Monatomic Two-Dimensional Layers: Properties, Fabrication and Industrial Applications provides a detailed examination on basic principles and state-of-the-art experimental techniques for monatomic layers on model surfaces, and in operating devices. Both conventional surface science and novel 2D materials science are included. The reader is guided through an introduction to the basic science of the field that is followed by advanced science specific to the system. Characterization techniques, the principles of state-of-the-art instruments for monatomic layers, and topics, including positron diffraction, time-resolved photoemission spectroscopy, surface transport measurements, and operando nanospectroscopy are also covered. Researchers, graduate students and professionals will find this volume invaluable to acquire a deeper knowledge of the basic science, preparation, and experimental characterization techniques for 2D materials. Industrial technicians and operators will find it a useful overview of surface science related methods for fabrication and characterization of 2D materials. - Gives comprehensive access to the properties of 2D materials, selected fabrication methods, and advanced characterization tools - Discusses structure analysis by diffraction methods and 'operando' spectroscopy to provide direct information on device performance for industrial applications - Written by authors who developed the techniques and have conducted extensive research on monatomic layers

This book reports the establishment of a single-atomic layer metal of In and a novel (In, Mg) ultrathin film on Si(111) surfaces. A double-layer phase of In called “rect” has been extensively investigated as a two-dimensional metal. Another crystalline phase called “hex” was also suggested, but it had not been established due to difficulty in preparing the sample. The author succeeded in growing the large and high-quality sample of the hex phase and revealed that it is a single-layer metal. The author also established a new triple-atomic layer (In, Mg) film with a nearly freestanding character by Mg deposition onto the In double layer. This work proposes a novel method to decouple ultrathin metal films from Si dangling bonds. The present study demonstrates interesting properties of indium itself, which is a p-block metal both with metallicity and covalency. In this book, readers also see principles of various surface analysis techniques and learn how to use them and analyze the results in the real systems. This book is useful to researchers and students interested in surface science, particularly ultrathin metal films on semiconductor surfaces.

X-ray experiments have been used widely in materials science, and conventional spectroscopy has been based on linear responses in light–matter interactions. Recent development of ultrafast light sources of tabletop lasers and X-ray free electron lasers reveals nonlinear optical phenomena in the X-ray region, and the measurement signals have been found to carry a further wealth of information on materials. This book overviews such nonlinear X-ray spectroscopy and its related issues for materials science. Each chapter is written by pioneers in the field and skillfully reviews the topics of nonlinear spectroscopy including X-ray multi-photon absorption and X-ray second harmonic generation. The chapters are divided depending on photon wavelength, ranging from extreme ultraviolet to (soft) X-ray. To facilitate readers’ comprehensive understanding, some of the chapters cover the conventional linear X-ray spectroscopy and basic principles of the non-linear responses. The book is mainly accessible as a primer for junior/senior- or graduate-level readers, and it also serves as a useful reference or guide even for established researchers in optical spectroscopy. The book offers readers opportunities to benefit from cutting-edge research in this new area of nonlinear X-ray spectroscopy.

2D Metals: Fundamentals, Emerging Applications, and Challenges delves into the state-of- the-art advancements in utilizing 2D metals for emerging applications, encompassing a comprehensive overview of synthetic methodologies and characterization techniques provided by leading experts in the field. 2D nanomaterials have emerged as highly promising candidates for a diverse array of cutting-edge applications, spanning energy and biomedicine, owing to their adjustable electrochemical properties, versatility, and exceptional mechanical resilience. Notably, carbon-based 2D materials have already demonstrated extensive utility across various domains. Meanwhile, 2D metals, often referred to as Metallenes, represent a burgeoning class of materials with broad reaching potential. In contrast to alternative 2D materials like graphene and transition metal chalcogenides, as well as bulk metals, 2D metals exhibit remarkable conductivity, expansive surface area, and customizable electronic and optoelectronic characteristics. This book explores the influence of structural modifications on the properties of 2D metals and addresses the myriad challenges associated with their burgeoning applications. Each chapter, authored by esteemed specialists from across the globe, offers invaluable insights, rendering this book an indispensable resource for students while furnishing researchers and industry professionals with novel guidance and perspectives.

Electrochemical processes and methods are basic to many important scientific disciplines, materials science and nanotechnology being only two keywords. For the first time in more than twenty years this volume presents a critical survey of the foundations, methodology and applications of electrochemical phase formation and growth processes. Written by a team of three internationally renowned authors, it is an invaluable source of information for all scientists concerned with electrocrystallization of metals or the in-situ characterization of electron-conducting surfaces. Not only the numerous illustrations (partly in colour) but also the vast number of references covering the literature up to and including 1995 make this volume indispensable for every laboratory working in electrochemical or materials science.

Discontinuous (first-order) phase transitions constitute the most fundamental and widespread type of structural transitions existing in Nature, forming a large majority of the transitions found in elemental crystals, alloys, inorganic compounds, minerals and complex fluids. Nevertheless, only a small part of them, namely, weakly discontinuous transformations, were considered by phenomenological theories, leaving aside the most interesting from a theoretical point of view and the most important for application cases. Discontinuous Phase Transitions in Condensed Matter introduces a density-wave approach to phase transitions which results in a unified, symmetry-based, model-free theory of the weak crystallization of molecular mixtures to liquid-crystalline mesophases, strongly discontinuous crystallization from molten metals and alloys to conventional, fully segregated crystals, to aperiodic, quasi-crystalline structures. Assembly of aperiodic closed virus capsids with non-crystallographic symmetry also falls into the domain of applicability of the density-wave approach.The book also considers the applicability domains of the symmetry-based approach in physics of low-dimensional systems. It includes comparisons of stability of different surface superstructures and metal monoatomic coverage structures on the surface of single-crystalline substrates. The example of the twisted graphene bilayer demonstrates how parametrization in the spirit of an advanced phenomenological approach can establish symmetry-controlled, and therefore model-free, links between geometrical parameters of the twisted bilayer structure and reconstruction of its Brillouin zone and energy bands.

After a brief introduction to the fundamental properties of graphene, this book focuses on synthesis, characterization and application of various types of two-dimensional (2D) nanocarbons ranging from single/few layer graphene to carbon nanowalls and graphene oxides. Three major synthesis techniques are covered: epitaxial growth of graphene on SiC,