Soot is an important air pollutant. Its formation must be modeled accurately to assist designers in development of low soot emission combustors. This study was concerned with the semi-empirical modeling of soot. The models considered inception, coagulation, agglomeration, and oxidation of the soot particles. Since inception is a key process in the development of soot it was studied in great detail. Two approaches to modeling inception were investigated: acetylene and phenyl. For a methane/air coflow diffusion flame at a pressure of one atmosphere both approaches showed good agreement with experimentally observed trends. Furthermore, the acetylene route under predicted the magnitude of the soot volume fraction while the phenyl route over predicted the magnitude of the soot volume fraction. However, it is believed that the phenyl model will perform better with more complex fuels such as kerosene and with improved laminar flamelet libraries that are optimized for C6 species.

Turbulent non-premixed stoichiometric methane-air flames have been studied using the direct numerical simulation approach. A global one- step mechanism is used to describe the chemical kinetics, and molecular transport is modeled with constant Lewis numbers for individual species. The effect of turbulence on the internal flame structure and extinction characteristics of methane-air flames is evaluated. The flame is wrinkled and in some regions extinguished by the turbulence, while the turbulence is weakened in the vicinity of the flame due to a combination of dilatation and a 25:1 increase in kinematic viscosity across the flame. Reignition followed by partially-premixed burning is observed in the present results. Local curvature effects are found to be important in determining the local stoichiometry of the flame, and hence, the location of the peak reaction rate relative to the stoichiometric surface. The results presented in this study demonstrate the feasibility of incorporating global-step kinetics for the oxidation of methane into direct numerical simulations of homogeneous turbulence to study the flame structure.

The combustion of fossil fuels remains a key technology for the foreseeable future. It is therefore important that we understand the mechanisms of combustion and, in particular, the role of turbulence within this process. Combustion always takes place within a turbulent flow field for two reasons: turbulence increases the mixing process and enhances combustion, but at the same time combustion releases heat which generates flow instability through buoyancy, thus enhancing the transition to turbulence. The four chapters of this book present a thorough introduction to the field of turbulent combustion. After an overview of modeling approaches, the three remaining chapters consider the three distinct cases of premixed, non-premixed, and partially premixed combustion, respectively. This book will be of value to researchers and students of engineering and applied mathematics by demonstrating the current theories of turbulent combustion within a unified presentation of the field.

Soot Formation in Combustion represents an up-to-date overview. The contributions trace back to the 1991 Heidelberg symposium entitled "Mechanism and Models of Soot Formation" and have all been reedited by Prof. Bockhorn in close contact with the original authors. The book gives an easy introduction to the field for newcomers, and provides detailed treatments for the specialists. The following list of contents illustrates the topics under review:

Turbulent combustion sits at the interface of two important nonlinear, multiscale phenomena: chemistry and turbulence. Its study is extremely timely in view of the need to develop new combustion technologies in order to address challenges associated with climate change, energy source uncertainty, and air pollution. Despite the fact that modeling of turbulent combustion is a subject that has been researched for a number of years, its complexity implies that key issues are still eluding, and a theoretical description that is accurate enough to make turbulent combustion models rigorous and quantitative for industrial use is still lacking. In this book, prominent experts review most of the available approaches in modeling turbulent combustion, with particular focus on the exploding increase in computational resources that has allowed the simulation of increasingly detailed phenomena. The relevant algorithms are presented, the theoretical methods are explained, and various application examples are given. The book is intended for a relatively broad audience, including seasoned researchers and graduate students in engineering, applied mathematics and computational science, engine designers and computational fluid dynamics (CFD) practitioners, scientists at funding agencies, and anyone wishing to understand the state-of-the-art and the future directions of this scientifically challenging and practically important field.