Organotitanium Reagents in Organic Synthesis
Title | Organotitanium Reagents in Organic Synthesis PDF eBook |
Author | Manfred T. Reetz |
Publisher | Springer |
Pages | 256 |
Release | 1986 |
Genre | Chemical tests and reagents |
ISBN |
Organotitanium Reagents in Organic Synthesis
Title | Organotitanium Reagents in Organic Synthesis PDF eBook |
Author | Manfred Reetz |
Publisher | |
Pages | 252 |
Release | 2014-01-15 |
Genre | |
ISBN | 9783642707056 |
Organotitanium Reagents in Organic Synthesis
Title | Organotitanium Reagents in Organic Synthesis PDF eBook |
Author | Manfred T. Reetz |
Publisher | Springer Science & Business Media |
Pages | 244 |
Release | 2013-11-11 |
Genre | Science |
ISBN | 3642707041 |
Titanium has been used to perform many kinds of reactions in organic and inorganic chemistry. The present book is concerned primarily with a new development in titanium chemistry which is useful in organic synthesis. In 1979/80 it was discovered that the titanation of classical carbanions using C1TiX leads to species with reduced basicity and reactivity. This increases 3 chemo-, regio-and stereo selectivity in reactions with organic compounds such as aldehydes, ketones and alkyl halides. Many new examples have been reported in recent times. Since the nature of the ligand X at titanium can be widely varied, the electronic and steric nature of the reagents is easily controlled. This helps in predicting the stereochemical outcome of many of the C-C bond forming reactions, but the trial and error method is still necessary in other cases. One of the ultimate objectives of chemistry is to understand correlations between structure and reactivity. Although this goal has not been reached in the area of organotitanium chemistry, appreciable progress has been made. A great deal of physical and computational data of organotitanium compounds described in the current and older literature (e. g. , Ziegler-Natta type catalysts) has been reported by polymer, inorganic and theoretical chemists. It is summarized in Chapter 2 of this book, because some aspects are useful in understanding reactivity and selectivity of organo titanium compounds in organic synthesis as described in the chapters which follow.
Organotitanium Reagents in Organic Chemistry
Title | Organotitanium Reagents in Organic Chemistry PDF eBook |
Author | Manfred T. Reetz |
Publisher | |
Pages | 824 |
Release | 1992 |
Genre | Organic compounds |
ISBN |
Organometallics in Synthesis
Title | Organometallics in Synthesis PDF eBook |
Author | Manfred Schlosser |
Publisher | John Wiley & Sons |
Pages | 1008 |
Release | 2013-05-28 |
Genre | Science |
ISBN | 1118484754 |
WINNER of the 2013 PROSE Award in Chemistry & Physics This latest edition enables readers to master new classes of organometallic compounds and syntheses A popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so that readers can easily replicate the results in their own labs. Moreover, each chapter has been written by a world leader in the field of organometallics in organic synthesis. These authors offer hands-on guidance and practical examples illustrating the preparation of organometallics and its application in organic synthesis. This Third Manual of Organometallics in Synthesis features completely new content and topics, with an eye towards providing researchers with the most useful and practical reference on the synthesis of organometallics. Organized into chapters by type of organometallic compound, the book covers: Organoalkali chemistry Organomagnesium and organozinc chemistry Organosilicon and relating organotin chemistry Organoiron chemistry Organopalladium chemistry Within each chapter, readers will find background information to learn more about the class of organometallics as well as mechanistic considerations. The authors thoroughly discuss the various methods of preparing the organometallic compounds presented in the book and outline their uses in synthetic reactions. In addition to current applications, the authors explore future research opportunities for each organometallic class. References at the end of each chapter enable readers to explore all the topics in greater depth. More and more industrial processes rely on organometallic chemistry. As a result, readers will find this book's step-by-step instructions essential in such fields as natural product synthesis, pharmaceuticals, fine chemicals, biotechnology, polymers, and materials science.
Titanium and Zirconium in Organic Synthesis
Title | Titanium and Zirconium in Organic Synthesis PDF eBook |
Author | Ilan Marek |
Publisher | Wiley-VCH Verlag GmbH |
Pages | 512 |
Release | 2002-01-01 |
Genre | Science |
ISBN | 9783527304288 |
During the last years, the role of titanium and zirconium in organic synthesis has dramatically increased and nowadays, no synthetic chemist can afford to be without a sound knowledge of this fascinating organometal chemistry. This unique book, edited by Ilan Marek, thus summarizes the numerous applications and developments of these two group 4 early transition metal complexes. A plethora of internationally renowned experts and leading scientists in this field cover all the significant aspects of this increasingly important part of organic chemistry and bring the reader up to date. A particularly attractive and useful feature is the inclusion of typical experimental procedures, chosen for broad utility and application. This comprehensive demonstrates the diversity and the applications of these important compounds and is a must-have for all chemists working in organometallic or synthetic organic chemistry.
Utilization of Organotitanium Compounds in Organic Synthesis
Title | Utilization of Organotitanium Compounds in Organic Synthesis PDF eBook |
Author | Walter Keung |
Publisher | |
Pages | 468 |
Release | 2000 |
Genre | |
ISBN |