From the authors' preface: "As we enter the era of intelligent materials and embark upon a new approach to material design, synthesis, and system integration, certain groups of materials will emerge as champions." Standing high among these champions are conductive electroactive polymers (CEPs), which appear destined to play a central ro

1. Introduction; 2. Assembly of Polypyrroles; 3. Properties of polypyrroles; 4. Polyanilines and polythiophenes; 5. Integrated structures.

Rapid advances in synthetic polymer science and nanotechnology have revealed new avenues of development in conductive electroactive polymers that take greater advantage of this versatile class of materials' unique properties. This third edition of Conductive Electroactive Polymers: Intelligent Polymer Systems continues to provide an in-depth unders

Electroactive polymers have been the object of increasing academic and industrial interest and in the past ten to fifteen years substantial progress has been achieved in the development and the characterization of this important new class of conducting materials. These materials are usually classified in two large groups, according to the mode of their electric transport. One group includes polymers having transport almost exclusively of the ionic type and they are often called 'polymer electrolytes' or, in a broader way, 'polymer ionics'. The other group includes polymeric materials where the transport mechanism is mainly electronic in nature and which are commonly termed 'conducting polymers'. Ionically conducting polymers or polymer ionics may be typically described as polar macromolecular solids in which one or more of a wide range of salts has been dissolved. The most classic example is the combina tion of poly(ethylene oxide), PEO, and lithium salts, LiX. These PEO-LiX polymer ionics were first described and proposed for applications just over ten years ago. The practical relevance of these new materials was im mediately recognized and in the course of a few years the field expanded tremendously with the involvement of many academic and industrial lab oratories. Following this diversified research activity, the ionic transport mechanism in polymer ionics was soon established and this has led to the development of new host polymers of various types, new salts and advanced polymer architectures which have enabled room temperature conductivity to be raised by several orders of magnitude.

From the authors' preface: "As we enter the era of intelligent materials and embark upon a new approach to material design, synthesis, and system integration, certain groups of materials will emerge as champions." Standing high among these champions are conductive electroactive polymers (CEPs), which appear destined to play a central role in the development of intelligent materials. Although recent advances have enabled the design and assembly of polymers from the molecular level, creating sophisticated structures requires a solid understanding of the structure-property relationships. Building on the standard-setting first edition, Conductive Electroactive Polymers: Intelligent Materials Systems, Second Edition provides a thorough, up-to-date introduction to conductive electroactive polymers. The authors discuss the parameters that affect the formation of important CEPs, including polypyrroles, polyanilines, and polythiophenes. They show how to use these parameters to manipulate the properties of the polymers, and they clarify the chemical and energy parameters that determine the structure and its properties. New in this edition are more details on polythiphene and polyaniline systems, an update on progress in polypyrroles, and reports on recent advances in CEP processing techniques and device fabrication. As the use of intelligent materials grows, it becomes increasingly important for scientists and engineers in fields ranging from materials science to electronics and biomedicine to understand the properties and potential of CEPs. This book is an outstanding introduction to conducting polymers and a valuable reference that brings you quickly up to date on recent developments.

This book covers the fundamental properties, modeling, and demonstration of Electroactive polymers in robotic applications. It particularly details artificial muscles and sensors. In addition, the book discusses the properties and uses in robotics applications of ionic polymer–metal composite actuators and dielectric elastomers.

Rapid advances in synthetic polymer science and nanotechnology have revealed new avenues of development in conductive electroactive polymers that take greater advantage of this versatile class of materials’ unique properties. This third edition of Conductive Electroactive Polymers: Intelligent Polymer Systems continues to provide an in-depth understanding of how to engineer dynamic properties in inherently conducting polymers from the molecular level. New to the third edition: Biomedical, MEMS, and electronic textile applications The synthesis and fabrication of nanocomponents and nanostructures The energy role of nanotechnology in improving the performance of conducting materials in devices Electrochemical Raman, electrochemical ESR, and scanning vibrating reference electrode studies After establishing the basic principles of polymer chemistry, the book pinpoints the dynamic properties of the more useful conducting polymers, such as polupyrroles, polythiophenes, and polyanilines. It then demonstrates how the control of these properties enables cutting-edge applications in nano, biomedicine, and MEMS as well as sensors and artificial muscles. Subsequent chapters discuss the effect of nanodimensional control on the resultant properties. Updated to reflect substantial developments and advances that have occurred in the past few years, this third edition of Conductive Electroactive Polymers unlocks a world of potential for integrating and interfacing conductive polymers.