These proceedings are the result of the third international workshop on Desorption Induced by Electronic Transitions, DIET III, which took place on Shelter Island, NY, May. 20-22, 1987. The work contained in this volume is an excellent summary of the current status of the field and should be a valuable reference text for both "seasoned" researchers and newcomers in the field of DIET. Based on the success of the meeting it seems clear that interest and enthusiasm in the field is strong. It is also apparent, from the many lively discussions during the meeting, that many unanswered questions (and controversies) remain to be solved. It was particularly pleasing to see many new participants from new and rapidly advancing fields, ranging from gas phase dynamics to semiconductor processing. The resulting cross-fertilization from these separate but related fields is playing an important role in helping us understand desorption processes at solid surfaces. In general, the topics covered during the course of the workshop over lapped those of both DIET I and DIET II. However, clear advances have been made and in general there is a much more sophisticated understand ing of the physics and chemistry of stimulated desorption. Of particular note in this regard is the gas phase research highlighted in this workshop by the work of Nenner et al. , where new results indicate that in the gas phase, photodissociation can precede or compete strongly with autoion ization and other electronic relaxation pathways.

This volume in the Springer Series on Surface Sciences presents a recent account of advances in the ever-broadening field of electron-and photon-stimulated sur face processes. As in previous volumes, these advances are presented as the proceedings of the International Workshop on Desorption Induced by Electronic Transitions; the fifth workshop (DIET V) was held in Taos, New Mexico, April 1-4, 1992. It will be abundantly clear to the reader that "DIET" is not restricted to desorption, but has for several years included photochemistry, non-thermal surface modification, exciton self-trapping, and many other phenomena that are induced by electron or photon bombardment. However, most stimulated surface processes do share a common physics: initial electronic excitation, localization of the excitation, and conversion of electronic energy into nuclear kinetic energy. It is the rich variation of this theme which makes the field so interesting and fruitful. We have divided the book into eleven parts in order to emphasize the wide range of materials that are examined and to highlight recent experimental and theoretical advances. Naturally, there is considerable overlap between sections, and many papers would be appropriate in more than one part. Part I focuses on perhaps the most active area in the field today: electron attachment. Here the detection and characterization of negative ions formed by attachment of elec trons supplied externally from the vacuum are discussed. In addition, the first observations of negative ions formed by substrate photoelectrons are presented.

The second workshop on Desorption Induced by Electronic Transitions (DIET II) took place October 15-17, 1984, in SchloB Elmau, Bavaria. DIET II, fol lowing the great success of DIET I (edited by N. H. Tolk, M. M. Traum, J. C. Tully, T. E. Madey and published in Springer Ser. Chem. Phys. , Vol. 24), again brought together over 60 workers in this exciting field. The "hard co re of experts" was essentially the same as in DIET I but the general overlap of participants between the two meetings was small. While DIET I had the function of an exposition of the status of the field DIET II focussed more on new developments. The main emphasis was again on the microscopic under standing of DIET but a number of side aspects and the application of DIET ideas to other fields such as sputtering, laser-induced desorption, fractu re, erosion, etc. were considered, too. New mechanisms and new refined expe rimental techniques were proposed and discussed at the meeting critically but with great enthusiasm. In addition to the talks, there was a continuous poster exhibition which also stimulated extended and excited discussions. This book is a collection of papers summarizing the talks and posters presented at the meeting.

This book is the latest to appear in a series documenting the progress of this exciting field in surface science. It presents recent results and reviews of the rapidly growing field of interaction of particles and lasers with solid surfaces leading to excitation, ionisation and desorption. The main emphasis is on the microscopic understanding of DIET, especially electron- and ion-induced desorption of adsorbed layers, emission from insulators, laser-induced desorption and ablation, photophysics and photochemistry. Applications ranging from laser ablation for medical purposes to DIET in high-temperature superconductors are also described.

The Workshop on Desorption Induced by Electronic Transitions (DIET) took place May 12-14, 1982, in Williamsburg, Virginia. The meeting brought together, for the first time, most of the leading workers in the fields of electron and photon stimulated desorption from surfaces, as well as many workers in related fields, including sputtering, gas-phase photodissociation and solid-state theory. The emphasis of the workshop was on the microscopic mechanism of stimu lated desorption. Many possible mechanisms have been proposed, and a few new ones emerged at the meeting. Though no consensus was reached, many views were espoused and criticized, frequently with considerable enthusiasm. The result was an appraisal of our current understanding of DIET, and a focus on the experimental and theoretical efforts most likely to lead to new insights. This volume is an attempt to record the information exchanged in this very successful workshop and, perhaps, convey some of the excitement of the field of DIET. The book is a collection of papers written by participants in the DIET workshop, including in addition a contribution from Dietrich Menzel, who was unable to attend. Thus, this book represents a complete statement of the state of the art of experimental and theoretical studies of DIET and related phenomena. More importantly, it addresses the interesting unsolved problems, and suggests strategies for unraveling them. We acknowledge the assistance given by the other members of the organizing committee, A. E. de Vries, R. Gomer, M. L. Knotek, D. Menzel and D. P.

Adsorption on Ordered Surfaces of Ionic Solids and Thin Films introduces to a new and topical field of surface science for which rather little experience is available at present. It reviews the recent results of the employed analytical methods comprising all modern surface techniques including scanning tunneling microscopy and various kinds of electron spectroscopies. The present status of this new, clearly defined field of surface science is nearly completely overviewed by contributions from most of the research groups active in this field. The book is meant as a basis for the expected rapid development in this area with applications in catalysis, thin-film and semiconductor technology, sensors, electrochemistry, controlled preparation of ultrathin epitaxial surfaces, and interfaces of insultors as well as future molecular electronics.

Crystal growth far from thermodynamic equilibrium is nothing but homoepitaxy - thin film growth on a crystalline substrate of the same material. Because of the absence of misfit effects, homoepitaxy is an ideal playground to study growth kinetics in its pure form. Despite its conceptual simplicity, homoepitaxy gives rise to a wide range of patterns. This book explains the formation of such patterns in terms of elementary atomic processes, using the well-studied Pt/Pt(111) system as a reference point and a large number of Scanning Tunneling Microscopy images for visualization. Topics include surface diffusion, nucleation theory, island shapes, mound formation and coarsening, and layer-by-layer growth. A separate chapter is dedicated to describing the main experimental and theoretical methods.