Chemistry and Physics of Matrix-isolated Species
Title | Chemistry and Physics of Matrix-isolated Species PDF eBook |
Author | Lester Andrews |
Publisher | |
Pages | 448 |
Release | 1989 |
Genre | Science |
ISBN |
Matrix-isolation spectroscopy, as a technique for studying unstable species, has had tremendous lasting powers. Since 1954, matrix-isolation has been able to assimilate new technology rather than being replaced by it. The matrix-isolation technique for producing and trapping new chemical species has been applied to an ever increasing range of chemical and physical problems since its inception. The last 12 years have seen a substantial number of new developments and applications of the matrix technique. The chapters in this book describe many of the contributions of matrix-isolation spectroscopy to chemistry and physics in the last decade, and as such predict the continued evolution of this technique over the next decade. Experimental techniques are generally closely related to the development of new apparatus, and each chapter has a section describing innovations in instrumentation such as the closed-cycle cryogenic cooler that has revolutionized the technique. In addition, each chapter describes many of the specialized methods used to prepare, trap and study particular new subject species. The volume will be an indispensable reference source for graduate students and other scientists new to this field, as well as chemists and physicists already involved in applied spectroscopy.
The Chemistry and Physics of Matrix Isolated Species
Title | The Chemistry and Physics of Matrix Isolated Species PDF eBook |
Author | Uniwersytet Wrocławski. Wydział Chemii |
Publisher | |
Pages | 178 |
Release | 2001 |
Genre | |
ISBN |
Matrix Isolation Spectroscopy
Title | Matrix Isolation Spectroscopy PDF eBook |
Author | A. Barnes |
Publisher | Springer Science & Business Media |
Pages | 602 |
Release | 2012-12-06 |
Genre | Science |
ISBN | 9400985401 |
The matrix isolation (MI) method has now been used for nearly thirty years. During this period it has been actively developed and the range of problems tackled greatly extended. Originally it was used for studies of transient species involv ing vibrational, electronic and ESR spectroscopy. Nowadays the study of transient species forms a comparatively small part of HI work since it has been amply demonstrated that very fruitful information can be obtained of the structure and interactions of stable molecules and their aggregates. In addition to the s~ectroscopic methods mentioned above the MI technique is nowadays a standard method in research based on vibrational relaxation, luminescence, Mossbauer, magnetic circular dichroism, pulsed NMR and photoelectron spectroscopy. The matrix isolation technique affords considerable advantages over more conventional methods in most applications of spectroscopy. Areas where the technique has been widely applied, or shows great potential, include: metal atom chemistry, and its relation to surface chemistry, high temperature inorganic species, transition metal complexes, interstellar species, free radicals and unstable molecules, conformational studies, molecular com plexes, and intermolecular forces.
CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2
Title | CRC Handbook of Organic Photochemistry and Photobiology, Volumes 1 & 2 PDF eBook |
Author | William M. Horspool |
Publisher | CRC Press |
Pages | 2898 |
Release | 2003-09-29 |
Genre | Science |
ISBN | 020349590X |
The second edition of this best-selling handbook is bigger, more comprehensive, and now completely current. In addition to thorough updates to the discussions featured in the first edition, this edition includes 66 new chapters that reflect recent developments, new applications, and emerging areas of interest. Within the handbook's 145 critically r
A Collection of Papers from the International Conference "MATRIX 2005 - Recent Progress and New Developments on the Physics and Chemistry of Matrix-Isolated Species", Funchal, Madeira, July 24 - 29, 2005
Title | A Collection of Papers from the International Conference "MATRIX 2005 - Recent Progress and New Developments on the Physics and Chemistry of Matrix-Isolated Species", Funchal, Madeira, July 24 - 29, 2005 PDF eBook |
Author | International Conference MATRIX 2005 - Recent Progress and New Developments on the Physics and Chemistry of Matrix Isolated Species |
Publisher | |
Pages | 142 |
Release | 2005 |
Genre | |
ISBN |
Reactive Intermediate Chemistry
Title | Reactive Intermediate Chemistry PDF eBook |
Author | Robert A. Moss |
Publisher | John Wiley & Sons |
Pages | 1088 |
Release | 2004-01-07 |
Genre | Science |
ISBN | 9780471233244 |
Reactive Intermediate Chemistry presents a detailed and timely examination of key intermediates central to the mechanisms of numerous organic chemical transformations. Spectroscopy, kinetics, and computational studies are integrated in chapters dealing with the chemistry of carbocations, carbanions, radicals, radical ions, carbenes, nitrenes, arynes, nitrenium ions, diradicals, etc. Nanosecond, picosecond, and femtosecond kinetic realms are explored, and applications of current dynamics and electronic structure calculations are examined. Reactive Intermediate Chemistry provides a deeper understanding of contemporary physical organic chemistry, and will assist chemists in the design of new reactions for the efficient synthesis of pharmaceuticals, fine chemicals, and agricultural products. Among its features, this authoritative volume is: Edited and authored by world-renowned leaders in physical organic chemistry. Ideal for use as a primary or supplemental graduate textbook for courses in mechanistic organic chemistry or physical chemistry. Enhanced by supplemental reading lists and summary overviews in each chapter.
Frontiers and Advances in Molecular Spectroscopy
Title | Frontiers and Advances in Molecular Spectroscopy PDF eBook |
Author | Jaan Laane |
Publisher | Elsevier |
Pages | 788 |
Release | 2017-11-13 |
Genre | Science |
ISBN | 0128112212 |
Frontiers and Advances in Molecular Spectroscopy once again brings together the most eminent scientists from around the world to describe their work at the cutting-edge of molecular spectroscopy. Much of what we know about atoms, molecules and the nature of matter has been obtained using spectroscopy over the last one hundred years or so. Going far beyond the topics discussed in Jaan Laane's earlier book on the subject, these chapters describe new methodologies and applications, instrumental developments and theory, which are taking spectroscopy into still new frontiers. The robust range of topics once again demonstrates the wide utility of spectroscopic techniques. New topics include ultrafast spectroscopy of the transition state, SERS/far-uv spectroscopy, femtosecond coherent anti-Stokes Raman spectroscopy, high-resolution laser induced fluorescence spectroscopy, Raman spectroscopy and biosensors, vibrational optical activity, ultrafast two-dimensional spectroscopy, biology with x-ray lasers, isomerization dynamics and hydrogen bonding, single molecule imaging, spectra of intermediates, matrix isolation spectroscopy and more. - Covers spectroscopic investigations on the cutting edge of science - Written and edited by leading experts in their respective fields - Allows researchers to access a broad range of essential modern spectroscopy content from a single source rather than wading through hundreds of scattered journal articles