The production of identified charged particles in pp collisions at .sqrt.s = 63 GeV with an identified high p/sub T/ trigger particle emitted in the central region is studied. The measurements were performed at the CERN ISR using the Axial Field Spectrometer. Trigger particle ratios, sigma(.pi./sup + -/)/ sigma(all/sup + -/), sigma(K/sup + -/) and sigma(p/sup + -/)/sigma(all/sup + -/) are presented for p/sub T/ from 5 GeV/c to 8 GeV/c. In addition sigma(.pi./sup + -/)/sigma(all/sup + -/) is presented in the p/sub T/ region from 2.5 GeV/c to 4.5 GeV/c. The charge compensation in the hemisphere containing the trigger particle is shown to depend strongly on the identity of the trigger particle and on the identity of the associated particles. 13 references.