A general model was developed to estimate the activities of fission products in reactor coolant and hence to predict a value for the I-129/Cs-137 scaling factor; the latter can be applied along with measured Cs-137 activities to estimate I-129 levels in reactor waste. The model accounts for fission product release from both defective fuel rods and uranium contamination present on in-core reactor surfaces. For simplicity, only the key release mechanisms were modeled. A mass balance, considering the two fuel source terms and a loss term due to coolant cleanup was solved to estimate fission product activity in the primary heat transport system coolant. Steady state assumptions were made to solve for the activity of shortlived fission products. Solutions for long-lived fission products are time-dependent. Data for short-lived radioiodines I-131, I-132, I-133, I-134 and I-135 were analyzed to estimate model parameters for I-129. The estimated parameter values were then used to determine I-1 29 coolant activities. Because of the chemical affinity between iodine and cesium, estimates of Cs-137 coolant concentrations were also based on parameter values similar to those for the radioiodines; this assumption was tested by comparing measured and predicted Cs-137 coolant concentrations. Application of the derived model to Douglas Point and Darlington Nuclear Generating Station plant data yielded estimates for I-129/I-131 and I-129/Cs-137 which are consistent with values reported for pressurized water reactors (PWRs) and boiling water reactors (BWRs). The estimated magnitude for the I-129/Cs-137 ratio was 10-8 - 10-7.

This document provides a description of a model of the radionuclide behavior in the reactor coolant system (RCS) of a light water reactor during a severe accident. This document serves as the user's manual for the computer code called VICTORIA, based upon the model. The VICTORIA code predicts fission product release from the fuel, chemical reactions between fission products and structural materials, vapor and aerosol behavior, and fission product decay heating. This document provides a detailed description of each part of the implementation of the model into VICTORIA, the numerical algorithms used, and the correlations and thermochemical data necessary for determining a solution. A description of the code structure, input and output, and a sample problem are provided. The VICTORIA code was developed upon a CRAY-XMP at Sandia National Laboratories in the USA and a CRAY-2 and various SUN workstations at the Winfrith Technology Centre in England. 60 refs.

During the normal operation of light water reactor, fuel defects can reside on fuel cladding from various reason such as fuel-pellet mechanical interaction, the hydriding of the Zr clad, the grid fritting from the assembly support, the warp wire fritting with the clad and also the stress corrosion cracking (SCC). The formation of defects on fuel cladding will result water ingression to the gap and react with nuclear fuel and the cladding inner surface. The interaction of water and nuclear fuel will affect the fuel thermal properties and deteriorate the cladding by hydriding and change of oxygen potential in the fuel. The change of fuel thermal properties will decrease the thermal conductivity, lead the decrease of heat transfer coefficient which may increase the fuel melting risk. The volatile fission products and fission gas will release to the coolant through cladding defects and increase the coolant activity and the defective nuclear fuel becomes a fission product source term when reactor is under normal operation. Experimental and modeling are applied to understand the behavior of a defective fuel pin. The experimental part focuses on the dissolution test of rare earth fission products in simulated LWR coolant chemistry and the diffusion coefficient measurement of cesium iodide in simulated LWR coolant chemistry using Nuclear Magnetic Resonance (NMR) technique. Rare earth fission products significantly contribute the residual heat and large quantity of radioactivity after the core shut down or in severe accident, therefore, their dissolution kinetic parameters in LWR are important to reactor safety and the understanding the source terms.