Many countries are currently exploring the option to dispose of highly radioactive solid wastes deep underground in purpose built, engineered repositories. A number of surface and shallow repositories for less radioactive wastes are already in operation. One of the challenges facing the nuclear industry is to demonstrate confidently that a repository will contain wastes for so long that any releases that might take place in the future will pose no significant health or environmental risk. One method for building confidence in the long-term future safety of a repository is to look at the physical and chemical processes which operate in natural and archaeological systems, and to draw appropriate parallels with the repository. For example, to understand why some uranium orebodies have remained isolated underground for billions of years. Such studies are called 'natural analogues'. This book investigates the concept of geological disposal and examines the wide range of natural analogues which have been studied. Lessons learnt from studies of archaeological and natural systems can be used to improve our capabilities for assessing the future safety of a radioactive waste repository.

The perception of radioactive waste as a major problem for the industrial world has developed only recently. Four decades ago the disposal of such waste was regarded as a relatively minor matter. Those were the heady days when nuclear fission seemed the answer to the world's energy needs: the two wartime bombs had demonstrated its awesome power, and now it was to be harnessed for the production of electricity, the excavation of canals, even the running of cars and airplanes. In all applications of fission some waste containing radioactive elements would be generated of course, but it seemed only a trivial annoyance, a problem whose solution could be deferred until the more exciting challenges of constructing reactors and devising more efficient weapons had been mastered. So waste accumulated, some in tanks and some buried in shallow trenches. These were recognized as only temporary, makeshift measures, because it was known that the debris would be hazardous to its surroundings for many thousands of years and hence that more permanent disposal would someday be needed. The difficulty of accomplishing this more lasting disposal only gradually became apparent. The difficulty has been compounded by uncertainty about the physiological effects oflow-Ievel radiation, by the inadequacy of detailed knowledge about the behavior of engineered and geologic materials over long periods under unusual conditions, and by the sensitization of popular fears about radiation in all its forms following widely publicized reactor accidents and leaks from waste storage sites.

The first purpose of this book is to provide a comprehensive review of the state of development of natural analogue studies with emphasis on those studies which are relevant to the following repository designs: Nagra (Switzerland) disposal concepts for high-level waste/low and intermediate-level waste; SKB (Sweden) disposal concepts for spent fuel/low and intermediate-level waste; and Nirex (UK) disposal concept for low and intermediate-level waste.The book's second aim is to discuss the expanding application of natural analogues for non-performance assessment purposes, especially their potential for presenting the concept of geological disposal to various interested audiences in a coherent, understandable and scientifically legitimate manner.Much of the discussion of the book is relevant to concepts for geological disposal of radioactive wastes by other countries, and is concerned only with those physico-chemical processes which control the release of radionuclides from the near-field, and their subsequent retardation and transport in the geosphere.

Geological Repository Systems for Safe Disposal of Spent Nuclear Fuels and Radioactive Waste, Second Edition, critically reviews state-of-the-art technologies and scientific methods relating to the implementation of the most effective approaches to the long-term, safe disposition of nuclear waste, also discussing regulatory developments and social engagement approaches as major themes. Chapters in Part One introduce the topic of geological disposal, providing an overview of near-surface, intermediate depth, and deep borehole disposal, spanning low-, medium- and high-level wastes. Part Two addresses the different types of repository systems – crystalline, clay, and salt, also discussing methods of site surveying and construction. The critical safety issue of engineered barrier systems is the focus of Part Three, with coverage ranging from nuclear waste canisters, to buffer and backfill materials. Lastly, Parts Four and Five focus on safety, security, and acceptability, concentrating on repository performance assessment, then radiation protection, environmental monitoring, and social engagement. Comprehensively revised, updated, and expanded with 25% new material on topics of current importance, this is the standard reference for all nuclear waste management and geological repository professionals and researchers. - Contains 25% more material on topics of current importance in this new, comprehensive edition - Fully updated coverage of both near-surface/intermediate depth, and deep borehole disposal in one convenient volume - Goes beyond the scientific and technical aspects of disposal to include the political, regulatory, and societal issues involved, all from an international perspective

There is an extremely voluminous literature on radioactive waste and its disposal, much in the form of government-sponsored research reports. To wade through this mountain of literature is indeed a tedious task, and it is safe to speculate that very few, if any, individuals have the time to examine each report that has been issued during the preceding ten years. This book attempts to summarize much of this literature. Further, many workers in the geosciences have not received training in the nuclear sciences, and many nuclear scientists could be better versed in geology. In this book an attempt is made to cover some background material on radioactive wastes and geotoxicity that may not be an integral part of a geologist's training, and background material on geology and geochemistry for the nuclear scientist. The geochemical material is designed for both the geoscientist and the nuclear scientist. There is no specific level for this book. Certainly, it should be useful to advanced undergraduates and graduates studying geology and nuclear science. It does not pretend to cover a tremendous amount of detail in all subjects, yet the references cited provide the necessary source materials for follow-up study. It is my intention that the reader of this book will have a better, broader understanding of the geochemical aspects of radioactive waste disposal than is otherwise available in anyone source.

Safety and environmental impact is of uppermost concern when dealing with the movement and storage of nuclear waste. The 20 chapters in 'An Introduction to Nuclear Waste Immobilisation' cover all important aspects of immobilisation, from nuclear decay, to regulations, to new technologies and methods. Significant focus is given to the analysis of the various matrices used in transport: cement, bitumen and glass, with the greatest attention being given to glass. The last chapter concentrates on the performance assessment of each matrix, and on new developments of ceramics and glass composite materials, thermochemical methods and in-situ metal matrix immobilisation. The book thoroughly covers all issues surrounding nuclear waste: from where to locate nuclear waste in the environment, through nuclear waste generation and sources, treatment schemes and technologies, immobilisation technologies and waste forms, disposal and long term behaviour. Particular attention is paid to internationally approved and worldwide-applied approaches and technologies.* Each chapter focuses on a different matrix used in nuclear waste immobilisation: Cement, bitumen, glass and new materials.* Keeps the most important issues surrounding nuclear waste – such as treatment schemes and technologies, and disposal - at the forefront.

Drawing on the authors' extensive experience in the processing and disposal of waste, An Introduction to Nuclear Waste Immobilisation, Second Edition examines the gamut of nuclear waste issues from the natural level of radionuclides in the environment to geological disposal of waste-forms and their long-term behavior. It covers all-important aspects of processing and immobilization, including nuclear decay, regulations, new technologies and methods. Significant focus is given to the analysis of the various matrices used, especially cement and glass, with further discussion of other matrices such as bitumen. The final chapter concentrates on the performance assessment of immobilizing materials and safety of disposal, providing a full range of the resources needed to understand and correctly immobilize nuclear waste.