This revised edition of a best-selling book continues to provide a basis for the identification and evaluation of chemical reaction hazards for chemists, engineers, plant personnel, and students. Before undertaking the design of a chemical manufacturing process it is vital that the chemical reactions involved be fully understood, potential hazards assessed, and safety measures planned. Chemical Reaction Hazards aims to help the people responsible for this design and operation to meet the general duties of safety. Two major additions to this revised book are the appendices. One of these describes 100 incidents, illustrating their cause and indicating consequences if appropriate procedures within this guide are not followed. The second provides a practical example of a typical chemical reaction hazard assessment, from consideration of the process description, through experimental testing to the specification of safety measures.

Summarizes core information for quick reference in the workplace, using tables and checklists wherever possible. Essential reading for safety officers, company managers, engineers, transport personnel, waste disposal personnel, environmental health officers, trainees on industrial training courses and engineering students. This book provides concise and clear explanation and look-up data on properties, exposure limits, flashpoints, monitoring techniques, personal protection and a host of other parameters and requirements relating to compliance with designated safe practice, control of hazards to people's health and limitation of impact on the environment. The book caters for the multitude of companies, officials and public and private employees who must comply with the regulations governing the use, storage, handling, transport and disposal of hazardous substances. Reference is made throughout to source documents and standards, and a Bibliography provides guidance to sources of wider ranging and more specialized information. Dr Phillip Carson is Safety Liaison and QA Manager at the Unilever Research Laboratory at Port Sunlight. He is a member of the Institution of Occupational Safety and Health, of the Institution of Chemical Engineers' Loss Prevention Panel and of the Chemical Industries Association's `Exposure Limits Task Force' and `Health Advisory Group'. Dr Clive Mumford is a Senior Lecturer in Chemical Engineering at the University of Aston and a consultant. He lectures on several courses of the Certificate and Diploma of the National Examining Board in Occupational Safety and Health. [Given 5 star rating] - Occupational Safety & Health, July 1994 - Loss Prevention Bulletin, April 1994 - Journal of Hazardous Materials, November 1994 - Process Safety & Environmental Prot., November 1994

The handbook provides ready information on the fire and chemical reactivity of commonly used chemicals. Its purpose is to provide basic information important to the safe handling of chemicals and to help provide guidance in responding to a hazardous materials incident, in particular, incidents involving reactive chemicals and materials posing fire and explosion hazards. The volume has been written for chemical handling specialists, first responders to hazardous materials incidents, and firefighters. The basic definition used for a hazard materials incident is any situation that may potentially lead to catastrophic fire or explosion, and or human exposed to a toxic chemical. This situation may result from a spill of a hazardous material, a leak from a storage vessel or shipping container, or the mixing of incompatible chemicals whereby a chemical reaction could occur resulting in the release of energy and generation of toxic and perhaps flammable by-products. The volume provides chemical specific information, providing the reader with rigorous information on the chemical of interest.This book is a compendium of chemical specific fire and chemical reactivity data and information. More than 1,000 chemicals have been researched and organized into a reference handbook for fire specialists, chemical handling specialists, and plant safety engineers. The specific information provided for chemicals includes the flammability characteristics, recommended fire extinguishing practices, fire extinguishing agents not to be used, behavior in fires, burning characteristics, chemical reactivity with regard to water and common materials, incompatible chemical mixtures, containment and neutralization methods for spills. This reference book has been designed as a data bank for the hazardous materials handling specialist and industrial safety managers dealing with large chemical inventories. It is intended to be used by fire and loss prevention specialists and as a basis for developing procedures for safe storing and handling of chemicals. The authors have included an extensive physical properties section on chemicals, with information most pertinent to fire response situations.

There is always potential for hazards during chemical reactions that can lead to accidents resulting in loss of time, equipment, products and harm to people. The hazards may result from uncontrolled exothermic reactions or secondary exothermic reactions such as decomposition of a reactant, reagent or product. Hazards may also occur from impurities or metal residues that can catalyze undesired exothermic reactions or decompositions. Many organic reactants, reagents, products as well as solvents have varying degrees of toxic effects and/or fire hazard if not handled properly. Improperly treated waste may also be a source of many hazards. Managing all these hazards effectively is very important for carrying out reactions safely, particularly on large scale. To achieve this goal, chemists and engineers need a clear understanding of the thermal characteristics of chemical reactions derived from accurate quantitative measurements and clear scientific knowledge of reaction mechanisms. They also need to build an expertise on handling toxic and flammable materials and proper procedures to waste treatment and disposal. To address these objectives, this book covers many topics on management of potential hazards in the chemical and pharmaceutical industries. The topics range from classical batch reactions to the latest innovative applications of continuous processes and flow chemistry. The applications range in scale from bench to manufacturing. The book contains 16 chapters on different aspects of managing chemical reaction hazards contributed by a group of internationally renowned leading chemical safety and hazard management experts. Their contributions make this book a valuable addition to the scientific literature

Prudent Practices in the Laboratory-the book that has served for decades as the standard for chemical laboratory safety practice-now features updates and new topics. This revised edition has an expanded chapter on chemical management and delves into new areas, such as nanotechnology, laboratory security, and emergency planning. Developed by experts from academia and industry, with specialties in such areas as chemical sciences, pollution prevention, and laboratory safety, Prudent Practices in the Laboratory provides guidance on planning procedures for the handling, storage, and disposal of chemicals. The book offers prudent practices designed to promote safety and includes practical information on assessing hazards, managing chemicals, disposing of wastes, and more. Prudent Practices in the Laboratory will continue to serve as the leading source of chemical safety guidelines for people working with laboratory chemicals: research chemists, technicians, safety officers, educators, and students.

In its recent investigation of chemical reactivity accidents, the US Chemical Safety Board noted a gap in technical guidance and regulatory coverage. This volume closes the gap in technical guidance, helping small and large companies alike identify, address, and manage chemical reactivity hazards. It guides the reader through an analysis of the potential for chemical reactivity accidents to help prevent fires, explosions, toxic chemical releases or chemical spills. This volume is applicable to processes at any scale and is particularly useful for chemists, safety managers, and engineers involved in scale-up. An enclosed CD-ROM provides portable checklists, analysis tools, and a list of additional references. Note: CD-ROM/DVD and other supplementary materials are not included as part of eBook file.

Drawn from international sources, this book provides principles and strategies for the evaluation of chemical reactions, and for using this information in process design and management. A useful resource for engineers who design, start-up, operate, and manage chemical and petrochemical plants, the book places special emphasis on the use of state-of-the-art technology in theory, testing methods, and applications in design and operations.