Automotive engine knock limits the maximum operating compression ratio and ultimate thermodynamic efficiency of spark-ignition (SI) engines. In compression-ignition (CI) or diesel cycle engines, the premixed burn phase, which occurs shortly after injection, determines the time it takes for autoignition to occur. In order to improve engine efficiency and to recommend more efficient, cleaner-burning alternative fuels, they must understand the chemical kinetic processes that lead to autoignition in both SI and CI engines. These engines burn large molecular-weight blended fuels, a class to which the primary reference fuels (PRF) n-heptane and iso-octane belong. In this study, experiments were performed under engine like conditions in a high-pressure flow reactor using both the pure PRF fuels and their mixtures in the temperature range 550-880 K and 12.5 atm pressure. These experiments not only provide information on the reactivity of each fuel but also identify the major intermediate products formed during the oxidation process. A detailed chemical kinetic mechanism is used to simulate these experiments, and comparisons of experimentally measured and model predicted profiles for O2, CO, CO2, H2O and temperature rise are presented. Intermediates identified in the flow reactor are compared with those present in the computations, and the kinetic pathways leading to their formation are discussed. In addition, autoignition delay times measured in a shock tube over the temperature range 690-1220 K and at 40 atm pressure were simulated. Good agreement between experiment and simulation was obtained for both the pure fuels and their mixtures. Finally, quantitative values of major intermediates measured in the exhaust gas of a cooperative fuels research engine operating under motored engine conditions are presented together with those predicted by the detailed model.

Automotive engine knock limits the maximum operating compression ratio and ultimate thermodynamic efficiency of spark-ignition (SI) engines. In compression-ignition (CI) or diesel cycle engines the premixed urn phase, which occurs shortly after injection, determines the time it takes for autoignition to occur. In order to improve engine efficiency and to recommend more efficient, cleaner-burning alternative fuels, we must understand the chemical kinetic processes which lead to autoignition in both SI and CI engines. These engines burn large molecular-weight blended fuels, a class to which the primary reference fuels (PRF), n-heptane and isooctane belong. In this study, experiments were performed under engine-like conditions in a high pressure flow reactor using both the pure PRF fuels and their mixtures in the temperature range 550-880 K and at 12.5 atm pressure. These experiments not only provide information on the reactivity of each fuel but also identify the major intermediate products formed during the oxidation process. A detailed chemical kinetic mechanism is used to simulate these experiments and comparisons of experimentally measures and model predicted profiles for O2, CO, CO2, H2O and temperature rise are presented. Intermediates identified in the flow reactor are compared with those present in the computations, and the kinetic pathways leading to their formation are discussed. In addition, autoignition delay times measured in a shock tube over the temperature range 690- 1220 K and at 40 atm pressure were simulated. Good agreement between experiment and simulation was obtained for both the pure fuels and their mixtures. Finally, quantitative values of major intermediates measured in the exhaust gas of a cooperative fuels research engine operating under motored engine conditions are presented together with those predicted by the detailed method.

Computational Optimization of Internal Combustion Engines presents the state of the art of computational models and optimization methods for internal combustion engine development using multi-dimensional computational fluid dynamics (CFD) tools and genetic algorithms. Strategies to reduce computational cost and mesh dependency are discussed, as well as regression analysis methods. Several case studies are presented in a section devoted to applications, including assessments of: spark-ignition engines, dual-fuel engines, heavy duty and light duty diesel engines. Through regression analysis, optimization results are used to explain complex interactions between engine design parameters, such as nozzle design, injection timing, swirl, exhaust gas recirculation, bore size, and piston bowl shape. Computational Optimization of Internal Combustion Engines demonstrates that the current multi-dimensional CFD tools are mature enough for practical development of internal combustion engines. It is written for researchers and designers in mechanical engineering and the automotive industry.

This book discusses all aspects of advanced engine technologies, and describes the role of alternative fuels and solution-based modeling studies in meeting the increasingly higher standards of the automotive industry. By promoting research into more efficient and environment-friendly combustion technologies, it helps enable researchers to develop higher-power engines with lower fuel consumption, emissions, and noise levels. Over the course of 12 chapters, it covers research in areas such as homogeneous charge compression ignition (HCCI) combustion and control strategies, the use of alternative fuels and additives in combination with new combustion technology and novel approaches to recover the pumping loss in the spark ignition engine. The book will serve as a valuable resource for academic researchers and professional automotive engineers alike.

This research book provides state-of-the-art advances in several areas of energy generation from, and environmental impact of, fuels and biofuels. It also presents novel developments in the areas of biofuels and products from various feedstock materials along with thermal management, emission control and environmental issues. Availability of clean and sustainable energy is of paramount importance in all applications of energy, power, mobility and propulsion. This book is written by internationally renowned experts from around the globe. They provide the latest innovations in cleaner energy utilization for a wide range of devices. The energy and environment sustainability requires a multipronged approach involving development and utilization of new and renewable fuels, design of fuel-flexible combustion systems and novel and environmentally friendly technologies for improved fuel use. This book serves as a good reference for practicing engineers, educators and research professionals.

This thesis investigates the combustion chemistry of cyclohexane, methylcyclohexane, and ethylcyclohexane on the basis of state-of-the-art synchrotron radiation photoionization mass spectrometry experiments, quantum chemistry calculations, and extensive kinetic modeling. It explores the initial decomposition mechanism and distribution of the intermediates, proposes a novel formation mechanism of aromatics, and develops a detailed kinetic model to predict the three cycloalkanes’ combustion properties under a wide range of conditions. Accordingly, the thesis provides an essential basis for studying much more complex cycloalkanes in transport fuels and has applications in engine and fuel design, as well as emission control.