is provided on rate laws, factors affecting rates, diffusion, and sintering. Subsequent chapters deal with electrical conductivity in dispersed phase polymers, thermochemical reactions for producing solid materials, reactions in coordination compounds, dynamic observations on plastic deformation, light driven phenomena in quantum materials, decomposition of perovskite photovoltaic compounds, and reaction of oxygen radicals with surfaces. This book is a practical introduction to the field for chemists and researchers whose work is directly related to dynamic changes in solids, and additionally for those in related fields whose work would be enhanced by an understanding of these types of rate processes. - Presents useful discussions of the applications of several experimental techniques - Describes approaches for synthesis of solid materials by thermochemical reactions - Presents theoretical interpretation structural dynamics and processes at the molecular level in solids - Provides information on the relationships between performance and rate processes in several types of materials related to electronic behavior

This book presents the latest advances in flowsheet simulation of solids processes, focusing on the dynamic behaviour of systems with interconnected solids processing units, but also covering stationary simulation. The book includes the modelling of solids processing units, for example for comminution, sifting and particle formulation and also for reaction systems. Furthermore, it examines new approaches for the description of solids and their property distributions and for the mathematical treatment of flowsheets with multivariate population balances.

This coherent monograph describes and explains quantum phenomena in two-dimensional (2D) electron systems with extremely strong internal interactions, which cannot be described by the conventional Fermi-liquid approach. The central physical objects considered are the 2D Coulomb liquid, of which the average Coulomb interaction energy per electron is much higher than the mean kinetic energy, and the Wigner solid. The text provides a new and comprehensive review of the remarkable properties of Coulomb liquids and solids formed on the free surface of liquid helium and other interfaces. This book is intended for graduate students and researchers in the fields of quantum liquids, electronic properties of 2D systems, and solid-state physics. It includes different levels of sophistication so as to be useful for both theorists and experimentalists. The presentation is largely self-contained, and also describes some instructive examples that will be of general interest to solid-state physicists.

Dieser Titel verbindet die Festkörpertheorie mit der Quantenchemie. Neue Konzepte der Vielteilchen-Verarbeitung und Korrelations-Effekte, normale quantenchemische Verfahren mit Projektionstechniken, Greensche Funktionen und Monte-Carlo-Methoden werden erarbeitet. Anwendungsbereiche der Molekültheorie, von Halbleitern, supraleitender high-Tc-Materialien, etc., werden vorgestellt.

About two years ago, while studying the dynamic properties of Fe (CO)IJ ,we realized that there 3 was virtually no single source of infonnation on the structural dynamics of materials. The time domain of different dynamic structural processes covers many orders of magnitude and may be in vestigated by numerous, vastly different, experimental techniques. Indeed, the subject seemed ap propriate for a NATO Advanced Study Institute at which we could bring together chemists, physicists, metallurgists, and bioscientists using the various techniques for the study of sundry time sensitive materials. The actual Advanced Study Institute, which met in II Ciocco, Italy, from 14 to 26 June 1987, was, in fact, a dynamic experience for those of us involved. Now we have come to the final phase, the communication of the results of this Advanced Study Institute to the general scientific community. In so doing, we hope to provide in one place a convenient source of infor mation on dynamics at the surface and within a solid state material. The beautiful mountainous setting of Tuscany and especially the idyllic surroundings of II Ciocco provided an ideal venue for the Advanced Study Institute. Our field trip to Pisa linked our topic to the history of time measurement through a visit to the Pisa cathedral where, presumably, Galileo first conceived the isochronism of the simple pendulum and its use in time measurement.

This book, based on the analogy between contact mechanics and fracture mechanics proposed by the author twenty years ago, starts with a treatment of the surface energy and tension of solids and surface thermodynamics. The essential concepts of fracture mechanics are presented with emphasis on the thermodynamic aspects. Readers will find complete analytical results and detailed calculations for cracks submitted to pressure distributions and the Dugdale model. Contact mechanics and the contact and adherence of rough solids are also covered.

This book provides an overview of the current of the state of the art in the multiscale mechanics of solids and structures. It comprehensively discusses new materials, including theoretical and experimental investigations their durability and strength, as well as fractures and damage