The physical and mechanical properties of GCRE-type fuel elements were determined from room temperature to 1650 deg F. The fuel elements were prepared by cladding Type 318 stainless steel sheet to a core containing 15 to 35 wt.% UO/ sub 2/ in either prealloyed Type 318 stainless steel or elemental iron-18 wt.% chromium-14 wt. % nickel-2.5 wt. % molybdenum. The tensile strength in the direction perpendicular to the rolling plane decreased from 24,600 psi at room temperature to 9,200 psi at 1650 deg F for the reference fuel plate, whose core contained 25 wt.% UO2 in the elemental alloy. The tensile strength in the longitudinal direction for this fuel element ranged from 54,800 psi at room temperature to 14,200 psi at 1650 deg F, with elongation in 2 in. ranging from 8 to 13 per cent. The extrapolated stress for 1000hr rupture life at 1650 deg F was 1800 psi, and a 1.4T bend was withstood without cracking. The mean linear thermal coefficient of expansion was 11.0 x 10−6 per deg F for the range 68 to 1700 deg F. (auth).

A review of contemporary actinide research that focuses on new advances in experiment and theory, and the interplay between these two realms Experimental and Theoretical Approaches to Actinide Chemistry offers a comprehensive review of the key aspects of actinide research. Written by noted experts in the field, the text includes information on new advances in experiment and theory and reveals the interplay between these two realms. The authors offer a multidisciplinary and multimodal approach to the nature of actinide chemistry, and explore the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry. The text covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques. The authors provide contemporary overviews of each topic area presented and describe the current and anticipated experimental approaches for the field, as well as the current and future computational chemistry and materials techniques. In addition, the authors explore the combination of experiment and theory. This important resource: Provides an essential resource the reviews the key aspects of contemporary actinide research Includes information on new advances in experiment and theory, and the interplay between the two Covers the basic science used in contemporary studies of the actinide systems, from basic synthesis to state-of-the-art spectroscopic and computational techniques Focuses on the interplay between multiple experiments and theory, as well as between basic and applied actinide chemistry Written for academics, students, professionals and researchers, this vital text contains a thorough review of the key aspects of actinide research and explores the most recent advances in experiment and theory.

This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.