In this reference, the author thoroughly reviews the current state of condensed phosphate chemistry. A unique feature of this volume is an examination of the recent developments in X-ray structural techniques, reporting on fundamental results obtained through their use. Enhanced by comprehensive tables reporting crystal data, chapters identify and characterize more than 2,000 compounds. Additional features include a concise survey of the historical development of condensed phosphate chemistry; the presently accepted classification system; a review of each family of condensed phosphates and much more.

This book aims to open new fields of interest in phosphate chemistry and to suggest a new system of classification for phosphates. Due to the very rapid development of this branch of chemistry during the last thirty years and the very confusing nomenclature often used in chemical literature, this first attempt seems not only justified but necessary. The suggested classification is not revolutionary, with respect to condensed phosphates for instance, but establishes clear boundaries between some categories of compounds such as adducts and heteropolyanion-compounds. The first chapters cover the present state of phosphate chemistry in a general way and could serve as an introduction to phosphates for some categories of students or teachers. The next few chapters are devoted to more specialized topics which would be of interest to chemists, crystallographers or solid-state specialists.Some specific aspects of the crystal chemistry of phosphates, such as the geometry of the networks built by acidic phosphoric anions, for instance, are covered for the first time. The final chapter suggests some improvements for the present system of classification for phosphates.In addition, presented for the first time are the results recently obtained for the replacement of asbestos by harmless biodegradable phosphate fibers.

Analytical Chemistry of the Condensed Phosphates describes the concept and mode of operation of various analytical methods for analysis of the condensed phosphates. This book is composed of ten chapters, and begins with a presentation of the general properties of the condensed phosphates. Considerable chapters are devoted to various analytical techniques used for condensed phosphate analysis, such as gravimetry, titrimetry, and electrometric, chromatographic, physical, and automated methods. A chapter discusses the procedures for the determination of esters of the condensed phosphates. The concluding chapters survey the preferred method of quantitative analysis of these compounds, as well as the preparation of pure samples. This book will prove useful to analytical, inorganic, and organic chemists and researchers.

This volume is a new, fully revised English edition of the Japanese version published in 1985. It is unique in being the first work of its kind to review phosphates from the materials science aspect, and contains contributions by Japanese researchers who are in the forefront of inorganic phosphate chemistry.