Geochemical modeling is an important tool in environmental studies, and in the areas of subsurface and surface hydrology, pedology, water resources management, mining geology, geothermal resources, hydrocarbon geology, and related areas dealing with the exploration and extraction of natural resources. The book fills a gap in the literature through its discussion of geochemical modeling, which simulates the chemical and physical processes affecting the distribution of chemical species in liquid, gas, and solid phases. Geochemical modeling applies to a diversity of subsurface environments, from the vadose zone close to the Earth’s surface, down to deep-seated geothermal reservoirs. This book provides the fundamental thermodynamic concepts of liquid-gas-solid phase systems. It introduces the principal types of geochemical models, such as speciation, reaction-path or forward, inverse- and reactive-transport models, together with examples of the most common codes and the best-practices for constructing geochemical models. The physical laws describing homogeneous and heterogeneous chemical reactions, their kinetics, and the transport of reactive solutes are presented. The partial differential or algebraic equations representing these laws, and the principal numerical methods that allow approximate solutions of these equations that can provide useful solutions to model different geochemical processes, are discussed in detail. Case studies applying geochemical models in different scientific areas and environmental settings, conclude the book. The book is addressed to students, teachers, other professionals, and to the institutions involved in water, geothermal and hydrocarbon resources, mining, and environmental management. The book should prove useful to undergraduate and graduate students, postgraduates, professional geologists and geophysicists, engineers, environmental scientists, soil scientists, hydrochemists, and others interested in water and geochemistry.

The single most important factor for the successful application of a geochemical model is the knowledge and experience of the individual(s) conducting the modeling. Geochemical Modeling for Mine Site Characterization and Remediation is the fourth of six volumes in the Management Technologies for Metal Mining Influenced Water series about technologies for management of metal mine and metallurgical process drainage. This handbook describes the important components of hydrogeochemical modeling for mine environments, primarily those mines where sulfide minerals are present—metal mines and coal mines. It provides general guidelines on the strengths and limitations of geochemical modeling and an overview of its application to the hydrogeochemistry of both unmined mineralized sites and those contaminated from mineral extraction and mineral processing. The handbook includes an overview of the models behind the codes, explains vital geochemical computations, describes several modeling processes, provides a compilation of codes, and gives examples of their application, including both successes and failures. Hydrologic modeling is also included because mining contaminants most often migrate by surface water and groundwater transport, and contaminant concentrations are a function of water residence time as well as pathways. This is an indispensable resource for mine planners and engineers, environmental managers, land managers, consultants, researchers, government regulators, nongovernmental organizations, students, stakeholders, and anyone with an interest in mining influenced water. The other handbooks in the series are Basics of Metal Mining Influenced Water; Mitigation of Metal Mining Influenced Water; Mine Pit Lakes: Characteristics, Predictive Modeling, and Sustainability; Techniques for Predicting Metal Mining Influenced Water; and Sampling and Monitoring for the Mine Life Cycle.

This extensively updated new edition of the widely acclaimed Treatise on Geochemistry has increased its coverage beyond the wide range of geochemical subject areas in the first edition, with five new volumes which include: the history of the atmosphere, geochemistry of mineral deposits, archaeology and anthropology, organic geochemistry and analytical geochemistry. In addition, the original Volume 1 on "Meteorites, Comets, and Planets" was expanded into two separate volumes dealing with meteorites and planets, respectively. These additions increased the number of volumes in the Treatise from 9 to 15 with the index/appendices volume remaining as the last volume (Volume 16). Each of the original volumes was scrutinized by the appropriate volume editors, with respect to necessary revisions as well as additions and deletions. As a result, 27% were republished without major changes, 66% were revised and 126 new chapters were added. In a many-faceted field such as Geochemistry, explaining and understanding how one sub-field relates to another is key. Instructors will find the complete overviews with extensive cross-referencing useful additions to their course packs and students will benefit from the contextual organization of the subject matter Six new volumes added and 66% updated from 1st edition. The Editors of this work have taken every measure to include the many suggestions received from readers and ensure comprehensiveness of coverage and added value in this 2nd edition The esteemed Board of Volume Editors and Editors-in-Chief worked cohesively to ensure a uniform and consistent approach to the content, which is an amazing accomplishment for a 15-volume work (16 volumes including index volume)!

The expansion of unconventional petroleum resources in the recent decade and the rapid development of computational technology have provided the opportunity to develop and apply 3D numerical modeling technology to simulate the hydraulic fracturing of shale and tight sand formations. This book presents 3D numerical modeling technologies for hydraulic fracturing developed in recent years, and introduces solutions to various 3D geomechanical problems related to hydraulic fracturing. In the solution processes of the case studies included in the book, fully coupled multi-physics modeling has been adopted, along with innovative computational techniques, such as submodeling. In practice, hydraulic fracturing is an essential project component in shale gas/oil development and tight sand oil, and provides an essential measure in the process of drilling cuttings reinjection (CRI). It is also an essential measure for widened mud weight window (MWW) when drilling through naturally fractured formations; the process of hydraulic plugging is a typical application of hydraulic fracturing. 3D modeling and numerical analysis of hydraulic fracturing is essential for the successful development of tight oil/gas formations: it provides accurate solutions for optimized stage intervals in a multistage fracking job. It also provides optimized well-spacing for the design of zipper-frac wells. Numerical estimation of casing integrity under stimulation injection in the hydraulic fracturing process is one of major concerns in the successful development of unconventional resources. This topic is also investigated numerically in this book. Numerical solutions to several other typical geomechanics problems related to hydraulic fracturing, such as fluid migration caused by fault reactivation and seismic activities, are also presented. This book can be used as a reference textbook to petroleum, geotechnical and geothermal engineers, to senior undergraduate, graduate and postgraduate students, and to geologists, hydrogeologists, geophysicists and applied mathematicians working in this field. This book is also a synthetic compendium of both the fundamentals and some of the most advanced aspects of hydraulic fracturing technology.

High temperature, high oil pressure, oil and gas well completion testing have always been a technical challenge and basic theoretical research is one of the key factors needed to ensure a successful completion test. The completion test basic theory includes: a stress analysis of the completion string, completion string buckling behavior, and temperature and pressure distribution prediction. The completion string is the main bearing and power transmission component for oil and gas well operations and production, and it is required to take on a combination of loads, which result in completion string deformation. Because of these complex relationships, completion string stress analysis has become increasingly more complicated. This book discusses the characters of tubular strings in HTHP (High Temperature - High Pressure) oil and gas wells. These characters include the mechanical behavior of tubular strings and the temperature and pressure variation of tubular strings in different conditions. Mathematical models are established for different conditions and solution existence and uniqueness of some models is discussed, providing algorithms corresponding to the different models. Numerical experiments are presented to verify the validity of models and the feasibility of algorithms, and the impact of the parameters of models for oil and gas wells is also discussed. This book is written for production and testing engineers to provide them with the tools to deal more effectively with the numerical decisions they have to take and for researchers and technicians in petroleum and gas testing and production engineering. Finally, it is also intended to serve as a reference book for mathematicians, college teachers and students.

The discipline of Integrated Environmental Modelling (IEM) has developed in order to solve complex environmental problems, for example understanding the impacts of climate change on the physical environment. IEM provides methods to fuse or link models together, this in turn requires facilities to make models discoverable and also to make the outputs of modelling easily visualized. The vision and challenges for IEM going forward are summarized by leading proponents. Several case studies describe the application of model fusion to a range of real-world problems including integrating groundwater and recharge models within the UK Environment Agency, and the development of ‘catastrophe’ models to predict better the impact of natural hazards. Communicating modelling results to end users who are often not specialist modellers is also an emerging area of research addressed within the volume. Also included are papers that highlight current developments of the technology platforms underpinning model fusion.

This book illustrates the diversity of hypogene speleogenetic processes and void-conduit patterns depending on variations of the geological environments by presenting regional and cave-specific case studies. The cases include both well-known and newly recognized hypogene karst regions and caves of the world. They all focus on geological, hydrogeological, geodynamical and evolutionary contexts of hypogene speleogenesis. The last decade has witnessed the boost in recognition of the possibility, global occurrence, and practical importance of hypogene karstification (speleogenesis), i.e. the development of solutional porosity and permeability by upwelling flow, independent of recharge from the overlying or immediately adjacent surface. Hypogene karst has been identified and documented in many regions where it was previously overlooked or misinterpreted. The book enriches the basis for generalization and categorization of hypogene karst and thus improves our ability to adequately model hypogene karstification and predict related porosity and permeability. It is a book which benefits every researcher, student, and practitioner dealing with karst.