The Chemistry of Pyrroles

The Chemistry of Pyrroles
Title The Chemistry of Pyrroles PDF eBook
Author R. Alan Jones
Publisher Academic Press
Pages 539
Release 2013-10-22
Genre Science
ISBN 1483218473

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The Chemistry of Pyrroles, Volume 34 aims to provide a comprehensive survey of the synthesis of simple pyrroles and to present, wherever possible, a mechanistic and theoretical rationale for the multitude of reactions known for pyrroles. The book discusses the structure and reactivity of pyrrole; the synthesis of the pyrrole ring; and the electrophilic substitution of the pyrrole ring. The text also describes the oxidation and reduction of the pyrrole ring; the rearrangement and addition reactions; and the ketones, aldehydes, and carboxylic acid derivatives of pyrrole. Alkylpyrroles and related compounds; hydroxy- and aminopyrroles and related compounds; and azafulvenes are also considered. The book further tackles the physico-organic properties of pyrrole. Chemists and researchers of pyrrole chemistry will find the text invaluable.

Chemistry of Pyrroles

Chemistry of Pyrroles
Title Chemistry of Pyrroles PDF eBook
Author Boris A. Trofimov
Publisher CRC Press
Pages 402
Release 2014-10-13
Genre Science
ISBN 1482232421

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During the last 30 years, knowledge of the essential role that pyrrole structures play in the chemistry of living organisms, drug design, and the development of advanced materials has increased. Correspondingly, research on the diverse issues of synthetic, theoretical, and applied chemistry has snowballed. Devoted to the latest achievements of this field, Chemistry of Pyrroles covers the discovery and development of a novel, facile, and highly effective method for the construction of the pyrrole ring from ketones (ketoximes) and acetylene in superbase catalytic systems (Trofimov reaction). It provides cutting-edge details on the preparation of valuable but previously inaccessible pyrrole compounds. It includes approximately 1,000 structures of novel pyrrole compounds, their yields, and physical-chemical characteristics. The authors analyze conditions of typical syntheses, limitations of their applicability, and possibility of vinyl chloride or dichloroethane application instead of acetylene. They examine chemical engineering aspects of the first synthesis of tetrahydroindole and indole from commercially available oxime of cyclohexanone and acetylene. In addition, the book discusses new facets of pyrroles and N-vinyl pyrroles reactivity in the reactions with the participation of both the pyrrole ring and N-vinyl groups. The book provides condensed, clear-cut information on novel syntheses of substituted pyrroles as key structural units of living matter (chlorophyll and hemoglobin), pharmaceuticals, and monomers for optoelectronic materials. It includes tables that provide references to original works, forming a guide to a variety of the reactions and synthesized compounds discussed. With coverage of the broad range of pyrrole chemistry and methods for their synthesis, it provides both a theoretical and an experimental basis for drug design.

Pyrrole

Pyrrole
Title Pyrrole PDF eBook
Author Colin Welch
Publisher
Pages 116
Release 2020-02-19
Genre Science
ISBN 9781536171693

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Pyrrole: Synthesis and Applications provides an overview of polypyrrole synthesis by different methods such as chemical polymerization, lecetro-polymerization, photo-initiated polymerization and γ irradiated polymerization.Pyrrole derivatives play a crucial role in organic chemistry, medicinal chemistry, and heterocyclic chemistry. Pyrrole scaffold is extensively used in the synthesis of drug molecules with various pharmacological properties, as well as in material sciences.Finally, the authors review studies on the electrical properties of hybrid polymers which revealed that their electrical conductivity increased markedly with the proportion of pyrrole in the initial mixture. This is attributed to the formation of an electrically conducting polymer network in the non-conducting methacrylate matrix.

Flavin-Dependent Enzymes: Mechanisms, Structures and Applications

Flavin-Dependent Enzymes: Mechanisms, Structures and Applications
Title Flavin-Dependent Enzymes: Mechanisms, Structures and Applications PDF eBook
Author
Publisher Academic Press
Pages 568
Release 2020-09-21
Genre Science
ISBN 012820138X

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The Enzymes, Volume 47, highlights new advances in the field, with this new volume presenting interesting chapters on The Multipurpose Family of Oxidases, Vanillyl alcohol oxidase, Choline oxidases, Aryl alcohol oxidase, D- and L-amino acid oxidases, Sugar oxidases, Phenolic Compounds hydroxylases, Baeyer-Villiger Monooxygenases, Flavin-dependent halogenases, Flavin-dependent dehalogenases, Styrene Monooxygenases, Bacterial luciferases, Cellobiose Dehydrogenases, Prenylated flavoenzymes, Ene-reductases, Flavoenzymes in Biocatalysis. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in The Enzymes series

Pyrroles, Volume 48, Part 1

Pyrroles, Volume 48, Part 1
Title Pyrroles, Volume 48, Part 1 PDF eBook
Author Richard A. Jones
Publisher John Wiley & Sons
Pages 765
Release 2009-09-17
Genre Science
ISBN 0470188847

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The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects – properties, synthesis, reactions, physiological and industrial significance – of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature on each individual ring system have been published. Many ring systems (such as pyridines and oxazoles) are treated in distinct books, each consisting of separate volumes or parts dealing with different individual topics. With all authors are recognized authorities, the Chemistry of Heterocyclic Chemistry is considered worldwide as the indispensable resource for organic, bioorganic, and medicinal chemists.

Practical Synthetic Organic Chemistry

Practical Synthetic Organic Chemistry
Title Practical Synthetic Organic Chemistry PDF eBook
Author Stéphane Caron
Publisher John Wiley & Sons
Pages 850
Release 2020-02-05
Genre Science
ISBN 1119448859

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This book is a hands-on guide for the organic chemist. Focusing on the most reliable and useful reactions, the chapter authors provide the information necessary for a chemist to strategically plan a synthesis, as well as repeat the procedures in the laboratory. Consolidates all the key advances/concepts in one book, covering the most important reactions in organic chemistry, including substitutions, additions, eliminations, rearrangements, oxidations, reductions Highlights the most important reactions, addressing basic principles, advantages/disadvantages of the methodology, mechanism, and techniques for achieving laboratory success Features new content on recent advances in CH activation, photoredox and electrochemistry, continuous chemistry, and application of biocatalysis in synthesis Revamps chapters to include new and additional examples of chemistry that have been demonstrated at a practical scale

Handbook of Heterocyclic Chemistry

Handbook of Heterocyclic Chemistry
Title Handbook of Heterocyclic Chemistry PDF eBook
Author Alan R. Katritzky
Publisher Elsevier
Pages 568
Release 2017-01-31
Genre Science
ISBN 1483293424

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Provides a one-volume overall picture of the largest of the classical divisions of organic chemistry, suitable for the graduate or advanced undergraduate student, as well as for research workers, both specialists in the field and those engaged in another discipline and requiring knowledge of heterocyclic chemistry. It represents Volume 9 of Comprehensive Heterocyclic Chemistry and utilizes the general chapters which appear in the 8-volume work. The highly systematic coverage given to the subject makes this the most authoritative one-volume account of modern heterocyclic chemistry available.