This reference book contains information about the structure and properties of atomic and molecular particles, as well as some of the nuclear parameters. It includes data which can be of use when studying atomic and molecular processes in the physics of gases, chemistry of gases and gas optics, in plasma physics and plasma chemistry, in physical chemistry and radiation chemistry, in geophysics, astrophysics, solid-state physics and a variety of cross-discipli nary fields of science and technology. Our aim was to collect carefully selected and estimated numerical values for a wide circle of microscopic parameters in a relatively "not thick" book. These values are of constant use in the work of practical investigators. In essence, the book represents a substantially revised and extended edi tion of our reference book published in Russian in 1980. Two main reasons made it necessary to rework the material. On the one hand, a great deal of new high-quality data has appeared in the past few years and furthermore we have enlisted many sources of information previously inaccessible to us. On the other hand, we have tried to insert extensive information on new, rapidly progressing branches of physical research, such as multiply charged ions, Rydberg atoms, van der Waals and excimer molecules, complex ions, etc. All this brings us to the very edge of studies being carried out in the field.

This book presents numerical methods for solving a wide range of problems associated with the structure of atoms and simplest molecules, and their interaction with electromagnetic radiation, electrons, and other particles. It introduces the ATOM-M software package, presenting a unified software suite, written in Fortran, for carrying out precise atomic and molecular numeric calculations. The book shows how to apply these numerical methods to obtain many different characteristics of atoms, molecules, and the various processes within which they interact. In an entirely self-sufficient approach, it teaches the reader how to use the codes provided to build atomic and molecular systems from the ground up and obtain the resulting one-electron wave functions. The computational programs presented and made available in this book allow calculations in the one-electron Hartree–Fock approximation and take into account many-electron correlations within the framework of the random-phase approximation with exchange or many-body perturbation theory. Ideal for scholars interested in numerical computation of atomic and molecular processes, the material presented in this book is useful to both experts and novices, theorists, and experimentalists.

Atomic and Molecular Processes focuses on radiative and collisional processes involving atoms or molecules, including photoionization, elastic and inelastic scattering of electrons, energy loss by slow electrons, excitation, ionization, detachment, charge transfer, elastic scattering, and chemical reactions. The selection first offers information on forbidden and allowed transitions, including forbidden transitions in diatomic molecular spectra; forbidden transitions in crystals; calculations of atomic line strengths; and measurements of atomic transition probabilities. The book also ponders on photoionization processes, photodetachment, and high temperature shock waves. The manuscript elaborates on electronic and ionic recombination, elastic scattering of electrons, and the motions of slow electrons in gases. The book also evaluates the theory of excitation and ionization by electron impact; measurement of collisional excitation and ionization cross sections; and spectral line broadening in plasmas. The selection is a dependable reference for readers interested in atomic and molecular processes.

Principles and Applications of Quantum Contro Over the past fifteen years, significant developments have been made in utilizing quantum attributes of light and matter to assume unprecedented control over the dynamics of atomic and molecular systems. This growth reflects a confluence of factors including the maturation of quantum mechanics as a tool for chemistry and physics, the development of new laser devices increasing our ability to manipulate light, and the recognition that coherent laser light can be used to imprint information on atoms and molecules for practical purposes. Written by two of the world’s leading researchers in the field, Principles of the Quantum Control of Molecular Processes offers a systematic introduction to the fundamental principles of coherent control, and to the physics and chemistry necessary to master it Designed as both a resource for self-study and as a graduate textbook, this survey of the subject provides a step-by-step discussion of light-matter interactions along with coverage of such essential topics as: Molecular dynamics and control LI>The dynamics of photodissociation LI>Bimolecular collision processes LI>The control of chirality and asymmetric synthesis LI>Application of control using moderate and strong fields LI>Tuning the system and laser parameters to achieve optimal control LI>Decoherence and methods for countering it P>Both authoritative and comprehensive, this first in-depth treatment of coherent control is destined to become the standard reference in an increasingly influential field PAUL W. BRUMER, PhD, is University Professor–Theoretical Chemical Physics and holds the Roel Buck Chair in Chemical Physics at the University of Toronto. He received his BSc. from Brooklyn College and his PhD from Harvard University. MOSHE SHAPIRO, PhD, is the Jacques Mimran Professor of Chemical Physics at the Weizmann Institute of Science, Rehovot, Israel, and a Professor of Chemistry and Physics at the University of British Columbia. He received his BSc, MSc, and PhD from the Hebrew University of Jerusalem The authors are among the cofounders of the field of coherent control. They have published extensively on this and related subjects in chemical physics, and have received numerous awards and worldwide recognition for their research contributions.

As part of the Physics 2010 decadal survey project, the Department of Energy and the National Science Foundation requested that the National Research Council assess the opportunities, over roughly the next decade, in atomic, molecular, and optical (AMO) science and technology. In particular, the National Research Council was asked to cover the state of AMO science, emphasizing recent accomplishments and identifying new and compelling scientific questions. Controlling the Quantum World, discusses both the roles and challenges for AMO science in instrumentation; scientific research near absolute zero; development of extremely intense x-ray and laser sources; exploration and control of molecular processes; photonics at the nanoscale level; and development of quantum information technology. This book also offers an assessment of and recommendations about critical issues concerning maintaining U.S. leadership in AMO science and technology.

A wide-ranging review of modern techniques in atomic and molecular spectroscopy. A brief description of atomic and molecular structure is followed by the relevant energy structure expressions. A discussion of radiative properties and the origin of spectra leads into coverage of X-ray and photoelectron spectroscopy, optical spectroscopy, and radiofrequency and microwave techniques. The treatment of laser spectroscopy investigates various tunable sources and a wide range of techniques characterized by high sensitivity and high resolution. Throughout this book, the relation between fundamental and applied aspects is shown, in particular by descriptions of applications to chemical analysis, photochemistry, surface characterisation, environmental and medical diagnostics, remote sensing and astrophysics.

Atomic and molecular processes play an important role in laboratory and astrophysical plasmas for a wide range of conditions, and determine, in part, their electrical, transport, thermal, and radiation properties. The study of these and other plasma properties requires a knowledge of the cross sections, reaction rate coefficients, and inelastic energy transfers for a variety of collisional reactions. In this review, we provide quantitative information about the most important collision processes occurring in hy drogen, helium, and hydrogen-helium plasmas in the temperature range from 0. 1 eV to 20 keY. The material presented here is based on published atomic and molecular collision data, theoretical calculations, and appro priate extrapolation and interpolation procedures. This review gives the properties of each reaction, graphs of the cross sections and reaction rate coeffiCients, and the coefficients of analytical fits for these quantities. We present this information in a form that will enable researchers who are not experts in atomic physics to use the data easily. The authors thank their colleagues at the Princeton Plasma Physics Laboratory and in the atomic physics community who have made many useful suggestions for the selection and presentation o. f t. he material. We gratefully acknowledge the excellent technical assistance of Elizabeth Carey for the typing, and Bernie Giehl for the drafting. This work was supported in part by the U. S. Department of Energy Contract No. DE-AC02-76-CHO-3073. Princeton, USA R. K. Janev W. D. Langer September, 1987 K. Evans, Jr. , D. E.