The first part of this book reviews the basics of atmospheric chemistry, radiation transport, and optical spectroscopy before detailing the principles underlying DOAS. The second part describes the design and application of DOAS instruments as well as the evaluation and interpretation of spectra. The recent expansion of DOAS application to the imaging of trace gas distributions by ground, aircraft, and satellite-based instruments is also covered.

The field of optical and laser remote sensing has grown rapidly in recent years. This dynamic growth has been stimulated not only by technological advances in lasers, detectors, and optical system design, but also by the potential application of remote sensing systems to a wide variety of atmo spheric measurements. Optical and laser remote sensing can allow single ended measurement capability not offered by conventional point-detection techniques. While many past measurements have been associated with labo ratory research. practical systems have recently been developed which are capable of remotely detecting. measuring. and tracking a wide range of molecular and atomic species in the atmosphere with concentrations of parts per billion and at ranges over 100 km. This book is a compilation of papers which represent an overview of the present state of development of optical and laser remote sensing tech nology. The subjects covered include both passive and active remote sen sing techniques in the UV, visible, and IR spectral regions. related laser and detector technology, and atmospheric propagation and system analysis considerations. While the papers do not constitute an exhaustive treat ment of the excellent research being conducted in this field, they are representative of the wide diversity of present efforts. It is hoped that the reader will gain a general understanding of the current research in optical and laser remote sensing as well as an overview of current systems development.

Almost all of the breakthroughs in understanding the atmospherehave been initiated by field observations, using a range ofinstrumental techniques. Developing or deploying instruments tomake further observations demands a thorough understanding of thechemical and spectroscopic principles on which such measurementsdepend. Written as an authoritative guide to the techniques of instrumentalmeasurement for the atmospheric scientist, research student orundergraduate, Analytical Techniques for Atmospheric Measurementfocuses on the instruments used to make real time measurements ofatmospheric gas and aerosol composition. Topics covered include howthey work, their strengths and weaknesses for a particular task,the platforms on which they have been deployed and how they arecalibrated. It explains the fundamental principles upon which theinstrumental techniques are based (ie what property of a moleculecan be exploited to enable its detection), what limits instrumentalsensitivity and accuracy, and the information that can be gainedfrom their use.

Leading experts discuss the characteristics, advantages, limitations and future aspects of modern spectroscopic techniques for environmental analysis. Demonstrates how these methods can be applied to trace gas detection and assessment. Concentrates on the latest techniques--both laser and non-laser based--which offer advantages for air pollution and gas monitoring as opposed to more conventional methods. Numerous examples of applications illustrate the potential of the techniques backed up by cutting-edge information and representative data.

Continuous Emission Monitoring, Second Edition is the most comprehensive source of information on the latest technical and regulatory issues that are affecting the design, application, and certification of CEM systems. It provides a thorough discussion of CEM systems, how they work, their advantages and drawbacks, and the regulatory requirements that govern their operation. Equally suitable for an environmental engineer in a plant or control agency, a CEM user, or an inspector/auditor, this book makes it possible to assess the operating characteristics of commercial systems and to evaluate them for a specific application. Thoroughly referenced, with numerous illustrations, it features: * A comprehensive review of regulations, with clear information on changes * New measurement techniques, designs for "smart" analyzers, and advanced monitoring approaches * New chapters on flow rate and continuous particulate monitors * Techniques for recordkeeping, generating reports, and using data acquisition and handling systems * Quality assurance/quality control programs CEMs are becoming a fact of life in regulatory programs throughout the United States, Canada, Europe, and Asia. Environmental professionals as well as vendors and manufacturers will turn to Continuous Emission Monitoring for clear, up-to-date information on the technical and regulatory issues shaping this dynamic field.

The revised 2nd edition of this practical book provides an expanded treatment and comparison of techniques used in advanced optical measurements, guiding its reader from fundamental radiometric and photometric concepts to the state-of-the-art in highly sensitive measurements of optical losses and in spectroscopic detection using coherent laser light and spontaneous radiation. The book describes and compares a broad array of high-sensitivity methods and techniques – from interferometric and/or calorimetric, acousto-optic and resonator or polarization to wavelength- and frequency-modulation, phase-shift and decay time studies, and direct-loss measurements for free-space, fiber- or waveguide-based systems and devices. Updated throughout, the new edition describes novel trends in spectral interferometry, frequency-comb and laser-excitation spectroscopy, reflected in the developments of Raman, Brillouin and FTIR (Fourier Transform Infra-Red) techniques for biomedical research, biotech sensing and detection. It also covers broad practical implementations of time- and frequency-domain terahertz spectroscopy measurements. This book reviews the physical concepts of radiation transfer, providing a quantitative foundation for the means of measurements of optical losses, which affect propagation and distribution of light waves in various media and in diverse optical systems and components. It focuses on the application of optical methods and procedures for the evaluation of transparent, reflecting, scattering, absorbing, and aggregated objects, and for determining the power and energy parameters of radiation and color properties of light. This updated new edition will serve as an up-to-date reference source and practical guide for those using photometric and radiometric techniques.