Atmospheric water plays a key role in climate. Water vapour is the most important greenhouse gas and its condensed forms exert a profound influence on both incoming solar and outgoing infrared radiation. Unfortunately, accurate, height-resolved global-scale measurements of atmospheric humidity are difficult to obtain. The change in concentration of five orders of magnitude form the ground to the stratosphere means there is no standard instrument that will measure everywhere. This has led to different measuring techniques, all with strengths and weaknesses. This book assesses all presently available techniques that are used in monitoring networks. Special weight is given to presenting the different technical concepts, the accuracy of different sensor types, addresses calibration issues and retrieval aspects.

Atmospheric Water Vapor contains the technical proceedings of the International Workshop on Atmospheric Water Vapor held in Vail, Colorado, on September 11-13, 1979. The papers assess the state-of-the-art in measurement, modeling, and application of atmospheric water vapor properties and highlight important problems that require further effort in order to better understand the atmosphere itself as well as the electromagnetic propagation through the atmosphere. Comprised of 39 chapters, this book begins with a discussion on the optics and spectroscopy of water vapor. Some actual spectra showing the problems specific to the water molecule are described, along with the method used to calculate precise vibration-rotation energy levels and wave functions. Atmospheric infrared transmission measurements in maritime locations are also presented. Subsequent sections explore microwave and millimeter wave phenomena; geoastrophysical applications; and in situ measurements, remote sensing, and meteorology of water vapor. The final chapters deal with the microphysics and atmospheric chemistry of water vapor. This monograph will be of interest to scientists from universities, government agencies, research laboratories, and industry.

This report compares simultaneous spectroscopic and radiometric measurements of atmospheric water vapor above aircraft flight levels and determines the water vapor overburden. The measurements taken during 15 flights indicate that (1) both techniques give the same water vapor overburden to within 1 micrometer of precipitable water vapor, and (2) the median water vapor overburden is 6.5 micrometers precipitable water vapor at 41,000 ft (approx 180 mbar pressure) in the mid-latitude western United States during the summer/fall season, with a range from 4 to 11 micrometers.