Molecular Physics and Hypersonic Flows bridges the gap between the fluid dynamics and molecular physics communities, emphasizing the role played by elementary processes in hypersonic flows. In particular, the work is primarily dedicated to filling the gap between microscopic and macroscopic treatments of the source terms to be inserted in the fluid dynamics codes. The first part of the book describes the molecular dynamics of elementary processes both in the gas phase and in the interaction with surfaces by using quantum mechanical and phenomenological approaches. A second group of contributions describes thermodynamics and transport properties of air components, with special attention to the transport of internal energy. A series of papers is devoted to the experimental and theoretical study of the flow of partially ionized gases. Subsequent contributions treat modern computational techniques for 3-D hypersonic flow. Non-equilibrium vibrational kinetics are then described, together with the coupling of vibration-dissociation processes as they affect hypersonic flows. Special emphasis is given to the interfacing of non-equilibrium models with computational fluid dynamics methods. Finally, the last part of the book deals with the application of direct Monte Carlo methods in describing rarefied flows.

Emphasis is placed on the analysis of translational, rotational, vibrational and electronically excited state kinetics, coupled to the electron Boltzmann equation.

Hypersonic Flow Theory presents the fundamentals of fluid mechanics, focusing on the hypersonic flow theory and approaches in theoretical aerodynamics. This book discusses the assumptions underlying hypersonic flow theory, unified supersonic-hypersonic similitude, two-dimensional and axisymmetric bodies, and circular cylinder. The constant-streamtube-area approximation, streamtube-continuity methods, and tangent-wedge and tangent-cone are also deliberated. This text likewise covers the similar laminar boundary layer solutions, bluntness induced interactions on slender bodies, and free molecule transfer theory. The dynamics of hypersonic flight or hypersonic wing theory, magnetohydrodynamic theory, or any developments involving treatment of the Boltzmann equation are not included. This publication is intended for hypersonic aerodynamicists, students, and researchers conducting work on the hypersonic flow phenomena.

In the present monograph, we develop the kinetic theory of transport phenomena and relaxation processes in the flows of reacting gas mixtures and discuss its applications to strongly non-equilibrium conditions. The main attention is focused on the influence of non-equilibrium kinetics on gas dynamics and transport properties. Closed systems of fluid dynamic equations are derived from the kinetic equations in different approaches. We consider the most accurate approach taking into account the state-to-state kinetics in a flow, as well as simplified multi-temperature and one-temperature models based on quasi-stationary distributions. Within these approaches, we propose the algorithms for the calculation of the transport coefficients and rate coefficients of chemical reactions and energy exchanges in non-equilibrium flows; the developed techniques are based on the fundamental kinetic theory principles. The theory is applied to the modeling of non-equilibrium flows behind strong shock waves, in the boundary layer, and in nozzles. The comparison of the results obtained within the frame of different approaches is presented, the advantages of the new state-to-state kinetic model are discussed, and the limits of validity for simplified models are established. The book can be interesting for scientists and graduate students working on physical gas dynamics, aerothermodynamics, heat and mass transfer, non-equilibrium physical-chemical kinetics, and kinetic theory of gases.

This book is a self-contained text for those students and readers interested in learning hypersonic flow and high-temperature gas dynamics. It assumes no prior familiarity with either subject on the part of the reader. If you have never studied hypersonic and/or high-temperature gas dynamics before, and if you have never worked extensively in the area, then this book is for you. On the other hand, if you have worked and/or are working in these areas, and you want a cohesive presentation of the fundamentals, a development of important theory and techniques, a discussion of the salient results with emphasis on the physical aspects, and a presentation of modern thinking in these areas, then this book is also for you. In other words, this book is designed for two roles: 1) as an effective classroom text that can be used with ease by the instructor, and understood with ease by the student; and 2) as a viable, professional working tool for engineers, scientists, and managers who have any contact in their jobs with hypersonic and/or high-temperature flow.

Chemical Kinetics relates to the rates of chemical reactions and factors such as concentration and temperature, which affects the rates of chemical reactions. Such studies are important in providing essential evidence as to the mechanisms of chemical processes. The book is designed to help the reader, particularly students and researchers of physical science, understand the chemical kinetics mechanics and chemical reactions. The selection of topics addressed and the examples, tables and graphs used to illustrate them are governed, to a large extent, by the fact that this book is aimed primarily at physical science (mainly chemistry) technologists. Undoubtedly, this book contains "must read" materials for students, engineers, and researchers working in the chemistry and chemical kinetics area. This book provides valuable insight into the mechanisms and chemical reactions. It is written in concise, self-explanatory and informative manner by a world class scientists in the field.