Irreducible Tensor Methods: An Introduction for Chemists explains the theory and application of irreducible tensor operators. The book discusses a compact formalism to describe the effect that results on an arbitrary function of a given set of coordinates when that set is subjected to a rotation about its origin. The text also explains the concept of irreducible tensor operators, particularly, as regards the transformation properties of operators under coordinate transformations, and, in a special way, the group of rotations. The book examines the systematic construction of compound tensor operators from simple operators to classify the behavior of any operator under coordinate rotations. This classification is a significant component of the irreducible tensor method. The text explains the use of the 6-j and 9-j symbols to complete theoretical concepts that are applied in irreducible tensor methods dealing with problems of atomic and molecular physics. The book describes the matrix elements in multielectron systems, as well as the reduced matrix elements found in these systems. The book is suitable for nuclear physicists, molecular physicists, scientists, and academicians in the field of quantum mechanics or advanced chemistry.

Suitable for advanced undergraduates and graduate students, this text covers V coefficients for the octahedral group and other symmetry groups, W coefficients, irreducible products and their matrix elements, two-electron formulae for the octahedral group, fractional parentage, X coefficients, spin, and matrices of one-electron operators. 1962 edition.

This text focuses on the physics of symmetries, developing symmetries and transformations through concrete physical examples and contexts rather than presenting the information axiomatically, mathematically, and abstractly. Readers are introduced gradually to advanced mathematical procedures, including the Wigner and Racah algebras and their applications to various symmetry groups. The book also includes some of the latest research on the use of non-invariance and non-compact groups in the consideration of relativistic and many-particle problems of atoms and nuclei.This book is an updated replacement for the text Irreducible Tensorial Sets (Academic Press, 1959). Parts A and B of the present book grew out of occasional lectures in the intervening decades at the University of Chicago, where it became neccessary to update or elaborate upon certain points. Part C has been built more recently to deal with innovations and new information in the field of mathematical physics. The book as a whole develops the subject of symmetry from a physical point of view, allowing students and researchers to gain new insight on their subject. This book can be used both as a text and as a reference by students and scientists in the field.Adapts and extends the earlier Irreducible Tensor Sets (Academic Press, 1959) to classroom useExtends to multi-particle systems and relativityIncludes problems in each chapter for homework assignmentsEmbraces the latest research on non-invariance groups