Over the past several decades, analyses of solute migration in aquifers have widely adopted the classical advection-dispersion equation. However, misunderstandings over advection-dispersion concepts, their relationship with the scales of heterogeneity, our observation and interest, and their ensemble mean nature have created furious debates about the concepts' validity. This book provides a unified and comprehensive overview and lucid explanations of the stochastic nature of solute transport processes at different scales. It also presents tools for analyzing solute transport and its uncertainty to meet our needs at different scales. Easy-to-understand physical explanations without complex mathematics make this book an invaluable resource for students, researchers, and professionals performing groundwater quality evaluations, management, and remediation.

The book addresses the development of the basic knowledge of the subsurface solute transfer with a particular emphasis on field data collection and analysis coupled with modeling (analytical and numerical) tool application. The relevant theoretical developments are concerned mainly with the formulation and solution of deterministic mass-transport equations for a wide range of engineering issues in groundwater quality assessment and forecasting. The book gives many computational examples and case studies drawn from the conducted field investigations. The analyzed problems are as follows: investigation and prediction of groundwater contamination by industrial contaminants and solutions (radionuclides, chloride and nitrate brine) with special focus on the effect of (a) aquifer heterogeneity, anisotropy, and dual porosity, (b) density contrast existing between industrial waste and groundwater, or in density-stratified artesian and coastal groundwater systems; (c) physicochemical interactions that play a major role in retarding (e.g. adsorption) or enhancing (e.g. interactions between dissolved species and mobile colloids) contaminant transport; prediction of the effects of pumping on groundwater quality at wellfields; groundwater dating using stable and radioactive isotopes for prediction and assessment of contamination potential; field and laboratory tests’ design and analysis, and monitoring data interpretation; partitioning of surface and subsurface flows using isotope techniques. One of the most essential topics addressed in the book is the migration and fate of radionuclides. Model development is motivated by field data analysis from a number of radioactively contaminated sites in the Russian Federation: near-surface radioactive waste disposal sites and deep-well radioactive waste injection sites. They play a unique role in the advancement of knowledge of the subsurface behavior and fate of many hazardous radionuclides and can be considered as field-scale laboratories. Thus, the book, along with theoretical findings, contains field information, which will facilitate the understanding of subsurface solute transport and the development of a methodology for practical applications to groundwater hydrology.

In many parts of the world, groundwater resources are under increasing threat from growing demands, wasteful use, and contamination. To face the challenge, good planning and management practices are needed. A key to the management of groundwater is the ability to model the movement of fluids and contaminants in the subsurface. The purpose of this book is to construct conceptual and mathematical models that can provide the information required for making decisions associated with the management of groundwater resources, and the remediation of contaminated aquifers. The basic approach of this book is to accurately describe the underlying physics of groundwater flow and solute transport in heterogeneous porous media, starting at the microscopic level, and to rigorously derive their mathematical representation at the macroscopic levels. The well-posed, macroscopic mathematical models are formulated for saturated, single phase flow, as well as for unsaturated and multiphase flow, and for the transport of single and multiple chemical species. Numerical models are presented and computer codes are reviewed, as tools for solving the models. The problem of seawater intrusion into coastal aquifers is examined and modeled. The issues of uncertainty in model input data and output are addressed. The book concludes with a chapter on the management of groundwater resources. Although one of the main objectives of this book is to construct mathematical models, the amount of mathematics required is kept minimal.

"This volume covers many of the important advances in the geological sciences from 1963 to 2013. These advances include understanding plate tectonics, exploration of the Moon and Mars, development of new computing and analytical technologies, understanding of the role of microbiology in geologic processes, and many others"--Provided by publisher.

A complete treatment of the theory and practice of groundwater engineering, The Handbook of Groundwater Engineering, Second Edition provides a current and detailed review of how to model the flow of water and the transport of contaminants both in the unsaturated and saturated zones, covers the production of groundwater and the remediation of contaminated groundwater.

Scientific understanding of fluid flow in rock fracturesâ€"a process underlying contemporary earth science problems from the search for petroleum to the controversy over nuclear waste storageâ€"has grown significantly in the past 20 years. This volume presents a comprehensive report on the state of the field, with an interdisciplinary viewpoint, case studies of fracture sites, illustrations, conclusions, and research recommendations. The book addresses these questions: How can fractures that are significant hydraulic conductors be identified, located, and characterized? How do flow and transport occur in fracture systems? How can changes in fracture systems be predicted and controlled? Among other topics, the committee provides a geomechanical understanding of fracture formation, reviews methods for detecting subsurface fractures, and looks at the use of hydraulic and tracer tests to investigate fluid flow. The volume examines the state of conceptual and mathematical modeling, and it provides a useful framework for understanding the complexity of fracture changes that occur during fluid pumping and other engineering practices. With a practical and multidisciplinary outlook, this volume will be welcomed by geologists, petroleum geologists, geoengineers, geophysicists, hydrologists, researchers, educators and students in these fields, and public officials involved in geological projects.

Building on the success of its 1993 predecessor, this second edition of Geochemistry, Groundwater and Pollution has been thoroughly re-written, updated and extended to provide a complete and authoritative account of modern hydrogeochemistry.Offering a quantitative approach to the study of groundwater quality and the interaction of water, minerals,