The replacement of polyols synthesized from petrochemical by polyols originating from natural products, notably from vegetable oils and animal fats, has been the subject of research projects for a number of decades. Very recently, however, the polymers industry has intensified its efforts to include the "green products", such as biobased polyols, in applications already available in the market. Examples of such applications include polyurethane foams, elastomers and epoxides. This book describes the extraction of the natural constituents of several fruits and plants as well as their chemical conversion to polyols. In addition to the chemistry involved in the process, particular emphasis is attributed to their applications.

This brief outlines the most recent advances in the production of polyols and polyurethanes from renewable resources, mainly vegetable oils, lignocellulosic biomass, starch, and protein. The typical processes for the production of polyols from each of the above mentioned feedstocks are introduced and the properties of the resultant polyols and polyurethanes are also discussed.

This ACS Symposium Series is the product of a symposium held at the 241st National Meeting of the American Chemical Society. 2011. It includes chapters on new biobased building blocks such as the furandicarboxylic acid, polyesters and polyamides from adipic, succinic and sebacic acids with aliphatic diols such as 1,3-propylene glycol, 1,4-butanediol, 1,12-dodecylenediol and isosorbide.

Bio-based Plant Oil Polymers and Composites provides engineers and materials scientists a useful framework to help take advantage of the latest research conducted in this rapidly advancing field—enabling them to develop and commercialize their own products quickly and more successfully. Plant oil is one of the most attractive options as a substitute for non-renewable resources in polymers and composites, and is producing materials with very promising thermomechanical properties relative to traditional, petroleum-based polymers. In addition to critical processing and characterization information, the book assists engineers in deciding whether or not they should use a plant oil-based polymer over a petroleum-based polymer, discussing sustainability concerns, biodegradability, associated costs, and recommended applications. The book details the advancements in the development of polymeric materials and composites from plant oils, and provides a critical review of current applications in various fields, including packaging, biomedical, and automotive applications. Also includes the latest progress in developing multifunctional biobased polymers—by increasing thermal conductivity or adding antibacterial properties, for example. - Essential coverage of processing, characterization, and the latest research into polymeric materials and composites derived from plant oils (thermoplastics, thermosets, nanocomposites, and fiber reinforced composites) - Critically reviews the potential applications of plant oil-based polymers, including sensors, structural parts, medical devices, and automotive interiors - Includes the latest developments in multifunctional bio-based polymer composites

"This book is about Polyurethane Chemistry: Renewable Polyols and Isocyanates"--

Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each class of reactive resin (thermoset), as well as additives, the curing process, applications and uses. The initial chapters are devoted to individual resin types (e.g., epoxides, cyanacrylates), followed by more general chapters on topics such as reactive extrusion and dental applications. Injection molding of reactive polymers, radiation curing, thermosetting elastomers, and reactive extrusion equipment are covered as well. The use of reactive polymers enables manufacturers to make chemical changes at a late stage in the production process, which, in turn, cause changes in performance and properties. Material selection and control of the reaction are essential to achieve optimal performance. Material new to this edition includes the most recent developments, applications and commercial products for each chemical class of thermosets, as well as sections on fabrication methods, reactive biopolymers, recycling of reactive polymers and case studies. - Covers the basics and most recent developments, including reactive biopolymers, recycling of reactive polymers, nanocomposites and fluorosilicones - Offers an indispensable guide for engineers and advanced students alike - Provides extensive literature and patent review - Reflects a thorough review of all literature published in this area since 2014 - Features revised and updated chapters to reflect the latest research in reactive polymers