This work demonstrates the autoignition and chemical-kinetic mechanisms of homogeneous charge compression ignition (HCCI) combustion for the fuels with various autoignition reactivity. This is done for four fuels: methane, dimethyl ether (DME), iso-octane and n-heptane. Methane and iso-octane are selected as the single-stage ignition fuel, and DME and n-heptane are selected as the two-stage ignition fuel. As a tool for understanding the characteristics of autoignition and combustion process in HCCI engine, a zero-dimensional single-zone engine model of 'CHEMKIN' in Chemkin-Pro was used. The complete compression and expansion strokes were modeled using an engine with a connecting-rod length to crank-radius ratio of 3.5 and a compression ratio of 13. A detailed chemical-kinetic mechanism for methane and DME is Mech_56.54 (113 species and 710 reactions). For iso-octane and n-heptane, a detailed chemical-kinetic mechanism from Lawrence Livermore National Laboratory (1034 species and 4236 reactions) is used. The results show that methane and iso-octane exhibit only the main heat release, 'high-temperature heat release (HTHR)' by high-temperature reactions (HTR). In contrast, both DME and n-heptane exhibit the first heat release 'low-temperature heat release (LTHR)' associated with low-temperature reactions (LTR) before HTHR.

Lean Combustion: Technology and Control, Second Edition outlines and explains the latest advances in lean combustion technology and systems. Combustion under sufficiently fuel-lean conditions can have the desirable attributes of high efficiency and low emissions. The book offers readers both the fundamentals and latest developments in how lean burn (broadly defined) can increase fuel economy and decrease emissions, while still achieving desired power output and performance. This volume brings together research and design of lean combustion systems across the technology spectrum in order to explore the state-of-the-art in lean combustion. Readers will learn about advances in the understanding of ultra-lean fuel mixtures and how new types of burners and approaches to managing heat flow can reduce problems often found with lean combustion (such as slow, difficult ignition and frequent flame extinction). This book offers abundant references and examples of real-world applications. New to this edition are significantly revised chapters on IC engines and stability/oscillations, and new case studies and examples. Written by a team of experts, this contributed reference book aims to teach its reader to maximize efficiency and minimize both economic and environmental costs. - Presents a comprehensive collection of lean burn technology across potential applications, allowing readers to compare and contrast similarities and differences - Provides an extensive update on IC engines including compression ignition (diesel), spark ignition, and homogeneous charge compression ignition (HCCI) - Includes an extensive revision to the Stability/Oscillations chapter - Includes use of alternative fuels such as biogas and hydrogen for relevant technologies - Covers new developments in lean combustion using high levels of pre-heat and heat recirculating burners, as well as the active control of lean combustion instabilities