Intermolecular and Surface Forces describes the role of various intermolecular and interparticle forces in determining the properties of simple systems such as gases, liquids and solids, with a special focus on more complex colloidal, polymeric and biological systems. The book provides a thorough foundation in theories and concepts of intermolecular forces, allowing researchers and students to recognize which forces are important in any particular system, as well as how to control these forces. This third edition is expanded into three sections and contains five new chapters over the previous edition. Starts from the basics and builds up to more complex systems Covers all aspects of intermolecular and interparticle forces both at the fundamental and applied levels Multidisciplinary approach: bringing together and unifying phenomena from different fields This new edition has an expanded Part III and new chapters on non-equilibrium (dynamic) interactions, and tribology (friction forces)

This monograph is devoted to long-range surface forces sig nificant far beyond a single monolayer and felt over tens or even hundreds of molecular layers adjacent to an interface. The transi tion from the concept of short-range effects that reigned earlier to the concept of long-range forces simultaneously signified the transition from a two-dimensional world to a three-dimensional one, incomparably richer in physicochemical phenomena. This transition took many years and evolved through many steps. It began with the Gouy-Chapman theory of diffuse ionic atmospheres, which together with London's theory of molecular forces was used as a basis for the development (beginning in 1937) of the DLVO theory of stability of lyophobic colloids. Further elaboration of the theory involved the introduction of new types of force, and a generalization (in 1954) to the case of interaction between unlike particles (hetero coagulation). This theory is fundamental in such large-scale prac tical problems as flotation, water treatment, dyeing, soil science, microbiology, and interaction between biological cells. This book is the first comprehensive monograph devoted to sur face forces. This fact makes it easier to attract the reader's interest; yet, the reader's demands become all the more difficult to satisfy completely. Indeed, the research that we review and analyze here covers about 50 years of work. Much data has been amassed, so that the main problem was a careful selection and an alysis.

A general introduction to surface and interfacial forces, perfectly combining theoretical concepts, experimental techniques and practical applications. In this completely updated edition all the chapters have been thoroughly revised and extended to cover new developments and approaches with around 15% new content. A large part of the book is devoted to surface forces between solid surfaces in liquid media, and while a basic knowledge of colloid and interface science is helpful, it is not essential since all important concepts are explained and the theoretical concepts can be understood with an intermediate knowledge of mathematics. A number of exercises with solutions and the end-of-chapter summaries of the most important equations, facts and phenomena serve as additional tools to strengthen the acquired knowledge and allow for self-study. The result is a readily accessible text that helps to foster an understanding of the intricacies of this highly relevant topic.

This book describes intermolecular and interparticle forces in determining the properties of systems such as gases, liquids and solids and of colloidal, polymeric and biological systems. The text includes developments on surface-force measurements, solvation and structural forces, hydration and hydrophobic forces, and ion-correlation forces.

A general introduction to surface and interfacial forces, perfectly combining theoretical concepts, experimental techniques and practical applications. In this completely updated edition all the chapters have been thoroughly revised and extended to cover new developments and approaches with around 15% new content. A large part of the book is devoted to surface forces between solid surfaces in liquid media, and while a basic knowledge of colloid and interface science is helpful, it is not essential since all important concepts are explained and the theoretical concepts can be understood with an intermediate knowledge of mathematics. A number of exercises with solutions and the end-of-chapter summaries of the most important equations, facts and phenomena serve as additional tools to strengthen the acquired knowledge and allow for self-study. The result is a readily accessible text that helps to foster an understanding of the intricacies of this highly relevant topic.

This reference describes the role of various intermolecular and interparticle forces in determining the properties of simple systems such as gases, liquids and solids, with a special focus on more complex colloidal, polymeric and biological systems. The book provides a thorough foundation in theories and concepts of intermolecular forces, allowing researchers and students to recognize which forces are important in any particular system, as well as how to control these forces. This third edition is expanded into three sections and contains five new chapters over the previous edition. Starts from the basics and builds up to more complex systems Covers all aspects of intermolecular and interparticle forces both at the fundamental and applied levels Multidisciplinary approach: bringing together and unifying phenomena from different fields This new edition has an expanded Part III and new chapters on non-equilibrium (dynamic) interactions, and tribology (friction forces)