Chirogenesis in Chemical Science is an exciting new book that takes readers inside the world of chirality and chirogenesis, guided by Victor Borovkov and Riina Aav, both internationally renowned experts on chirality. Chirality is a fundamental property of the universe and has significance in different organic/inorganic materials, living organisms, and human beings. The basic principle of chirality is existence of an object in two mirror image forms, which are not superimposable. This phenomenon is widely seen in various fields of knowledge including mathematics, astronomy, physics, chemistry, biology and ranging in scale from galaxies to nuclear particles.In chemical science, chirality is generally associated with a single molecule or group of molecules, which symmetry properties belonging to the Cn or Dn point groups with the simplest example of sp3 carbon atom bonded to four different substituents. The dynamic processes of chirality generation, modulation, transfer, amplification, etc. are termed chirogenesis.This is a fast-growing and interdisciplinary field of research, which is widely seen in many natural systems (such as DNA double helix, the secondary alpha-helix structure of proteins, lipid membranes, saccharides, heme proteins, and other biological molecular objects) and various artificial systems. It is of prime importance not only for fundamental science but also for a number of practical applications in such areas as pharmacology and agrochemistry, perfumery and food industry, materials and polymer sciences, enantioselective catalysis and nonlinear optics, nanoscience and nanotechnology, molecular devices and chemical sensors, and others. Therefore, understanding the mechanisms and various influencing factors is of particular significance for smart control and further effective application of chirogenesis in chemistry.

June 14-15, 2018 London, UK Key Topics : Chemistry Of Compounds, Organic Chemistry And Inorganic Chemistry, Physical And Theoretical Chemistry, Heterocyclic Chemistry, Electrochemistry, Electrolysis And Corrosion, Geochemistry, Nuclear Chemistry/Radiochemistry, Biochemistry, Pharmaceutical/Medicinal Chemistry, Polymer Chemistry, Forensic Chemistry, Environmental Chemistry, Bio Based Chemistry, Analytical Chemistry, Multi-Scale And/Or Multi-Disciplinary Approach To Process-Product Innovation, Sustainable Process-Product Development Through Green Chemistry, ,

Selected, peer reviewed papers from the 2013 International Conference on Materials Science and Chemical Engineering (MSCE 2013), February 20-21, 2013, Singapore, Singapore

Comprehensive resource illustrating the latest stage and development of chiral luminescence in science and technology, from fundamentals to applications Chiral Luminescence imparts a comprehensive understanding for chiral materials bearing circularly polarized luminescence (CPL) functions, including molecules, oligomers, polymers, chiral metal organic complexes, and chiral biochemical materials, with guidance on how to promote and control this kind of luminescence towards the development of advanced photonic materials and devices such as chiroptical and electronic devices, next-generation displays, and others. The book covers detailed information on the molecular design, synthesis, and polymerization methods of chiral luminescent materials, the evaluation of chiroptical properties represented by CPL, novel spectroscopic instruments and techniques, the fabrication of chiral luminescent devices such CPL-OLED, a theoretical evaluation, and potential applications. With insight from leading academics and industrial researchers in the field, Chiral Luminescence includes information on: Optical resolution and chiroptical properties of partially overlapping carbazolophanes and developments in CPL research using cyclodextrins Synthesis and chiroptical properties of helical, conjugated polymers and twisted molecules, and chiroptical and magnetooptical properties of porphyrin compounds Principles of CPL measurement systems and advances in measurement methods, and intense and sign-invertible CPL Development of organic light-emitting diodes using aggregation-induced enhanced CPL perylene diimides Binding constants as fundamental physical properties for quantitative treatments of sensing processes in supramolecular systems Providing far-reaching coverage of chiral luminescence and its many applications, Chiral Luminescence is a must-read resource for a variety of chemists and engineers who wish to understand the state-of-the-art development in this optical science.

Supramolecular chemistry deals with the organisation of molecules into defined assemblies using non-covalent interactions, including weaker and reversible interactions such as hydrogen bonds, and metal-ligand interactions. The aspect of stereochemistry within such chemical architectures, and in particular chirality, is of special interest as it impacts on considerations of molecular recognition, the development of functional materials, the vexed question of homochirality, nanoscale effects of interactions at interfaces, biocatalysis and enzymatic catalysis, and applications in organic synthesis. Chirality in Supramolecular Assemblies addresses many of these aspects, presenting a broad overview of this important and rapidly developing interdisciplinary field. Topics covered include: Origins of molecular and topological chirality Homochirogenesis Chirality in crystallinity Host-guest behavior Chiral influences in functional materials Chirality in network solids and coordination solids Aspects of chirality at interfaces Chirality in organic assemblies Chirality related to biocatalysis and enzymes in organic synthesis. This book is a valuable reference for researchers in the molecular sciences, materials science and biological science working with chiral supramolecular systems. It provides summaries and special insights by acknowledged international experts in the various fields.

Fundamentals of Supramolecular Chirality is a critical description of the start and advancement of supramolecular chirality. This book focuses on the noncovalent approach with some supplementary examples of covalent supramolecular chirality.This contribution to supramolecular chirality is not intended to be a mere catalogue and description of the work done. It also traces a philosophical path following the development and possible perspectives of this topic, providing not a review but a critical examination of the field.