The use of Compound-specific Stable Isotope Analysis (CSIA) is increasing in many areas of science and technology for source allocation, authentication, and characterization of transformation reactions. Until now, there have been no textbooks available for students with an analytical chemical background or basic introductory books emphasising the instrumentation and theory. This book is the first to focus solely on stable isotope analysis of individual compounds in sometimes complex mixtures. It acts as both a lecture companion for students and a consultant for advanced scientists in fields including forensic and environmental science. The book starts with a brief history of the field before going on to explain stable isotopes from scratch. The different ways to express isotope abundances are introduced together with isotope effects and isotopic fractionation. A detailed account of the required technical equipment and general procedures for CSIA is provided. This includes sections on derivatization and the use of microextraction techniques in GC-IRMS. The very important topic of referencing and calibration in CSIA is clearly described. This differs from approaches used in quantitative analysis and is often difficult for the newcomer to comprehend. Examples of successful applications of CSIA in food authenticity, forensics, archaeology, doping control, environmental science, and extraterrestrial materials are included. Applications in isotope data treatment and presentation are also discussed and emphasis is placed on the general conclusions that can be drawn from the uses of CSIA. Further instrumental developments in the field are highlighted and selected experiments are introduced that may act as a basis for a short practical course at graduate level.

The 20th century has experienced environmental changes that appear to be unprecedented in their rate and magnitude during the Earth's history. For the first time, Stable Isotopes as Indicators of Ecological Change brings together a wide range of perspectives and data that speak directly to the issues of ecological change using stable isotope tracers. The information presented originates from a range of biological and geochemical sources and from research fields within biological, climatological and physical disciplines covering time-scales from days to centuries. Unlike any other reference, editors discuss where isotope data can detect, record, trace and help to interpret environmental change. - Provides researchers with groundbreaking data on how to predict the terrestrial ecosystems response to the ongoing rapid alterations - Reveals how ecosystems have responded to environmental and biotic fluctuations in the past - Includes examples from research by a wide range of biological and physical scientists who are using isotopic records to both detect and interpret environmental change

Tracking Animal Migration with Stable Isotopes provides a consolidated overview of the current knowledge of stable isotopes in terrestrial migration research questions. It offers ecologists and conservation biologists provide a practical handbook for those considering using stable isotopes in their migration research. - Presents information for readers to understand how to apply isotopic methods for tracking - Critical information on areas for future research - Practical guidelines and discussions of sample collection, sample preparation, and data analysis - Enhanced understanding of data and statistical analysis in isotope-based studies of migratory animals

This textbook provides a unique and thorough look at the application of chemical biomarkers to aquatic ecosystems. Defining a chemical biomarker as a compound that can be linked to particular sources of organic matter identified in the sediment record, the book indicates that the application of these biomarkers for an understanding of aquatic ecosystems consists of a biogeochemical approach that has been quite successful but underused. This book offers a wide-ranging guide to the broad diversity of these chemical biomarkers, is the first to be structured around the compounds themselves, and examines them in a connected and comprehensive way. This timely book is appropriate for advanced undergraduate and graduate students seeking training in this area; researchers in biochemistry, organic geochemistry, and biogeochemistry; researchers working on aspects of organic cycling in aquatic ecosystems; and paleoceanographers, petroleum geologists, and ecologists. Provides a guide to the broad diversity of chemical biomarkers in aquatic environments The first textbook to be structured around the compounds themselves Describes the structure, biochemical synthesis, analysis, and reactivity of each class of biomarkers Offers a selection of relevant applications to aquatic systems, including lakes, rivers, estuaries, oceans, and paleoenvironments Demonstrates the utility of using organic molecules as tracers of processes occurring in aquatic ecosystems, both modern and ancient

I was asked to introduce this volume by examining "why a knowledge of ecosys tem functioning can contribute to understanding species activities, dynamics, and assemblages." I have found it surprisingly difficult to address this topic. On the one hand, the answer is very simple and general: because all species live in ecosystems, they are part of and dependent on ecosystem processes. It is impossible to understand the abundance and distribution of populations and the species diversity and composition of communities without a knowledge of their abiotic and biotic environments and of the fluxes of energy and mat ter through the ecosystems of which they are a part. But everyone knows this. It is what ecology is all about (e.g., Likens, 1992). It is why the discipline has retained its integrity and thrived, despite a sometimes distressing degree of bickering and chauvinism among its various subdisciplines: physiological, be havioral, population, community, and ecosystem ecology.

A solid introduction to stable isotopes that can also be used as an instructive review for more experienced researchers and professionals. The book approaches the use of isotopes from the perspective of ecological and biological research, but its concepts can be applied within other disciplines. A novel, step-by-step spreadsheet modeling approach is also presented for circulating tracers in any ecological system, including any favorite system an ecologist might dream up while sitting at a computer. The author’s humorous and lighthearted style painlessly imparts the principles of isotope ecology. The online material contains color illustrations, spreadsheet models, technical appendices, and problems and answers.

Physiological plant ecology is primarily concerned with the function and performance of plants in their environment. Within this broad focus, attempts are made on one hand to understand the underlying physiological, biochemical and molecular attributes of plants with respect to performance under the constraints imposed by the environment. On the other hand physiological ecology is also concerned with a more synthetic view which attempts to under stand the distribution and success of plants measured in terms of the factors that promote long-term survival and reproduction in the environment. These concerns are not mutually exclusive but rather represent a continuum of research approaches. Osmond et al. (1980) have elegantly pointed this out in a space-time scale showing that the concerns of physiological ecology range from biochemical and organelle-scale events with time constants of a second or minutes to succession and evolutionary-scale events involving communities and ecosystems and thousands, if not millions, of years. The focus of physiological ecology is typically at the single leaf or root system level extending up to the whole plant. The time scale is on the order of minutes to a year. The activities of individual physiological ecologists extend in one direction or the other, but few if any are directly concerned with the whole space-time scale. In their work, however, they must be cognizant both of the underlying mechanisms as well as the consequences to ecological and evolutionary processes.