A Textbook of Physical Chemistry

A Textbook of Physical Chemistry, Second Edition serves as an introductory text to physical chemistry. Topics covered range from wave mechanics and chemical bonding to molecular spectroscopy and photochemistry; ideal and nonideal gases; the three laws of thermodynamics; thermochemistry; and solutions of nonelectrolytes. The kinetics of gas-phase reactions; colloids and macromolecules; and nuclear chemistry and radiochemistry are also discussed. This edition is comprised of 22 chapters; the first of which introduces the reader to the behavior of ideal and nonideal gases, with particular emphasis on the van der Waals equation. The discussion then turns to the kinetic molecular theory of gases and the application of the Boltzmann principle to the treatment of molar polarization; dipole and magnetic moments; the phenomenology of light absorption; and classical and statistical thermodynamics. The chapters that follow focus on the traditional sequence of chemical and phase equilibria, electrochemistry, and chemical kinetics in gas phase and solution phase. This book also considers wave mechanics and its applications; molecular spectroscopy and photochemistry; and the excited state, and then concludes with an analysis of crystal structure, colloid and polymer chemistry, and radio and nuclear chemistry. This reference material is intended primarily as an introductory text for students of physical chemistry.

This elegant book provides a student-friendly introduction to the subject of physical chemistry. It is by the author of the very successful Basic Chemical Thermodynamics and is written in the same well-received popular style. It is concise and more compact than standard textbooks on the subject and emphasises the two important topics underpinning the subject: quantum mechanics and the second law of thermodynamics. Both topics are challenging to students because they focus on uncertainty and probability. The book explains these fundamental concepts clearly and shows how they offer the key to understanding a wide range of chemical phenomena including atomic and molecular spectra, the structure and properties of solids, liquids and gases, chemical equilibrium and the rates of chemical reactions.This revised edition has enabled improvements and corrections to be made.

Elements of Physical Chemistry has been carefully crafted to help students increase their confidence when using physics and mathematics to answer fundamental questions about the structure of molecules, how chemical reactions take place, and why materials behave the way they do.

This fifth edition gives students an in-depth fundamental treatment of physical chemistry which is made easy to follow by providing full step-by-step derivations, clear explanations and by avoiding advanced mathematics unfamiliar to students. Necessary maths and physics have thorough review sections, and all worked examples are now followed by a practice exercise. The material on quantum mechanics has been substantially revised. The book is organized so that students can see the broad structure and logic of physical chemistry rather than a mixture of formulas and ideas presented randomly, and a fair number of biological applications are included.

Maintaining the clear, approachable writing style characteristic of author Karen Timberlake, Basic Chemistry, Fourth Edition, adds to its suite of problem-solving tools and techniques necessary for success in chemistry. Engaging new features such as end-of-section Math Practice problems, video tutorials and Math Review Modules allow readers to practice and master quantitative skills. Popular features, including "Combining Ideas" sections and end-of-chapter questions, have also been strengthened and expanded. Modern real-world applications help students connect chemical principles to events in their world, while stories involving careers illustrate the importance of chemistry in future careers.