This book is a beginners introduction to chemical thermodynamics for engineers. In the textbook efforts have been made to visualize as clearly as possible the main concepts of thermodynamic quantities such as enthalpy and entropy, thus making them more perceivable. Furthermore, intricate formulae in thermodynamics have been discussed as functionally unified sets of formulae to understand their meaning rather than to mathematically derive them in detail. In this textbook, the affinity of irreversible processes, defined by the second law of thermodynamics, has been treated as the main subject, rather than the equilibrium of chemical reactions. The concept of affinity is applicable in general not only to the processes of chemical reactions but also to all kinds of irreversible processes. This textbook also includes electrochemical thermodynamics in which, instead of the classical phenomenological approach, molecular science provides an advanced understanding of the reactions of charged particles such as ions and electrons at the electrodes. Recently, engineering thermodynamics has introduced a new thermodynamic potential called exergy, which essentially is related to the concept of the affinity of irreversible processes. This textbook discusses the relation between exergy and affinity and explains the exergy balance diagram and exergy vector diagram applicable to exergy analyses in chemical manufacturing processes. This textbook is written in the hope that the readers understand in a broad way the fundamental concepts of energy and exergy from chemical thermodynamics in practical applications. Finishing this book, the readers may easily step forward further into an advanced text of their specified line. - Visualizes the main concepts of thermodynamics to show the meaning of the quantities and formulae. - Focuses mainly on the affinity of irreversible processes and the related concept of exergy. - Provides an advanced understanding of electrochemical thermodynamics.

Exergy, Second Edition deals with exergy and its applications to various energy systems and applications as a potential tool for design, analysis and optimization, and its role in minimizing and/or eliminating environmental impacts and providing sustainable development. In this regard, several key topics ranging from the basics of the thermodynamic concepts to advanced exergy analysis techniques in a wide range of applications are covered as outlined in the contents. Offers comprehensive coverage of exergy and its applications, along with the most up-to-date information in the area with recent developments Connects exergy with three essential areas in terms of energy, environment and sustainable development Provides a number of illustrative examples, practical applications, and case studies Written in an easy-to-follow style, starting from the basics to advanced systems

Discover a straightforward and holistic look at energy conversion and conservation processes using the exergy concept with this thorough text. Explains the fundamental energy conversion processes in numerous diverse systems, ranging from jet engines and nuclear reactors to human bodies. Provides examples for applications to practical energy conversion processes and systems that use our naturally occurring energy resources, such as fossil fuels, solar energy, wind, geothermal, and nuclear fuels. With more than one-hundred diverse cases and solved examples, readers will be able to perform optimizations for a cleaner environment, a sustainable energy future, and affordable energy generation. An essential tool for practicing scientists and engineers who work or do research in the area of energy and exergy, as well as graduate students and faculty in chemical engineering, mechanical engineering and physics.

In addition to the exergy analysis of thermal processes, e.g. heat engines and commercial power stations, for which the methods described have been long established, the book considers the chemical and metallurgical process industries. Charts and tables are provided for the determination of the exergy of many typical substances. Examples are drawn from the fields of thermal, chemical and metallurgical engineering and the exergetic efficiency of typical processes is calculated. The book also discusses the application of the exergy concept to the problem of the economical optimization of complex plants and the implications to the environment of pollution due to external exergy losses. An Instructor's Manual is available which contains outline solutions to the problems listed at the end of each chapter.

The exergy method makes it possible to detect and quantify the possibilities of improving thermal and chemical processes and systems. The introduction of the concept thermo-ecological cost (cumulative consumption of non-renewable natural exergy resources) generated large application possibilities of exergy in ecology. This book contains a short presentation on the basic principles of exergy analysis and discusses new achievements in the field over the last 15 years. One of the most important issues considered by the distinguished author is the economy of non-renewable natural exergy. Previously discussed only in scientific journals, other important new problems highlighted include: calculation of the chemical exergy of all the stable chemical elements, global natural and anthropogenic exergy losses, practical guidelines for improvement of the thermodynamic imperfection of thermal processes and systems, development of the determination methods of partial exergy losses in thermal systems, evaluation of the natural mineral capital of the Earth, and the application of exergy for the determination of a pro-ecological tax.A basic knowledge of thermodynamics is assumed, and the book is therefore most appropriate for graduate students and engineers working in the field of energy and ecological management.

The main scope of this study is to emphasize exergy efficiency in all fields of industry. The chapters collected in the book are contributed by invited researchers with a long-standing experience in different research areas. I hope that the material presented here is understandable to a wide audience, not only energy engineers but also scientists from various disciplines. The book contains seven chapters in three sections: (1) "General Information about Exergy," (2) "Exergy Applications," and (3) "Thermoeconomic Analysis." This book provides detailed and up-to-date evaluations in different areas written by academics with experience in their fields. It is anticipated that this book will make a scientific contribution to exergy workers, researchers, academics, PhD students, and other scientists in both the present and the future.

Details energy and exergy efficiencies of all major aspects of bioenergy systems Covers all major bioenergy processes starting from photosynthesis and cultivation of biomass feedstocks and ending with final bioenergy products, like power, biofuels, and chemicals Each chapter includes historical developments, chemistry, major technologies, applications as well as energy, environmental and economic aspects in order to serve as an introduction to biomass and bioenergy A separate chapter introduces a beginner in easy accessible way to exergy analysis and the similarities and differences between energy and exergy efficiencies are underlined Includes case studies and illustrative examples of 1st, 2nd, and 3rd generation biofuels production, power and heat generation (thermal plants, fuel cells, boilers), and biorefineries Traditional fossil fuels-based technologies are also described in order to compare with the corresponding bioenergy systems