This book is the second volume of Solids Volumes in theShockWaveScience and Technology Reference Library. These volumes are primarily concerned with high-pressure shock waves in solid media, including detonation and hi- velocity impact and penetration events. This volume contains four articles. The ?rst two describe the reactive behavior of condensed-phase explosives, and the remaining two discuss the inert, mechanical response of solid materials. The articles are each se- contained, and can be read independently of each other. They o?er a timely reference, for beginners as well as professional scientists and engineers, cov- ing the foundations and the latest progress, and include burgeoning devel- ment as well as challenging unsolved problems. The ?rst chapter, by S. She?eld and R. Engelke, discusses the shock initiation and detonation phenomena of solids explosives. The article is an outgrowth of two previous review articles: “Explosives” in vol. 6 of En- clopedia of Applied Physics (VCH, 1993) and “Initiation and Propagation of Detonation in Condensed-Phase High Explosives” in High-Pressure Shock Compression of Solids III (Springer, 1998). This article is not only an - dated review, but also o?ers a concise heuristic introduction to shock waves and condensed-phase detonation. The authors emphasize the point that d- onation is not an uncontrollable, chaotic event, but that it is an orderly event that is governed by and is describable in terms of the conservation of mass, momentum, energy and certain material-speci?c properties of the explosive.

This book discusses methods for the assessment of energetic compounds through heat of detonation, detonation pressure, velocity and temperature, Gurney energy and power. The authors focus on the detonation pressure and detonation velocity of non-ideal aluminized energetic compounds. This 2nd Edition includes an updated and improved presentation of simple, reliable methods for the design, synthesis and development of novel energetic compounds.

Developing and testing novel energetic materials is an expanding branch of the materials sciences. Reaction, detonation or explosion of such materials invariably produce extremely high pressures and temperatures. To study the equations-of-state (EOS) of energetic materials in extreme regimes both shock and static high pressure studies are required. The present volume is an introduction and review of theoretical, experimental and numerical aspects of static compression of such materials. Chapter 1 introduces the basic experimental tool, the diamond anvil pressure cell and the observational techniques used with it such as optical microscopy, infrared spectrometry and x-ray diffraction. Chapter 2 outlines the principles of high-nitrogen energetic materials synthesis. Chapters 3 and 4, examine and compare various EOS formalisms and data fitting for crystalline and non-crystalline materials, respectively. Chapter 5 details the reaction kinetics of detonating energetic materials. Chapter 6 investigates the interplay between static and dynamic (shock) studies. Finally, Chapters 7 and 8 introduce numerical simulations: molecular dynamics of energetic materials under either hydrostatic or uni-axial stress and ab-inito treatments of defects in crystalline materials. This timely volume meets the growing demand for a state-of-the art introduction and review of the most relevant aspects of static compression of energetic materials and will be a valuable reference to researchers and scientists working in academic, industrial and governmental research laboratories.