The increasing production of industrial goods, heat, and energy, as well as traffic, has led to the release of considerable amounts of toxic trace metals to the atmosphere. The result is elevated concentrations of toxic metals in local populations and eco systems. Recently the problem of atmospheric long-range transport of trace metals has also been recognized. Significant amounts of these pollutants are disposed and deposited both on regional and global scales. In the atmosphere they may influence the chemical reactions. Of particular interest is their catalytic effect on the oxidation prosesses taking place in water droplets or on the surface of wet particles (e. g. the oxidation of sulphur dioxide to sulphate), however, the main environmental impact starts when the atmospheric trace metals are deposited on ground and vegetation and subsequently brought into the water circulation. During the later years significant progress has been made in the development of equipment to reduce and control the atmospheric emissions of toxic trace metals. This particularly applies to electrostatic precipitators and wet scrubbers for the collection of fine particles. The main objective of the workshop was to survey present knowledge concerning the sources, atmospheric fluxes, sinks and chemical impact of the atmospheric trace metals, and to review the developments of emission control equipment and the perspectives to reduce the potential risks from toxic metals. During the first two days of the meeting, 15 invited review papers were presented.

Under current U.S. EPA guidelines, particularly the Clean Air Act Amendments, stack gasses and the solid products of combustion require specialized treatment for removal of trace metals. This book presents a data-intensive assessment of the fate of trace metals during combustion. The data are derived from actual operating combustion systems, and the text emphasizes case studies that document trace metal fate control. Issues covered include metal volatility, metal reactions, and trace metal management through the enhancement or inhibition of specific chemical reactions.

Table of contents

This book provides a detailed examination of the concentration, form and cycling of trace metals and metalloids through the aquatic biosphere, and has sections dealing with the atmosphere, the ocean, lakes and rivers. It discusses exchanges at the water interface (air/water and sediment/water) and the major drivers of the cycling, concentration and form of trace metals in aquatic systems. The initial chapters focus on the fundamental principles and modelling approaches needed to understand metal concentration, speciation and fate in the aquatic environment, while the later chapters focus on specific environments, with case studies and research highlights. Specific examples deal with metals that are of particular scientific interest, such as mercury, iron, arsenic and zinc, and the book deals with both pollutant and required (nutrient) metals and metalloids. The underlying chemical principles controlling toxicity and bioavailability of these elements to microorganisms and to the aquatic food chain are also discussed. Readership: Graduate students studying environmental chemistry and related topics, as well as scientists and managers interested in the cycling of trace substances in aqueous systems Additional resources for this book can be found at: www.wiley.com/go/mason/tracemetals.