This laboratory book delivers hands-on advice to researchers in all fields of life and physical sciences already applying or intending to apply electro-analytical methods in their research. The authors represent in a strictly practice-oriented manner not only the necessary theoretical background but also substantial know-how on measurement techniques, interpretation of data, experimental setup and trouble shooting. The author and the editor are well-known specialists in their field.

Researchers and professionals will find a hands-on guide to successful experiments and applications of modern electroanalytical techniques here. The new edition has been completely revised and extended by a chapter on quartz-crystal microbalances. The book is written for chemists, biochemists, environmental and materials scientists, and physicists. A basic knowledge of chemistry and physics is sufficient for understanding the described methods. Electroanalytical techniques are particularly useful for qualitative and quantitative analysis of chemical, biochemical, and physical systems. Experienced experts provide the necessary theoretical background of electrochemistry and thoroughly describe frequently used measuring techniques. Special attention is given to experimental details and data evaluation.

This laboratory book delivers advice to researchers in all fields of life and physical sciences already applying or intending to apply electroanalytical methods in their research. The authors represent not only the necessary theoretical background but know-how on measurement techniques, interpretation of data and experimental setup.

Das führende Werk auf seinem Gebiet - jetzt durchgängig auf den neuesten Stand gebracht! Die theoretischen Grundlagen der Elektrochemie, erweitert um die aktuellsten Erkenntnisse in der Theorie des Elektronentransfers, werden hier ebenso besprochen wie alle wichtigen Anwendungen, darunter modernste Verfahren (Ultramikroelektroden, modifizierte Elektroden, LCEC, Impedanzspektrometrie, neue Varianten der Pulsvoltammetrie und andere). In erster Linie als Lehrbuch gedacht, läßt sich das Werk aber auch hervorragend zum Selbststudium und zur Auffrischung des Wissensstandes verwenden. Lediglich elementare Grundkenntnisse der physikalischen Chemie werden vorausgesetzt.

The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays

Introduction1. CONDUCTOMETRYElectrolytic ConductanceOhm’s LawSpecific ConductanceEquivalent ConductanceMolar ConductanceDetermination of Electrolytic ConductanceTypes of Conductivity CellsConductivity MeasurementsImmersed-Electrode MeasurementsElectrodeless MeasurementsApplications of Conductivity MeasurementsDetermination of Ionic Product of Water (KW)Determination of Solubility of Sparingly Soluble SaltsConductometric TitrationsDetermination of Purity of WaterConcentration DeterminationIon ChromatographyProblemsReferences2. POTENTIOMETRYPrincipleInstrumentationReference ElectrodesIndicator ElectrodesAnalytical InformationAdvantagesApplicationsPotentiometric TitrationsOther ApplicationsProblemsReferences3. VOLTAMMETRYPolarographyDc Polarography (Conventional Polarography)PrincipleFaradaic and Non-Faradaic ProcessesFaradaic CurrentNon-Faradaic CurrentPolarographic WaveCharging CurrentMass TransportLimiting CurrentsPolarographic MaximaInstrumentationPotentiostatElectrochemical CellTwo-electrode PolarographThree-electrode PolarographInert AtmosphereQuantitative TechniquesWave Height–Concentration PlotsInternal Standard (Pilot Ion) MethodMethod of Standard AdditionPulse PolarographyBasic PrincipleNormal Pulse PolarographyDifferential Pulse PolarographyPulse Voltammetry at Stationary ElectrodeApplicationsFundamental Harmonic AC PolarographyFaradaic Electrode ProcessesChronopotentiometryLinear Sweep Voltammetry and Related TechniquesTheory for Faradaic ProcessesCoupled Chemical ReactionsStripping VoltammetryAnodic Stripping VoltammetryElectrodesTheory and TechniquesCathodic Stripping VoltammetryAdsorptive Stripping VoltammetryProblemsReferences4. AMPEROMETRYPrincipleInstrumentationAmperometric Detection and BiosensorsAmperometric TitrationsTitrations with DMETitrations with Rotating Pt ElectrodeBiamperometric TitrationsAdvantages of Amperometric TitrationsApplicationsProblemsReferences5. COULOMETRYControlled Potential MethodsCoulometric MeasurementsControlled Current MethodsCoulometric MeasurementsApplications