Earlier works on plant essential elements have revealed a series of complicated, counter-intuitive relationships among various chemical elements in different plant species, due to both unlike usage of certain elements in plants and to different carriers effecting resorption and transport. In an attempt to provide a more coherent theory behind plant mineral nutrition, this groundbreaking book adopts a very different approach from the existing literature, presenting an explanation of the essentiality of chemical elements in biological systems and the application of stoichiometric network analysis (SNA) to the biological system of elements. Starting with data from biochemical environmental analysis, and a discussion of the phenomena involved in metal ion partition and autocatalytic behaviour, conditions and criteria controlling the partition of metals into biomass are investigated. Several rules are derived and investigated in terms of their interaction both in comparisons among contemporary organisms and in terms of evolution. This allows the construction, for example of a map which directly traces the biological feature of essentiality to parameters of coordination chemistry. The book will have worldwide appeal for researchers interested in fields such as soil/plant interactions, bioinorganic chemistry, plant nutrition, phytomining, bioremediation, biogeochemistry, nutrient cycling, soil chemistry, and cellular physiology.

The book explains the principles and fundamentals of Green Analytical Chemistry (GAC) and highlights the current developments and future potential of the analytical green chemistry-oriented applications of various solutions. The book consists of sixteen chapters, including the history and milestones of GAC; issues related to teaching of green analytical chemistry and greening the university laboratories; evaluation of impact of analytical activities on the environmental and human health, direct techniques of detection, identification and determination of trace constituents; new achievements in the field of extraction of trace analytes from samples characterized by complex composition of the matrix; “green” nature of the derivatization process in analytical chemistry; passive techniques of sampling of analytes; green sorption materials used in analytical procedures; new types of solvents in the field of analytical chemistry. In addition green chromatography and related techniques, fast tests for assessment of the wide spectrum of pollutants in the different types of the medium, remote monitoring of environmental pollutants, qualitative and comparative evaluation, quantitative assessment, and future trends and perspectives are discussed. This book appeals to a wide readership of the academic and industrial researchers. In addition, it can be used in the classroom for undergraduate and graduate Ph.D. students focusing on elaboration of new analytical procedures for organic and inorganic compounds determination in different kinds of samples characterized by complex matrices composition.Jacek Namieśnik was a Professor at the Department of Analytical Chemistry, Gdańsk University of Technology, Poland. Justyna Płotka-Wasylka is a teacher and researcher at the same department.

X-Ray Fluorescence in Biological Sciences Discover a comprehensive exploration of X-ray fluorescence in chemical biology and the clinical and plant sciences In X-Ray Fluorescence in Biological Sciences: Principles, Instrumentation, and Applications, a team of accomplished researchers delivers extensive coverage of the application of X-ray fluorescence (XRF) in the biological sciences, including chemical biology, clinical science, and plant science. The book also explores recent advances in XRF imaging techniques in these fields. The authors focus on understanding and investigating the intercellular structures and metals in plant cells, with advanced discussions of recently developed micro-analytical methods, like energy dispersive X-ray fluorescence spectrometry (EDXRF), total reflection X-ray fluorescence spectrometry (TXRF), micro-proton induced X-ray emission (micro-PIXE), electron probe X-ray microanalysis (EPXMA), synchrotron-based X-ray fluorescence microscopy (SXRF, SRIXE, or micro-XRF) and secondary ion mass spectrometry (SIMS). With thorough descriptions of protocols and practical approaches, the book also includes: A thorough introduction to the historical background and fundamentals of X-ray fluorescence, as well as recent developments in X-ray fluorescence analysis Comprehensive explorations of the general properties, production, and detection of X-rays and the preparation of samples for X-ray fluorescence analysis Practical discussions of the quantification of prepared samples observed under X-ray fluorescence and the relation between precision and beam size and sample amount In-depth examinations of wavelength-dispersive X-ray fluorescence and living materials Perfect for students and researchers studying the natural and chemical sciences, medical biology, plant physiology, agriculture, and botany, X-Ray Fluorescence in Biological Sciences: Principles, Instrumentation, and Applications will also earn a place in the libraries of researchers at biotechnology companies.

Earlier works on plant essential elements have revealed a series of complicated, counter-intuitive relationships among various chemical elements in different plant species, due to both unlike usage of certain elements in plants and to different carriers effecting resorption and transport. In an attempt to provide a more coherent theory behind plant mineral nutrition, this groundbreaking book adopts a very different approach from the existing literature, presenting an explanation of the essentiality of chemical elements in biological systems and the application of stoichiometric network analysis (SNA) to the biological system of elements. Starting with data from biochemical environmental analysis, and a discussion of the phenomena involved in metal ion partition and autocatalytic behaviour, conditions and criteria controlling the partition of metals into biomass are investigated. Several rules are derived and investigated in terms of their interaction both in comparisons among contemporary organisms and in terms of evolution. This allows the construction, for example of a map which directly traces the biological feature of essentiality to parameters of coordination chemistry. The book will have worldwide appeal for researchers interested in fields such as soil/plant interactions, bioinorganic chemistry, plant nutrition, phytomining, bioremediation, biogeochemistry, nutrient cycling, soil chemistry, and cellular physiology.

Contemporary legislation respecting environmental protection and public health, at both national and international levels, are based on data that characterize chemical properties of environmental phenomena, especially those that reside in our food chain. Thus, environmental and food quality are now matters of major public concern and therefore a sy

This book is written for researchers and students interested in the function and role of chemical elements in biological or environmental systems. Experts have long known that the Periodic System of Elements (PSE) provides only an inadequate chemical description of elements of biological, environmental or medicinal importance. This book explores the notion of a Biological System of the Elements (BSE) established on accurate and precise multi-element data, including evolutionary aspects, representative sampling procedures, inter-element relationships, the physiological function of elements and uptake mechanisms. The book further explores the concept Stoichiometric Network Analysis (SNA) to analyze the biological roles of chemical species. Also discussed is the idea of ecotoxicological identity cards which give a first-hand description of properties relevant for biological and toxicological features of a certain chemical element and its geo biochemically plausible speciation form. The focus of this book goes beyond both classical bioinorganic chemistry and toxicology.

The burgeoning demand on the world food supply, coupled with concern over the use of chemical fertilizers, has led to an accelerated interest in the practice of precision agriculture. This practice involves the careful control and monitoring of plant nutrition to maximize the rate of growth and yield of crops, as well as their nutritional value.