This work is based on the observation that further major advances in geochemistry, particularly in understanding the rules that govern the ways in which elements come together to form minerals and rocks, will require the application of the theories of quantum mechanics. The book therefore outlines this theoretical background and discusses the models used to describe bonding in geochemical systems. It is the first book to describe and critically review the application of quantum mechanical theories to minerals and geochemical systems. The book consolidates valuable findings from chemistry and materials science as well as mineralogy and geochemistry, and the presentation has relevance to professionals in a wide range of disciplines. Experimental techniques are surveyed, but the emphasis is on applying theoretical tools to various groups of minerals: the oxides, silicates, carbonates, borates, and sulfides. Other topics dealt with in depth include structure, stereochemistry, bond strengths and stabilities of minerals, various physical properties, and the overall geochemical distribution of the elements.

This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry

Environmental Geochemistry: Site Characterization, Data Analysis and Case Histories, Second Edition, reviews the role of geochemistry in the environment and details state-of-the-art applications of these principles in the field, specifically in pollution and remediation situations. Chapters cover both philosophy and procedures, as well as applications, in an array of issues in environmental geochemistry including health problems related to environment pollution, waste disposal and data base management. This updated edition also includes illustrations of specific case histories of site characterization and remediation of brownfield sites. - Covers numerous global case studies allowing readers to see principles in action - Explores the environmental impacts on soils, water and air in terms of both inorganic and organic geochemistry - Written by a well-respected author team, with over 100 years of experience combined - Includes updated content on: urban geochemical mapping, chemical speciation, characterizing a brownsfield site and the relationship between heavy metal distributions and cancer mortality

Updated throughout with the latest data and findings, the Second Edition of Essentials of Geochemistry provides students with a solid understanding of the fundamentals of and approaches to modern geochemical analysis. The text uses a concepts of chemical equilibrium approach, which considers the reactions that occur as a result of changes in heat production and pressure within the Earth to introduce students to the basic geochemical principles. This text is for those who want a quantitative treatment that integrates the principles of thermodynamics, solution chemistry, and kinetics into the study of earth processes. This timely text contains numerous examples and problems sets which use SUPCRT92 to allow students to test their understanding of thermodynamic theory and maximize their comprehension of this prominent field. New sections introduce current “hot” topics such as global geochemical change with the short and long term carbon cycle, carbon isotopes and the Permo-Triassic extinction event, kinetics and the origin of life and the use of boron and nitrogen isotopes.

Stable Isotope Geochemistry is an introduction to the use of stable isotopes in the fields of geoscience. It is subdivided into three parts: - theoretical and experimental principles; - fractionation mechanisms of light elements; - the natural variations of geologically important reservoirs. In this updated 4th edition many of the chapters have been expanded, especially those on techniques and environmental aspects. The main focus is on recent results and new developments. For students and scientists alike the book will be a primary reference with regard to how and where stable isotopes can be used to solve geological problems.

This book is a brief summary of the course of lectures in Geochemistry for undergraduate and graduate students from other than Geological Departments (chemists, biologists, ecologists and naturalists). It describes the Earth’s structure and some geological processes. The modern geochemical concepts take proper account of global geological processes and the influence of Cosmos. They are based on the laws and approaches of equilibrium and non-equilibrium thermodynamics. The cycles of energy and chemical elements within the Earth are interrelated with the global geochemical cycle. In addition to the traditional Geochemistry course, this book offers Geochemistry of microorganisms, Geochemistry of dispersed systems, Geochemistry of cryogenesis, and Geochemistry of cryptobiosphere. Features: Provides the reader with a general idea of the Earth’s chemical life and its related global geological events Offers a concise and clear description of the modern concepts in Geochemistry, including new directions such as Geochemistry of Cryogenesis, Geochemistry of Disperse Systems, Geochemistry of Microorganisms, and Geochemistry of Cryptobiosphere Implies a wide application of the thermodynamic approach. Useful for students who, though lacking in geology basics, are experienced in chemistry and biology

"This book presents quantitative treatments of a wide range of fundamental problems related to geochemistry and geology. It shows that trace elements, isotopes, and equations are integrative tools in modern geochemistry for studying various Earth processes." -- Back cover.