The new edition of the cornerstone text on electrochemistry Spans all the areas of electrochemistry, from the basicsof thermodynamics and electrode kinetics to transport phenomena inelectrolytes, metals, and semiconductors. Newly updated andexpanded, the Third Edition covers important new treatments, ideas,and technologies while also increasing the book's accessibility forreaders in related fields. Rigorous and complete presentation of the fundamentalconcepts In-depth examples applying the concepts to real-life designproblems Homework problems ranging from the reinforcing to the highlythought-provoking Extensive bibliography giving both the historical developmentof the field and references for the practicing electrochemist.

Using electrochemical impedance spectroscopy in a broad range of applications This book provides the background and training suitable for application of impedance spectroscopy to varied applications, such as corrosion, biomedical devices, semiconductors and solid-state devices, sensors, batteries, fuel cells, electrochemical capacitors, dielectric measurements, coatings, electrochromic materials, analytical chemistry, and imaging. The emphasis is on generally applicable fundamentals rather than on detailed treatment of applications. With numerous illustrative examples showing how these principles are applied to common impedance problems, Electrochemical Impedance Spectroscopy is ideal either for course study or for independent self-study, covering: Essential background, including complex variables, differential equations, statistics, electrical circuits, electrochemistry, and instrumentation Experimental techniques, including methods used to measure impedance and other transfer functions Process models, demonstrating how deterministic models of impedance response can be developed from physical and kinetic descriptions Interpretation strategies, describing methods of interpretating of impedance data, ranging from graphical methods to complex nonlinear regression Error structure, providing a conceptual understanding of stochastic, bias, and fitting errors in frequency-domain measurements An overview that provides a philosophy for electrochemical impedance spectroscopy that integrates experimental observation, model development, and error analysis This is an excellent textbook for graduate students in electrochemistry, materials science, and chemical engineering. It's also a great self-study guide and reference for scientists and engineers who work with electrochemistry, corrosion, and electrochemical technology, including those in the biomedical field, and for users and vendors of impedance-measuring instrumentation.

Intercalation Chemistry introduces the specialist reader to the breadth of intercalation chemistry and the newcomer to the diverse research opportunities and challenges available in synthetic and reaction chemistry and also in the controlled modification of physical properties. Topics covered range from graphite chemistry to sheet silicate intercalates, diffusion and shape-selective catalysis in zeolites, organic and organometallic intercalation compounds of the transition metal dichalcogenides, and solvated intercalation compounds of layered chalcogenide and oxide bronzes. This book is comprised of 18 chapters and begins with an introduction to intercalation chemistry. The discussions that follow focus on the intercalation chemistry of graphite and of complex oxides with both two (clays and acid phosphates)- and three (zeolites)-dimensional structures, along with organic conversions that have been discovered using essentially smectite (i.e., montmorillonite- and hectorite-based) intercalates. The next chapters focus on ß-aluminas, acid salts of tetravalent metals with layered structure, and layered chalcogenides and halides with simple and hydrated cations as well as organic and organometallic ions. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and tungsten. The final chapter touches on the physical properties of some intercalation compounds of the dichalcogenides. This book is intended for researchers in the various materials science disciplines.

A Comprehensive Reference for Electrochemical Engineering Theory and Application From chemical and electronics manufacturing, to hybrid vehicles, energy storage, and beyond, electrochemical engineering touches many industries—any many lives—every day. As energy conservation becomes of central importance, so too does the science that helps us reduce consumption, reduce waste, and lessen our impact on the planet. Electrochemical Engineering provides a reference for scientists and engineers working with electrochemical processes, and a rigorous, thorough text for graduate students and upper-division undergraduates. Merging theoretical concepts with widespread application, this book is designed to provide critical knowledge in a real-world context. Beginning with the fundamental principles underpinning the field, the discussion moves into industrial and manufacturing processes that blend central ideas to provide an advanced understanding while explaining observable results. Fully-worked illustrations simplify complex processes, and end-of chapter questions help reinforce essential knowledge. With in-depth coverage of both the practical and theoretical, this book is both a thorough introduction to and a useful reference for the field. Rigorous in depth, yet grounded in relevance, Electrochemical Engineering: Introduces basic principles from the standpoint of practical application Explores the kinetics of electrochemical reactions with discussion on thermodynamics, reaction fundamentals, and transport Covers battery and fuel cell characteristics, mechanisms, and system design Delves into the design and mechanics of hybrid and electric vehicles, including regenerative braking, start-stop hybrids, and fuel cell systems Examines electrodeposition, redox-flow batteries, electrolysis, regenerative fuel cells, semiconductors, and other applications of electrochemical engineering principles Overlapping chemical engineering, chemistry, material science, mechanical engineering, and electrical engineering, electrochemical engineering covers a diverse array of phenomena explained by some of the important scientific discoveries of our time. Electrochemical Engineering provides the critical understanding required to work effectively with these processes as they become increasingly central to global sustainability.

Excellent teaching and resource material . . . it is concise, coherently structured, and easy to read . . . highly recommended for students, engineers, and researchers in all related fields." -Corrosion on the First Edition of Fundamentals of Electrochemical Deposition From computer hardware to automobiles, medical diagnostics to aerospace, electrochemical deposition plays a crucial role in an array of key industries. Fundamentals of Electrochemical Deposition, Second Edition is a comprehensive introduction to one of today's most exciting and rapidly evolving fields of practical knowledge. The most authoritative introduction to the field so far, the book presents detailed coverage of the full range of electrochemical deposition processes and technologies, including: * Metal-solution interphase * Charge transfer across an interphase * Formation of an equilibrium electrode potential * Nucleation and growth of thin films * Kinetics and mechanisms of electrodeposition * Electroless deposition * In situ characterization of deposition processes * Structure and properties of deposits * Multilayered and composite thin films * Interdiffusion in thin film * Applications in the semiconductor industry and the field of medicine This new edition updates the prior edition to address the new developments in the science and its applications, with new chapters on innovative applications of electrochemical deposition in semiconductor technology, magnetism and microelectronics, and medical instrumentation. Added coverage includes such topics as binding energy, nanoclusters, atomic force, and scanning tunneling microscopy.Example problems at the end of chapters and other features clarify and improve understanding of the material. Written by an author team with extensive experience in both industry and academe, this reference and text provides a well-rounded introduction to the field for students, as well as a means for professional chemists, engineers, and technicians to expand and sharpen their skills in using the technology.

Viscoelastic behavior reflects the combined viscous and elastic responses, under mechanical stress, of materials which are intermediate between liquids and solids in character. Polymers the basic materials of the rubber and plastic industries and important to the textile, petroleum, automobile, paper, and pharmaceutical industries as well exhibit viscoelasticity to a pronounced degree. Their viscoelastic properties determine the mechanical performance of the final products of these industries, and also the success of processing methods at intermediate stages of production. Viscoelastic Properties of Polymers examines, in detail, the effects of the many variables on which the basic viscoelastic properties depend. These include temperature, pressure, and time; polymer chemical composition, molecular weight and weight distribution, branching and crystallinity; dilution with solvents or plasticizers; and mixture with other materials to form composite systems. With guidance by molecular theory, the dependence of viscoelastic properties on these variables can be simplified by introducing certain ancillary concepts such as the fractional free volume, the monomeric friction coefficient, and the spacing between entanglement loci, to provide a qualitative understanding and in many cases a quantitative prediction of how to achieve desired results. The phenomenological theory of viscoelasticity which permits interrelation of the results of different types of experiments is presented first, with many useful approximation procedures for calculations given. A wide variety of experimental methods is then described, with critical evaluation of their applicability to polymeric materials of different consistencies and in different regions of the time scale (or, for oscillating deformations, the frequency scale). A review of the present state of molecular theory follows, so that viscoelasticity can be related to the motions of flexible polymer molecules and their entanglements and network junctions. The dependence of viscoestic properties on temperature and pressure, and its descriptions using reduced variables, are discussed in detail. Several chapters are then devoted to the dependence of viscoelastic properties on chemical composition, molecular weight, presence of diluents, and other features, for several characteristic classes of polymer materials. Finally, a few examples are given to illustrate the many potential applications of these principles to practical problems in the processing and use of rubbers, plastics, and fibers, and in the control of vibration and noise. The third edition has been brought up to date to reflect the important developments, in a decade of exceptionally active research, which have led to a wider use of polymers, and a wider recognition of the importance and range of application of viscoelastic properties. Additional data have been incorporated, and the book s chapters on dilute solutions, theory of undiluted polymers, plateau and terminal zones, cross-linked polymers, and concentrated solutions have been extensively rewritten to take into account new theories and new experimental results. Technical managers and research workers in the wide range of industries in which polymers play an important role will find that the book provides basic information for practical applications, and graduate students in chemistry and engineering will find, in its illustrations with real data and real numbers, an accessible introduction to the principles of viscoelasticity.