Precise measurements of the calcium (Ca) isotopes have provided constraints on Ca cycling at global and local scales, and quantified rates of carbonate diagenesis in marine sedimentary systems. Key to applying Ca isotopes as a geochemical tracer of Ca cycling, carbonate (bio)mineralization, and diagenesis is an understanding of the impact of multiple factors potentially impacting Ca isotopes in the rock record. These factors include variations in stable isotopic fractionation factors, the influence of local-scale Ca cycling on Ca isotopic gradients in carbonate settings, carbonate dissolution and reprecipitation, and the relationship between the Ca isotopic composition of seawater and mineral phases that record the secular evolution of seawater chemistry.

This book provides an overview of the fundamentals and reference values for Ca stable isotope research, as well as current analytical methodologies including detailed instructions for sample preparation and isotope analysis. As such, it introduces readers to the different fields of application, including low-temperature mineral precipitation and biomineralisation, Earth surface processes and global cycling, high-temperature processes and cosmochemistry, and lastly human studies and biomedical applications. The current state of the art in these major areas is discussed, and open questions and possible future directions are identified. In terms of its depth and coverage, the current work extends and complements the previous reviews of Ca stable isotope geochemistry, addressing the needs of graduate students and advanced researchers who want to familiarize themselves with Ca stable isotope research.

Earth’s present-day environments are the outcome of a 4.5 billion year period of evolution reflecting the interaction of global-scale geological and biological processes. Punctuating that evolution were several extraordinary events and episodes that perturbed the entire Earth system and led to the creation of new environmental conditions, sometimes even to fundamental changes in how planet Earth operated. Volume 3: Global Events and the Fennoscandian Arctic Russia - Drilling Earth Project represents another kind of illustrated journey through the early Palaeoproterozoic, provided by syntheses, reviews and summaries of the current state of our understanding of a series of global events that resulted in a fundamental change of the Earth System from an anoxic to an oxic state. The book discusses traces of life, possible causes for the Huronian-age glaciations, addresses radical changes in carbon, sulphur and phosphorus cycles during the Palaeoproterozoic, and provides a comprehensive description and a rich photo-documentation of the early Palaeoproterozoic supergiant, petrified oil-field. Terrestrial environments are characterised through a critical review of available data on weathered and calichified surfaces and travertine deposits. Potential implementation of Ca, Mg, Sr, Fe, Mo, U and Re-Os isotope systems for deciphering Palaeoproterozoic seawater chemistry and a change in the redox-state of water and sedimentary columns are discussed. The volume considers in detail the definition of the oxic atmosphere, possible causes for the oxygen rise, and considers the oxidation of terrestrial environment not as a single event, but a slow-motion process lasting over hundreds of millions of years. Finally, the book provides a roadmap as to how the FAR-DEEP cores may facilitate future interesting science and provide a new foundation for education in earth-science community. Welcome to the illustrative journey through one of the most exciting periods of planet Earth!