Crown Ethers and Phase Transfer Catalysis in Polymer Science

Crown Ethers and Phase Transfer Catalysis in Polymer Science
Title Crown Ethers and Phase Transfer Catalysis in Polymer Science PDF eBook
Author Lon Mathias
Publisher Springer Science & Business Media
Pages 421
Release 2013-11-22
Genre Technology & Engineering
ISBN 1461593492

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Phase transfer catalysis or interfacial catalysis is a syn thetic technique involving transport of an organic or inorganic salt from a solid or aqueous phase into an organic liquid where reaction with an organic-soluble substrate takes place. Over the past 15 years there has been an enormous amount of effort invested in the development of this technique in organic synthe sis. Several books and numerous review articles have appeared summarizing applications in which low molecular weight catalysts are employed. These generally include either crown ethers or onium salts of various kinds. While the term phase transfer catalysis is relatively new, the concept of using a phasetrans fer agent (PTA) is much older~ Both Schnell and Morgan employed such catalysts in synthesis of polymeric species in the early 1950's. Present developments are really extensions of these early applications. It has only been within the last several years that the use of phase transfer processes have been employed in polymer synthesis and modification. Similarly, the use of polymer-bound phase transfer agents is also a recent development. These and related areas have nonetheless enjoyed explosive growth as mea sured by the number of publications and the variety of applica tions which have appeared. Several reviews dealing with these l 6 polymer-related investigations have been published.

Concise Polymeric Materials Encyclopedia

Concise Polymeric Materials Encyclopedia
Title Concise Polymeric Materials Encyclopedia PDF eBook
Author Joseph C. Salamone
Publisher CRC Press
Pages 1778
Release 1998-08-28
Genre Technology & Engineering
ISBN 9780849322266

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Concise Polymeric Materials Encyclopedia culls the most used, widely applicable articles from the Polymeric Materials Encyclopedia - more than 1,100 - and presents them to you in a condensed, well-ordered format. Featuring contributions from more than 1,800 scientists from all over the world, the book discusses a vast array of subjects related to the: synthesis, properties, and applications of polymeric materials development of modern catalysts in preparing new or modified polymers modification of existing polymers by chemical and physical processes biologically oriented polymers This comprehensive, easy-to-use resource on modern polymeric materials serves as an invaluable addition to reference collections in the polymer field.

Asphalt Science and Technology

Asphalt Science and Technology
Title Asphalt Science and Technology PDF eBook
Author Arthur Usmani
Publisher CRC Press
Pages 548
Release 1997-08-22
Genre Technology & Engineering
ISBN 9780824799984

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"Offers comprehensive, authoritative coverage of the chemistry, technology, and engineering of asphaltic products for paving, road construction, roofing, coatings, adhesives, and batteries. Analyzes microcracking and elucidates the mechanisms of degradation to aid the development of hot melt asphalt and increase longevity."

Ion Exchangers

Ion Exchangers
Title Ion Exchangers PDF eBook
Author Konrad Dorfner
Publisher Walter de Gruyter
Pages 1532
Release 2011-06-15
Genre Science
ISBN 3110862433

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NASA Technical Memorandum

NASA Technical Memorandum
Title NASA Technical Memorandum PDF eBook
Author
Publisher
Pages 632
Release 1985
Genre Aeronautics
ISBN

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Handbook of Ring-Opening Polymerization

Handbook of Ring-Opening Polymerization
Title Handbook of Ring-Opening Polymerization PDF eBook
Author Philippe Dubois
Publisher John Wiley & Sons
Pages 425
Release 2008-12-17
Genre Technology & Engineering
ISBN 3527623787

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This comprehensive, truly one-stop reference discusses monomers, methods, stereochemistry, industrial applications and more. Chapters written by internationally acclaimed experts in their respective fields cover both basic principles and up-to-date information, ranging from the controlled ring-opening polymerization methods to polymer materials of industrial interest. All main classes of monomers including heterocyclics, cyclic olefins and alkynes, and cycloalkanes, are discussed separately as well as their specificities regarding the ring-opening polymerization techniques, the mechanisms, the degree of control, the properties of the related polymers and their applications. The two last chapters are devoted to the implementation of green chemistry in ring-opening polymerization processes. Of much interest to chemists in academia and industry.

Polymer Additives

Polymer Additives
Title Polymer Additives PDF eBook
Author Jiri E. Kresta
Publisher Springer Science & Business Media
Pages 403
Release 2012-12-06
Genre Science
ISBN 1461327970

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Ever since the beginning of the plastics and rubber industry, it was realized that useful products could be produced only if cer tain additives were incorporated into polymers. With the help of these additives, when physically dispersed in a polymer matrix, it has been possible to improve stability against thermal, oxidative, UV, hydrolytic and biological degradation, mechanical properties, flammability, cost, and processibility of plastics. The enormous growth of the volume of plastics consumed by modern society, and new application areas for plastics, have created a demand for new, better additives and better understanding of their functions in polymer systems. As a result of these trends there is a need for sharing of information on progress achieved in the area of polymer additives among engineers and scientists of the plastics industry and academia. This book is based on expanded and updated papers originally presented at the International Symposium on Polymer Additives, which was held in Las Vegas, Nevada, and was sponsored by the American Chemical Society, Division of Polymeric Materials Science and Engi neering. The book is divided into five parts which cover advances in various areas of polymer additives. The first part is devoted to the progress in understanding of UV degradation and stabilization of various polymers. Oxidation degradation and stabilization of plastic materials is covered in the second part. New developments in the stabilization of PVC are presented in the third part.