Precise measurements of the calcium (Ca) isotopes have provided constraints on Ca cycling at global and local scales, and quantified rates of carbonate diagenesis in marine sedimentary systems. Key to applying Ca isotopes as a geochemical tracer of Ca cycling, carbonate (bio)mineralization, and diagenesis is an understanding of the impact of multiple factors potentially impacting Ca isotopes in the rock record. These factors include variations in stable isotopic fractionation factors, the influence of local-scale Ca cycling on Ca isotopic gradients in carbonate settings, carbonate dissolution and reprecipitation, and the relationship between the Ca isotopic composition of seawater and mineral phases that record the secular evolution of seawater chemistry.

Handbook of Environmental Isotope Geochemistry, Volume 2: The Terrestrial Environment, B focuses on the processes, methodologies, principles, and approaches involved in isotope geochemistry. The selection first elaborates on mathematical models for the interpretation of environmental radioisotopes in groundwater systems; isotopes in cloud physics; and environmental isotopes in lake studies. Discussions focus on water balance studies of lakes, isotopic fractionations during evaporation of water, study of hailstone growth mechanisms by means of isotopic analyses, isotopic effects during growth of individual elements, and models and their hydrological significance. The text then takes a look at environmental isotope and anthropogenic tracers of lake sedimentation; stable isotope geochemistry of travertines; and isotope geochemistry of carbonates in the weathering zone. Topics include isotopic composition of carbonates in the weathering zone; reprecipitation processes in the weathering zone; isotopic composition of carbon and oxygen sources in the weathering zone; and geochemical conditions controlling travertine deposition. The manuscript also reviews radioactive noble gases in the terrestrial environment, isotope effects of nitrogen in the soil and biosphere, and oxygen and hydrogen isotope geochemistry of deep basin brines. The selection is a vital source of data for researchers interested in isotope geochemistry.

Applications of radioactive and stable isotopes have revolutionized our understanding of the Earth and near-earth surface processes. The utility of the isotopes are ever-increasing and our sole focus is to bring out the applications of these isotopes as tracers and chronometers to a wider audience so that they can be used as powerful tools to solve environmental problems. New developments in this field remain mostly in peer-reviewed journal articles and hence our goal is to synthesize these findings for easy reference for students, faculty, regulators in governmental and non-governmental agencies, and environmental companies. While this volume maintains its rigor in terms of its depth of knowledge and quantitative information, it contains the breadth needed for wide variety problems and applications in the environmental sciences. This volume presents all of the newer and older applications of isotopes pertaining to the environmental problems in one place that is readily accessible to readers. This book not only has the depth and rigor that is needed for academia, but it has the breadth and case studies to illustrate the utility of the isotopes in a wide variety of environments (atmosphere, oceans, lakes, rivers and streams, terrestrial environments, and sub-surface environments) and serves a large audience, from students and researchers, regulators in federal, state and local governments, and environmental companies.

''A voluminous encyclopedia of Tethyan geology and, as such, it provides an invaluable source of information for those interested in this region, and Earth history in general...The book is a must for the libraries of universities and geologic institutions.'' --- Palaios, October 1997 Volume 8 focuses on the Tethys oceanic realm and introduces new concepts such as 'transit plates' and 'seuils lithospheriques.' Contributors include new guides to understanding the distribution of Tethyan mineral and organic resources, and present insights into the role of carbonate platforms. Chapters are abundant with maps and illustrations.

The applications of calcium-isotope measurements in marine carbonates are explored in several different contexts within this thesis. As a record of global ion fluxes, seawater calcium-isotope ratios can be used as tracers for large weathering imbalances, which develop as a feedback system in response to intervals of climate change. This approach provides valuable constraints on the complex climatic and oceanographic phenomena known as the Oceanic Anoxic Events. Over much longer timescales, the calcium-isotope ratio of seawater is influenced by steady-state processes that reflect the evolution of seawater chemistry. To understand these influences, the modern calcium-isotope budget is assessed quantitatively using a compilation of marine carbonate samples, revealing several distinctive components of the carbonate burial sink that can affect the steady-state balance of the calcium cycle. Changes in the major ion composition of seawater and in the organisms that contribute to sedimentary carbonate burial are shown to contribute significantly to the geological record of seawater calcium-isotope ratios. The importance of skeletal carbonate in the calcium cycle leads to another application of calcium isotopes towards understanding biomineralization. This large and complex topic is approached with calcium-isotope data from two unique growth experiments that constrain some of the mechanisms by which biogenic aragonite acquires its geochemical signatures. This range of topics presents a diverse, but by no means exclusive, sample of the topics that are accessible for investigation through calcium-isotope analysis. The potential of this isotopic tool is demonstrated by the breadth of environments and timescales represented in this work.