Synthesizing the raw data needed for a wide variety of industrial applications, this work supplies up-to-date advanced in research on star, hyperbranched and dendritic polymers. It provides detailed descriptions of the size and shape of the molecules that make up these polymers, as well as their biological advances, low viscosity in solution and substrate-holding properties.

Amphiphilic polymer co-networks (APCNs) are a type of polymeric hydrogel, their hydrophobic polymer segments and hydrophilic components produce less aqueous swelling, giving better mechanical properties than conventional hydrogels. This new class of polymers is attracting increasing attention, resulting in further basic research on the system, as well as new applications. This book focuses on new developments in the field of APCNs, and is organised in four sections: synthesis, properties, applications and modelling. Co-network architectures included in the book chapters are mainly those deriving from hydrophobic macro-cross-linkers, representing the classical approach; however, more modern designs are also presented. Properties of interest discussed include aqueous swelling, thermophysical and mechanical properties, self-assembly, electrical actuation, and protein adsorption. Applications described in the book chapters include the use of co-networks as soft contact lenses, scaffolds for drug delivery and tissue engineering, matrices for heterogeneous biocatalysis, and membranes of controllable permeability. Finally, an important theory chapter on the modelling of the self-assembly of APCNs is also included. The book is suitable for graduate students and researchers interested in hydrogels, polymer networks, polymer chemistry, block copolymers, self-assembly and nanomaterials, as well as their applications in contact lenses, drug delivery, tissue engineering, membranes and biocatalysis.

The term ‘miktoarm polymers’ refers to asymmetric branched macromolecules, a relatively new entry to the macromolecular field. Recent advances in their synthesis and intriguing supramolecular chemistry in a desired medium has seen a fast expansion of their applications. The composition of miktoarm polymers can be tailored and even pre-defined to allow a desired combination of functions, meaning polymer chemists can have complete control of the overall architecture of these macromolecules. By carefully selecting the composition, they can create supramolecular structures with intriguing properties, particularly for applications in biology. Miktoarm Star Polymers features chapters from experts actively working in this field, and provides the reader with a unique introduction to the fundamental principles of this exciting macromolecular system. Topics covered include the design, synthesis, characterization, self-assembly and applications of miktoarm polymers. The book is an excellent overview and up to date guide to those working in research in polymer chemistry, materials science, and polymers for medical applications.

This book presents a comprehensive study on a new class of branched polymers, known as hyperbranched polymers (HBPs). It discusses in detail the synthesis strategies for these particular classes of polymers as well as biocompatible and biodegradable HBPs, which are of increasing interest to polymer technologists due to their immense potential in biomedical applications. The book also describes the one-pot synthesis technique for HBPs, which is feasible for large-scale production, as well as HBPs’ structure-property relationship, which makes them superior to their linear counterparts. The alterable functional groups present at the terminal ends of the branches make HBPs promising candidates in the biomedical domain, and the book specifically elaborates on the suitable characteristic properties of each of the potential biological HBPs’ applications. As such, the book offers a valuable reference guide for all scientists and technologists who are interested in using these newly developed techniques to achieve faster and better treatments.

Click Polymerization has been edited by world renowned experts and provides an authoritative guide to this reaction type.

Providing a detailed monograph on the topic, this book features chapters from experts actively working in this field, and is intended to provide the reader with a unique overview of the fundamental principles of this exciting macromolecular platform.

The field of CMA (complex macromolecular architecture) stands at the cutting edge of materials science, and has been a locus of intense research activity in recent years. This book gives an extensive description of the synthesis, characterization, and self-assembly of recently-developed advanced architectural materials with a number of potential applications. The architectural polymers, including bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are introduced chapter by chapter in the book. In particular, the book also emphasizes the topic of synthetic breakthroughs by living/controlled polymerization since 2000. Furthermore, renowned authors contribute on special topics such as helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, which have attracted considerable interest as novel polymer materials with potential future applications. In addition, recent advances in reactive blending achieved with well-defined end-functionalized polymers are discussed from an industrial point of view. Topics on polymer-based nanotechnologies, including self-assembled architectures and suprastructures, nano-structured materials and devices, nanofabrication, surface nanostructures, and their AFM imaging analysis of hetero-phased polymers are also included. Provides comprehensive coverage of recently developed advanced architectural materials Covers hot new areas such as: click chemistry; chain walking; polyhomologation; ADMET Edited by highly regarded scientists in the field Contains contributions from 26 leading experts from Europe, North America, and Asia Researchers in academia and industry specializing in polymer chemistry will find this book to be an ideal survey of the most recent advances in the area. The book is also suitable as supplementary reading for students enrolled in Polymer Synthetic Chemistry, Polymer Synthesis, Polymer Design, Advanced Polymer Chemistry, Soft Matter Science, and Materials Science courses. Color versions of selected figures can be found at www.wiley.com/go/hadjichristidis