Biologically-inspired Bimetallic Complexes for the Activation of Small Molecules
Title | Biologically-inspired Bimetallic Complexes for the Activation of Small Molecules PDF eBook |
Author | Rachel Clare Linck |
Publisher | |
Pages | 438 |
Release | 2004 |
Genre | |
ISBN |
Bio-inspired First-row Transition Metal Complexes for Small Molecule Activation
Title | Bio-inspired First-row Transition Metal Complexes for Small Molecule Activation PDF eBook |
Author | Yun Ji Park |
Publisher | |
Pages | |
Release | 2016 |
Genre | |
ISBN |
Activation of Small Molecules
Title | Activation of Small Molecules PDF eBook |
Author | William B. Tolman |
Publisher | John Wiley & Sons |
Pages | 382 |
Release | 2006-12-13 |
Genre | Science |
ISBN | 3527609377 |
The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.
Modes of Cooperative Effects in Dinuclear Complexes
Title | Modes of Cooperative Effects in Dinuclear Complexes PDF eBook |
Author | Philippe Kalck |
Publisher | Springer Nature |
Pages | 241 |
Release | 2023-05-23 |
Genre | Science |
ISBN | 3031322509 |
This book presents recent advances in dinuclear complexes in which the metal-metal cooperative effect operates for obtaining substrate activation and high performance catalysts. Catalysis continues to be a fast expanding area to design efficient tools in synthesis and in industrial chemistry. It allows performing syntheses with short reaction times, atom economy, reduced consumption of energy and loss of reagents, and low level of wastes. Dinuclear complexes are known to be more efficient than the mononuclear analogues for the reaction rates and the selectivities. This book analyses the latest research, focusing on the key concepts, in building and using these dinuclear complexes. The book is aimed at researchers, graduate students and chemists at all levels in academia and industry.
Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation
Title | Synthesis and Characterization of Transition Metal Complexes with Bulky Tin Ligands for Application in Small Molecule Activation PDF eBook |
Author | Veeranna Yempally |
Publisher | |
Pages | |
Release | 2012 |
Genre | |
ISBN |
The role of bulky tin ligands in the stabilization of transition metal complexes with electronic unsaturation has been studied to understand the mode of binding of small molecules at an unsaturated metal center. We were able to isolate electronically unsaturated Pt-Sn bimetallic complexes effective in the reversible activation of small molecules including CO, H2, C2H4, and NH3 at room temperature. We have examined the effect of the modification of ligands in Pt-Sn bimetallic complexes for the activation of small molecules and have observed that the Pt(SnBut3)2(CNBut)2 bimetallic complex reversibly activates hydrogen at room temperature both in the solid state and in solution. Similarly, we have also prepared bimetallic Pt-Sn complexes with an NHC carbine ligand which were also shown to activate hydrogen and alkenes reversibly. A bimetallic Fe-Sn cluster complex, Fe2 ([mu]-SnBut2)2(CO)8, was synthesized from the reaction of But3SnH with the Fe2(CO)9 and shown to be selective at activating the benzylic C-H bond of alkylaromatic solvent molecules. The new complexes containing tin have been characterized spectroscopically to gain an insight into the reaction mechanism involved in small molecule activation.
Bimetallic Uranium and Cerium Tetraphenolate Complexes for the Activation and Functionalisation of Small Molecules
Title | Bimetallic Uranium and Cerium Tetraphenolate Complexes for the Activation and Functionalisation of Small Molecules PDF eBook |
Author | Megan Lucy Seymour |
Publisher | |
Pages | |
Release | 2019 |
Genre | |
ISBN |
The Catalytic Activation of Small Molecules by Transition Metal Complexes
Title | The Catalytic Activation of Small Molecules by Transition Metal Complexes PDF eBook |
Author | Edward Mason Gordon |
Publisher | |
Pages | 456 |
Release | 1987 |
Genre | |
ISBN |