The book intends to give a state-of-the-art overview of flexoelectricity, a linear physical coupling between mechanical (orientational) deformations and electric polarization, which is specific to systems with orientational order, such as liquid crystals. Chapters written by experts in the field shed light on theoretical as well as experimental aspects of research carried out since the discovery of flexoelectricity. Besides a common macroscopic (continuum) description the microscopic theory of flexoelectricity is also addressed. Electro-optic effects due to or modified by flexoelectricity as well as various (direct and indirect) measurement methods are discussed. Special emphasis is given to the role of flexoelectricity in pattern-forming instabilities. While the main focus of the book lies in flexoelectricity in nematic liquid crystals, peculiarities of other mesophases (bent-core systems, cholesterics, and smectics) are also reviewed. Flexoelectricity has relevance to biological (living) systems and can also offer possibilities for technical applications. The basics of these two interdisciplinary fields are also summarized.

Liquid crystals are widely used in flat panel displays and smart windows. In flat panel display application, one way to improve the efficiency is to decrease the driving frequency when static images are displayed. As the driving frequency is decreased, the transmittance of the display may vary with time, a phenomenon known as flickering. We carried out both experimental and simulation studies to investigate the origins that cause the flickering problem. Our results show that flexoelectric effect and ions in the liquid crystal are the main factors responsible for the flickering. We quantitatively analyzed the flickering caused by the two factors. The ionic effect can be eliminated by using the fluorinated liquid crystals with high resistivity. The flexoelectric effect is attributed to the intrinsic flexoelectric coefficient of the liquid crystal and nonuniformity of the liquid crystal director configurations. We demonstrated that polymer stabilization can smooth the spatial variation of the liquid crystal orientation, while doping a liquid crystal dimer can reduce the flexoelectric coefficient of the liquid crystal. Using these methods we are able to reduce the flickering significantly. Radiant energy-flow control and privacy control are two important features for smart windows (or glass). Current smart window technologies can, however, only control one of them: radiant energy flow or privacy. Therefore, a dual-mode smart window is highly desirable. We developed a dual-mode switchable liquid-crystal window that can control both radiant energy flow and privacy. The switchable liquid-crystal window makes use of dielectric and flexoelectric effects. In the absence of an applied voltage, the window is clear and transparent, and radiant energy can flow through it and the scenery behind the window can be seen. When a low-frequency (50 Hz) voltage is applied, the window is switched to an optical scattering and absorbing state by a flexoelectric effect, and thus, privacy is protected. When a high-frequency (1 kHz) voltage is applied, the window is switched to an optical absorbing but nonscattering state through a dielectric effect, and thus, radiant energy flow is controlled. Smart windows can be categorized mainly into two types according to the operation principle: electrical switchable window and thermal switchable windows. In the electric switchable window, voltage must be applied to switch the window, which consumes energy and is not environmentally friendly. Therefore, a power-free smart window is highly demanded. We developed a thermal switchable smart window that is sensitive to ambient temperature. The window is based on a liquid crystal whose orientation imposed by an alignment layer varies with temperature. The liquid crystal layer is sandwiched between two parallel polarizers to make the window. At high temperature, the liquid crystal is aligned parallel to the cell substrate and rotates the polarization of the incident light after the first polarizer by 90o such that incident light is completely absorbed by the second polarizer, and the transmittance of the window is 0. When temperature is decreased, the liquid crystal is tilted toward the cell substrate normal and rotates the polarization of the incident light less so that some light can pass the second polarizer, and the transmittance of the window increases. When temperature is decreased below a critical value, the liquid crystal is aligned perpendicular to the cell substrate and does not rotate the polarization of the incident light such that all light passes the second polarizer, and the transmittance reaches a maximum.

The work focuses on recent developments of the rapidly evolving field of Non-conventional Liquid Crystals. After a concise introduction it discusses the most promising research such as biosensing, elastomers, polymer films , photoresponsive properties and energy harvesting. Besides future applications it discusses as well potential frontiers in LC science and technology.

Over the past ten years liquid crystals have attracted much interest and considerable progress has been made with respect to our knowledge in this field. The recent development was initiated mainly by the work of J. L. Fergason and G. H. Heilmeier, who pointed out the importance of liquid crystals for thermographic and electro optic applications. The first part of this book is a brief introduction to the physics of liquid crystals. The structures and properties of the three basic types of liquid crystals are discussed. A special paragraph is devoted to electric-field effects, which are important in display applications. The chapter on Scientific Applications gives an insight into the potential applications of liquid crystals in fundamental research, with special emphasis on explaining the principles involved. Two groups of potential applications are discussed in detail: 1. the use of liquid crystals as anisotropic solvent for the determination of molecular properties by means of spectroscopy, and 2. their use in analytical chemistry, particularly in gas chromatography. The reverse process involves the use of the dissolved molecules as microscopic probes in the investigation of the dynamical molecular structure of anisotropic fluid systems (e.g. biological membranes). This extremely important technique is also described.

This book reviews comprehensively the technological, scientific, artistic and medical applications of liquid crystals. It starts with the basics of liquid crystals and covers electro-optical, thermo-optical, colour, polymeric, lyotropic, and scientific applications of liquid crystalline materials. It discusses the fabrication and operational principles of a full range of liquid crystal displays including dynamic scattering, twisted nematic, supertwisted nematic, dichroic, smectic A, ferroelectric, polymer dispersed, light valve, active matrix, etc., in detail. It also covers the emerging applications of liquid crystals such as optical computing, nonlinear optics, decorative and visual arts. Classification, theory, chemical structure, physical properties and surface alignment of liquid crystals have detailed chapters to facilitate the basic understanding of the science behind LCDs and other uses of liquid crystals. The chapters, liquid crystal polymers and lyotropic liquid crystals, give deep insight into these areas. The potential uses and applications are also described in detail.

The Handbook of Liquid Crystals is a unique compendium of knowledge on all aspects of liquid crystals. In over 2000 pages the Handbook provides detailed information on the basic principles of both low- and high-molecular weight materials, as well as the synthesis, characterization, modification, and applications (such as in computer displays or as structural materials) of all types of liquid crystals. The five editors of the Handbook are internationally renowned experts from both industry and academia and have drawn together over 70 leading figures in the field as authors. The four volumes of the Handbook are designed both to be used together or as stand-alone reference sources. Some users will require the whole set, others will be best served with one or two of the volumes. Volume 1 deals with the basic physical and chemical principles of liquid crystals, including structure-property relationships, nomenclature, phase behavior, characterization methods, and general synthesis and application strategies. As such this volume provides an excellent introduction to the field and a powerful learning and teaching tool for graduate students and above. Volumes 2A and 2B concentrate on low-molecular weight materials, for example those typically used in display technology. A high quality survey of the literature is provided along with full details of molecular design strategies, phase characterization and control, and applications development. These volumes are therefore by far the most detailed reference sources on these industrially very important materials, ideally suited for professionals in the field. Volume 3 concentrates on high-molecular weight, or polymeric, liquid crystals, some of which are found in structural applications and others occur as natural products of living systems. A high-quality literature survey is complemented by full detail of the synthesis, processing, analysis, and applications of all important materials classes. This volume is the most comprehensive reference source on these materials, and is therefore ideally suited for professionals in the field.