Conditional Source-term Estimation (CSE) is a turbulent combustion model that uses conditional averages to close the chemical source term. Previous CSE studies have shown that the model is able to predict the flame characteristics successfully, however, these studies have only focused on simple hydrocarbon fuels mostly composed of methane. The objective of the present study is to evaluate the capabilities of CSE applied to turbulent non-premixed methanol flames, which has never been done previously. The present study investigates two different types of methanol flames: piloted and bluff -body flames. For the piloted flame, the standard k-

Conditional Source-term Estimation (CSE) methods are used to obtain chemical closure in turbulent combustion simulation. A Laminar Flamelet Decomposition (LFD) and then a Trajectory Generated Low-Dimensional Manifold (TGLDM) method are combined with CSE in Reynolds-Averaged Navier Stokes (RANS) simulation of non-premixed autoigniting jets. Despite the scatter observed in the experimental data, the predictions of ignition delay from both methods agree reasonably well with the measurements. The discrepancy between predictions of these two methods can be attributed to different ways of generating libraries that contain information of detailed chemical mechanism. The CSE-TGLDM method is recommended for its seemingly better performance and its ability to transition from autoignition to combustion. The effects of fuel composition and injection parameters on ignition delay are studied using the CSE-TGLDM method. The CSE-TGLDM method is then applied in Large Eddy Simulation of a non-premixed, piloted jet flame, Sandia Flame D. The adiabatic CSE-TGLDM method is extended to include radiation by introducing a variable enthalpy defect to parameterize TGLDM manifolds. The results are compared to the adiabatic computation and the experimental data. The prediction of NO formation is improved, though the predictions of temperature and major products show no significant difference from the adiabatic computation due to the weak radiation of the flame. The scalar fields are then extracted and used to predict the mean spectral radiation intensities of the flame. Finally, the application of CSE in turbulent premixed combustion is explored. A product-based progress variable is chosen for conditioning. Presumed Probability Density Function (PDF) models for the progress variable are studied. A modified version of a laminar flame-based PDF model is proposed, which best captures the distribution of the conditional variable among all PDFs under study. A priori tests are performed with the CSE.

Conditional Source-term Estimation (CSE) is a closure technique for modelling turbulent combustion phenomena. CSE uses the Conditional Moment Closure (CMC) hypothesis for closing chemical source terms: conditionally averaged chemical source terms are closed by conditional averaged scalars, which are obtained by inverting an integral equation, instead of solving transport equations (as in CMC). Since CSE has been successfully applied to both premixed and non-premixed configurations, it represents an attractive method for dealing with the more general and complex case of partially premixed combustion. The objectives of the present study are to (i) consolidate the premixed formulation of CSE through numerical simulations of a turbulent bluff body premixed flame; (ii) formulate, implement and test the Doubly conditional CSE (DCSE) in the context of partially premixed combustion; (iii) compare the DCSE predictions with well documented turbulent partially premixed flames. The canonical example of partially premixed flames is represented by turbulent lifted flames. A series of lifted turbulent jet flames is investigated in RANS by using DCSE. The DCSE calculations are successful in predicting the lift-off heights at three different conditions and reproducing many aspects of the flame structure in agreement with the experimental observations. The current results show that important aspects of the stabilization mechanism can be reproduced by the DCSE combustion model. The applicability of DCSE is further evaluated by applying this approach to a series of turbulent V-shaped flames for which experimental data is available. Premixed and stratified conditions are investigated. Overall, the agreement between numerical results and experimental findings is good, demonstrating the capability of DCSE to deal with partially premixed combustion. Future work includes implementation of CSE in LES and investigation of different fuels such as propane and biofuels.