The understanding of how small solid particles operate at liquid interfaces is minimal. This book brings together the topics actively being investigated, with contributions from experts in the field. It will be of interest to researchers in chemistry, physics, chemical engineering, pharmacy, food science and materials science.

Fluid interfaces are promising candidates for confining different types of materials, e.g., polymers, surfactants, colloids, and even small molecules, to be used in designing new functional materials with reduced dimensionality. The development of such materials requires a deepening of the physicochemical bases underlying the formation of layers at fluid interfaces as well as on the characterization of their structures and properties. This is of particular importance because the constraints associated with the assembly of materials at the interface lead to the emergence of equilibrium and features of dynamics in the interfacial systems, which are far removed from those conventionally found in traditional materials. This Special Issue is devoted to studies on the fundamental and applied aspects of fluid interfaces, and attempts to provide a comprehensive perspective on the current status of the research field.

Volume V is the counterpart of Volume IV and treats hydrophilic colloids and related items. Contains edited contributions on steric stabilization, depletion, polyelectrolytes, proteins at interfaces, association colloids, microemulsions, thin films, foams and emulsions. J. Lyklema is coauthor of two chapters and general editor. Other authors include: G.J. Fleer, F.A.M. Leermakers, M.A. Cohen Stuart, W. Norde, J.A.G. Buijs, J.C. Eriksson, T.Sottmann, R. Strey, D. Platikanov, D. Ekserova, V.Bergeron and P.Walstra. * This volume completes the prestigious series Fundamentals of Interface and Colloid Science* Together with Volume IV this book provides a comprehensive introduction to colloid science.* Explains and elaborates phenomena starting from basic principles and progresses to more advanced topics

This textbook seeks to bring readers with no prior knowledge or experience in interfacial phenomena, colloid science or nanoscience to the point where they can comfortably enter the current scientific and technical literature in the area.Designed as a pedagogical tool, this textbook recognizes the cross-disciplinary nature of the subject. To facilitate learning, the topics are developed from the beginning with ample cross-referencing. The understanding of concepts is enhanced by clear descriptions of experiments and provisions of figures and illustrations.

In the small world of micrometer to nanometer scale many natural and industrial processes include attachment of colloid particles (solid spheres, liquid droplets, gas bubbles or protein macromolecules) to fluid interfaces and their confinement in liquid films. This may lead to the appearance of lateral interactions between particles at interfaces, or between inclusions in phospholipid membranes, followed eventually by the formation of two-dimensional ordered arrays. The book is devoted to the description of such processes, their consecutive stages, and to the investigation of the underlying physico-chemical mechanisms. The first six chapters give a concise but informative introduction to the basic knowledge in surface and colloid science, which includes both traditional concepts and some recent results. Chapters 1 and 2 are devoted to the basic theory of capillarity, kinetics of surfactant adsorption, shapes of axisymmetric fluid interfaces, contact angles and line tension. Chapters 3 and 4 present a generalization of the theory of capillarity to the case, in which the variation of the interfacial (membrane) curvature contributes to the total energy of the system. The generalized Laplace equation is applied to determine the configurations of free and adherent biological cells. Chapters 5 and 6 are focused on the role of thin liquid films and hydrodynamic factors in the attachment of solid and fluid particles to an interface. Surface forces of various physical nature are presented and their relative importance is discussed. Hydrodynamic interactions of a colloidal particle with an interface (or another particle) are also considered.Chapters 7 to 10 are devoted to the theoretical foundation of various kinds of capillary forces. When two particles are attached to the same interface (membrane), capillary interactions, mediated by the interface or membrane, appear between them. Two major kinds of capillary interactions are described: (i) capillary immersion force related to the surface wettability (Chapter 7), (ii) capillary flotation force originating from interfacial deformations due to particle weight (Chapter 8). Special attention is paid to the theory of capillary immersion forces between particles entrapped in spherical liquid films (Chapter 9). A generalization of the theory of immersion forces allows one to describe membrane-mediated interactions between protein inclusions into a lipid bilayer (Chapter 10).Chapter 11 is devoted to the theory of the capillary bridges and the capillary-bridge forces, whose importance has been recognized in phenomena like consolidation of granules and soils, wetting of powders, capillary condensation, long-range hydrophobic attraction, etc. The nucleation of capillary bridges is also examined.Chapter 12 considers solid particles, which have an irregular wetting perimeter upon attachment to a fluid interface. The undulated contact line induces interfacial deformations, which engender a special lateral capillary force between the particles. The latter contributes to the dilatational and shear elastic moduli of particulate adsorption monolayers.Chapter 13 describes how lateral capillary forces, facilitated by convective flows and some specific and non-specific interactions, can lead to the aggregation and ordering of various particles at fluid interfaces or in thin liquid films. Recent results on fabricating two-dimensional (2D) arrays from micrometer and sub-micrometer latex particles, as well as 2D crystals from proteins and protein complexes, are reviewed. Chapter 14 presents applied aspects of the particle-surface interaction in antifoaming and defoaming. The mechanisms of antifoaming action involve as a necessary step the entering of an antifoam particle at the air-water interface. The considered mechanisms indicate the factors for control of foaminess.

Fundamentals of Interface and Colloid Science (FICS) is a standard reference work with an educational nature. The emphasis is on the basic facts and phenomena, which are systematically explained. FICS aims to make interface and colloid science accessible to a wide audience. Interface and colloid science is an important and fascinating field, but one that is often overlooked and undervalued. It has applications as diverse as agriculture, mineral dressing, oil recovery, industrial chemistry, medical science and biotechnology.A deductive approach is followed, with systems of growing complexity being treated as the book progresses. Volume I: Fundamentals (1st ed. 1991, 2nd ed. 1993) reviews the physical chemistry required to understand current literature on interfacial and colloid science. The volume starts from first principles and gradually increases the level. Volume II: Solid-Liquid Interfaces (1995) treats the subject systematically for the first time, including adsorption, double layers and electronkinetics. Volume III: Interface Tension covers interfacial tensions, monolayers and wetting. - Accessible to a wide audience without a detailed knowledge of physics and chemistry - Complex mathematical derivations are kept to a minimum - Treats interfacial and colloidal phenomena from first principles (advanced command of physics and chemistry not required) - Takes the reader from elementary to expert level - Acts as a reference and a textbook - Contains extensive and detailed cumulative subject index

From the reviews of the First Edition: "The book has admirably met its stated goal. The whole gamut of surface and colloid science has been presented in a comprehensive manner without any undue oversimplification. The author should be congratulated for his clarity." -Advanced Materials Now in its second edition, this work remains the single most useful introduction available to the complex area of surface and colloids science. Industry expert Drew Myers walks readers through concepts, theories, and applications-keeping the mathematics to a minimum and presenting real-world case studies to illustrate key technological and biological processes. He substantially reorganizes and updates the material to reflect the current state of knowledge in the field, offering new chapters on absorption and biological systems in addition to the important areas of colloid stability, emulsions and foams, monolayer films, surfactants, and wetting. This revision also boasts an improved index, more than 200 new line drawings, general and specific chapter bibliographies, and end-of-chapter problems. Geared to scientists, technologists, and students dealing with colloidal and surface systems and their numerous industrial applications, the book imparts an understanding of the fundamental aspects of surfaces, interfaces, and colloids, which is essential for effective solutions in diverse areas of chemistry, physics, biology, medicine, engineering, and material sciences.